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Title: Spiers Memorial Lecture: Water at interfaces

Journal Article · · Faraday Discussions
DOI: https://doi.org/10.1039/D3FD00147D · OSTI ID:2007665

In this article we discuss current issues in the context of the four chosen subtopics for the meeting: dynamics and nano-rheology of interfacial water, electrified/charged aqueous interfaces, ice interfaces, and soft matter/water interfaces.

Sponsoring Organization:
USDOE
OSTI ID:
2007665
Journal Information:
Faraday Discussions, Journal Name: Faraday Discussions Vol. 249; ISSN 1359-6640
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (141)

Confirmation of enhanced anion concentration at the liquid water surface journal October 2004
Prebiotic phosphorylation enabled by microdroplets journal November 2017
Hydrogen bond network rearrangement dynamics in water clusters: Effects of intermolecular vibrational excitation on tunneling rates journal August 2017
Experimental and theoretical evidence for bilayer-by-bilayer surface melting of crystalline ice journal December 2016
Electrokinetic detection for X-ray spectra of weakly interacting liquids: n-decane and n-nonane journal June 2014
Elucidating the mechanism of selective ion adsorption to the liquid water surface journal January 2012
Two sides of the acid–base story journal January 2013
Molecular Insights into Chemical Reactions at Aqueous Aerosol Interfaces preprint January 2023
Electrostatics and Chemical Reactivity at the Air–Water Interface journal January 2023
Surface Characterization of Colloidal Silica Nanoparticles by Second Harmonic Scattering: Quantifying the Surface Potential and Interfacial Water Order journal July 2019
In Situ XPS Studies of Electrochemically Positively Polarized Molybdenum Carbide Derived Carbon Double Layer Capacitor Electrode journal January 2014
Direct Measurement of pH in Individual Particles via Raman Microspectroscopy and Variation in Acidity with Relative Humidity journal February 2016
Water Structure at the Hydrophobic Nanodroplet Surface Revealed by Vibrational Sum Frequency Scattering Using Isotopic Dilution journal April 2022
Interfacial Structures of Acidic and Basic Aqueous Solutions journal October 2008
pH jump kinetics in colliding microdroplets: accelerated synthesis of azamonardine from dopamine and resorcinol journal January 2023
Surface relaxation in liquid water and methanol studied by x-ray absorption spectroscopy journal October 2002
Effect of droplet lifetime on where ions are formed in electrospray ionization journal January 2019
The chemical reactions in electrosprays of water do not always correspond to those at the pristine air–water interface journal January 2019
Surface Propensities of the Self-Ions of Water journal March 2016
Effect of Surface Active Ions on the Rate of Water Evaporation journal May 2010
Hydroxide anion at the air–water interface journal October 2009
Probing the Molecular Structure and Bonding of the Surface of Aqueous Salt Solutions journal April 2004
Strong Electric Field Observed at the Interface of Aqueous Microdroplets journal August 2020
Water at charged interfaces journal June 2021
Accelerated reactions of amines with carbon dioxide driven by superacid at the microdroplet interface journal January 2021
Plasmon-Resonant Vibrational Sum Frequency Generation of Electrochemical Interfaces: Direct Observation of Carbon Dioxide Electroreduction on Gold journal August 2020
Label-free second harmonic and hyper Rayleigh scattering with high efficiency journal January 2013
Can electric fields drive chemistry for an aqueous microdroplet? journal January 2022
Evaporation kinetics of aqueous acetic acid droplets: effects of soluble organic aerosol components on the mechanism of water evaporation journal January 2013
On the mechanisms of ion adsorption to aqueous interfaces: air-water vs. oil-water journal October 2022
Imaging of pH distribution inside individual microdroplet by stimulated Raman microscopy journal May 2023
Analysis of the evaporation coefficient and the condensation coefficient of water journal January 2001
Titration of Aerosol pH through Droplet Coalescence journal July 2019
Improving the Accuracy of Atomistic Simulations of the Electrochemical Interface journal May 2022
Molecular Structure and Dynamics of Water at the Water-Air Interface Studied with Surface-Specific Vibrational Spectroscopy journal April 2015
Experimental and Thermodynamic Viewpoints on Claims of a Spontaneous H2O2 Formation at the Air–Water Interface journal March 2023
Simple model for the electric field and spatial distribution of ions in a microdroplet journal May 2020
Spatial homogeneity of pH in aerosol microdroplets journal April 2023
Microdroplets can act as electrochemical cells journal February 2022
Interfacial Structure and Electric Field Probed by in Situ Electrochemical Vibrational Stark Effect Spectroscopy and Computational Modeling journal August 2017
Bronsted basicity of the air-water interface journal October 2012
Premelting, fluctuations, and coarse-graining of water-ice interfaces journal November 2014
Electrokinetic Power Generation from Liquid Water Microjets journal October 2008
A discrepancy of 107 in experimental and theoretical density detection limits of aerosol particles by surface nonlinear light scattering journal June 2023
Studying Chemistry in Micro-compartments by Separating Droplet Generation from Ionization journal October 2018
On the evaporation of ammonium sulfate solution journal November 2009
Amine-functionalized metal-organic framework ZIF-8 toward colorimetric CO2 sensing in indoor air environment journal October 2021
Molecular reactions at aqueous interfaces journal July 2020
Surface Potential at the Air−Water Interface Computed Using Density Functional Theory journal December 2009
New Insights into the Charge-Transfer-to-Solvent Spectrum of Aqueous Iodide: Surface versus Bulk journal February 2020
Water Evaporation: A Transition Path Sampling Study journal January 2013
Diversity at the Water–Metal Interface: Metal, Water Thickness, and Confinement Effects journal February 2016
Molecular Mechanism of Water Evaporation journal November 2015
Dynamics of Water Molecules at the Water/Air Interface book April 2018
Role of stacking disorder in ice nucleation journal November 2017
Spontaneous generation of hydrogen peroxide from aqueous microdroplets journal August 2019
Bridging electrostatic properties between nanoscopic and microscopic highly charged droplets journal May 2020
Ice Surfaces journal May 2017
Sprayed Water Microdroplets Are Able to Generate Hydrogen Peroxide Spontaneously journal April 2022
Disentangling reaction rate acceleration in microdroplets journal January 2022
Electric buzz in a glass of pure water journal May 2022
Water at surfaces and interfaces: From molecules to ice and bulk liquid journal December 2018
Operando X-ray photoelectron spectroscopic investigations of the electrochemical double layer at Ir/KOH(aq) interfaces journal November 2017
Fundamentals of Sum-Frequency Spectroscopy book February 2016
Can the pH at the air/water interface be different from the pH of bulk water? journal August 2018
Abundant Production of Reactive Water Radical Cations under Ambient Conditions journal April 2022
Electrokinetic Hydrogen Generation from Liquid Water Microjets journal July 2007
Hydrogen and Electric Power Generation from Liquid Microjets: Design Principles for Optimizing Conversion Efficiency journal June 2016
High-efficiency ballistic electrostatic generator using microdroplets journal April 2014
Peeling back the layers: Investigating the effects of polyelectrolyte layering on surface structure and stability of oil-in-water nanoemulsions journal October 2021
Instantaneous Liquid Interfaces journal February 2010
Abiotic production of sugar phosphates and uridine ribonucleoside in aqueous microdroplets journal October 2017
Charge-Transfer-to-Solvent Spectrum of Thiocyanate at the Air/Water Interface Measured by Broadband Deep Ultraviolet Electronic Sum Frequency Generation Spectroscopy journal August 2018
Abiotic synthesis of purine and pyrimidine ribonucleosides in aqueous microdroplets journal December 2017
On the Nature of ions at the Liquid Water Surface journal May 2006
Microdroplet fusion mass spectrometry for fast reaction kinetics journal March 2015
Exploring Solid/Aqueous Interfaces with Ultradilute Electrokinetic Analysis of Liquid Microjets journal June 2013
Understanding the Surface Potential of Water journal April 2011
Spontaneous dark formation of OH radicals at the interface of aqueous atmospheric droplets journal April 2023
Isotopic fractionation of water during evaporation journal January 2003
Molecular Properties and Chemical Transformations Near Interfaces journal August 2021
New Information on the Hydrophobic Interaction Revealed by Frequency Modulation AFM journal February 2017
Ab Initio Simulations of Water/Metal Interfaces journal January 2022
Size dependence of second-harmonic scattering from nanoparticles: Disentangling surface and electrostatic contributions journal March 2023
Accelerated Reaction Kinetics in Microdroplets: Overview and Recent Developments journal April 2020
Water at Interfaces journal April 2016
Propensity of Hydrated Excess Protons and Hydroxide Anions for the Air–Water Interface journal September 2015
Low- and High-Density Unknown Waters at Ice–Water Interfaces journal May 2022
Soft X-Ray Second Harmonic Generation as an Interfacial Probe journal January 2018
Raman Thermometry Measurements of Free Evaporation from Liquid Water Droplets journal October 2006
Second-Harmonic Scattering in Layered Double Hydroxide Colloids: A Microscopic View of Adsorption and Intercalation journal September 2018
Water as a contrast agent to quantify surface chemistry and physics using second harmonic scattering and imaging: A perspective journal April 2022
Chemical Kinetics in Microdroplets journal August 2023
Vibrational Sum Frequency Scattering from a Submicron Suspension journal December 2003
Revisiting the Effect of the Air–Water Interface of Ultrasonically Atomized Water Microdroplets on H2O2 Formation journal April 2022
Local Ice-like Structure at the Liquid Water Surface journal June 2022
Double-layer distribution of hydronium and hydroxide ions in the air-water interface journal May 2023
Characterizing Anion Adsorption to Aqueous Interfaces: Toluene–Water versus Air–Water journal December 2021
Analysis of the evaporation coefficients of water, heavy water, and methanol in a high vacuum environment journal May 2023
Ions at the Air/Water Interface journal June 2002
Spontaneous Water Radical Cation Oxidation at Double Bonds in Microdroplets journal April 2022
Dynamics of Micropollutant Adsorption to Polystyrene Surfaces Probed by Angle-Resolved Second Harmonic Scattering journal May 2019
Hydration of metal surfaces can be dynamically heterogeneous and hydrophobic journal February 2013
Aerosol microdroplets exhibit a stable pH gradient journal June 2018
Water Exchange at a Hydrated Platinum Electrode is Rare and Collective journal October 2015
Is the liquid water surface basic or acidic? Macroscopic vs. molecular-scale investigations journal June 2008
Quantum Mechanical Modeling of Reaction Rate Acceleration in Microdroplets journal May 2020
Water Interfaces, Solvation, and Spectroscopy journal April 2013
Interfacial Steric and Molecular Bonding Effects Contributing to the Stability of Neutrally Charged Nanoemulsions journal October 2021
Variation of droplet acidity during evaporation journal May 2013
The Donnan potential revealed journal October 2022
Polarization-Dependent Heterodyne-Detected Sum-Frequency Generation Spectroscopy as a Tool to Explore Surface Molecular Orientation and Ångström-Scale Depth Profiling journal July 2022
Enhancement of reaction rate in small-sized droplets: A combined analytical and simulation study journal June 2018
Mechanism of ion adsorption to aqueous interfaces: Graphene/water vs. air/water journal August 2017
Terahertz VRT Spectroscopy of the Water Hexamer-h12 Cage: Dramatic Libration-Induced Enhancement of Hydrogen Bond Tunneling Dynamics journal August 2018
Evidence for an Enhanced Hydronium Concentration at the Liquid Water Surface journal April 2005
Structure and Dynamics of the Instantaneous Water/Vapor Interface Revisited by Path-Integral and Ab Initio Molecular Dynamics Simulations journal July 2015
Simultaneous and Spontaneous Oxidation and Reduction in Microdroplets by the Water Radical Cation/Anion Pair journal September 2022
Where Do the Ions Reside in a Highly Charged Droplet? journal October 2019
XPS at solid–aqueous solution interface journal September 2006
Surprising Effects of Hydrochloric Acid on the Water Evaporation Coefficient Observed by Raman Thermometry journal February 2017
The role of analyte concentration in accelerated reaction rates in evaporating droplets journal January 2023
Measurement of Bromide Ion Affinities for the Air/Water and Dodecanol/Water Interfaces at Molar Concentrations by UV Second Harmonic Generation Spectroscopy journal July 2010
Soft interface design for electrokinetic energy conversion journal January 2020
The Air–Water Interface of Water Microdroplets Formed by Ultrasonication or Condensation Does Not Produce H2O2 journal November 2021
Probing the Gold/Water Interface with Surface-Specific Spectroscopy journal January 2023
Experimentally probing the libration of interfacial water: the rotational potential of water is stiffer at the air/water interface than in bulk liquid journal January 2016
On the formation of hydrogen peroxide in water microdroplets journal January 2022
The excess proton at the air-water interface: The role of instantaneous liquid interfaces journal June 2017
Chemical transformations and transport phenomena at interfaces journal October 2022
Power generation from microjet array of liquid water journal June 2018
Condensing water vapor to droplets generates hydrogen peroxide journal November 2020
Characterizing heterogeneous dynamics at hydrated electrode surfaces journal May 2013
The microscopic mechanism of bulk melting of ice journal September 2021
Ion at Air–Water Interface Enhances Capillary Wave Fluctuations: Energetics of Ion Adsorption journal September 2018
Nature of Excess Hydrated Proton at the Water–Air Interface journal December 2019
Direct Determination of Aerosol pH: Size-Resolved Measurements of Submicrometer and Supermicrometer Aqueous Particles journal September 2018
Water surface is acidic journal April 2007
Spontaneous Formation of Hydrogen Peroxide in Water Microdroplets journal October 2022
Studies of electrochemical interfaces by broadband sum frequency generation journal September 2017
Molecular Structure and Modeling of Water–Air and Ice–Air Interfaces Monitored by Sum-Frequency Generation journal March 2020