Synthesis and Characterization of Cerium-Oxo Clusters Capped by Acetylacetonate

Blanes-Díaz, Anamar; Shohel, Mohammad; Rice, Natalie T.; Piedmonte, Ida; McDonald, Morgan A.; Jorabchi, Kaveh; Kozimor, Stosh A.; Bertke, Jeffery A.; Nyman, May; Knope, Karah E.

doi:10.1021/acs.inorgchem.3c02141

Title: Synthesis and Characterization of Cerium-Oxo Clusters Capped by Acetylacetonate

Journal Article · 03 October 2023 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.3c02141 · OSTI ID:2007569

Blanes-Díaz, Anamar ^[1]; Shohel, Mohammad ^[2]; Rice, Natalie T. ^[3]; Piedmonte, Ida ^[3];

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Department of Chemistry, Georgetown University, 37th and O Streets NW, Washington, D.C. 20057, United States
Department of Chemistry, Oregon State University, Corvallis, Oregon 97331, United States
Los Alamos National Laboratory (LANL), P.O. Box 1663, Los Alamos, New Mexico 87545, United States

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: SC0019190; NA0003763

OSTI ID:: 2007569

Alternate ID(s):: OSTI ID: 2367459; OSTI ID: 2007802; OSTI ID: 2008296

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 21 Vol. 63; ISSN 0020-1669

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (102)

A precursor method for the synthesis of new Ce( iv ) MOFs with reactive tetracarboxylate linkers Smolders, Simon; Struyf, Arnaud; Reinsch, Helge Chemical Communications, Vol. 54, Issue 8 https://doi.org/10.1039/C7CC08200B	journal	January 2018
Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products Knope, Karah E.; Soderholm, L. Chemical Reviews, Vol. 113, Issue 2 https://doi.org/10.1021/cr300212f	journal	October 2012
X-ray absorption studies of CeO 2 , PrO 2 , and TbO 2 . II. Rare-earth valence state by L III absorption edges Dexpert, H.; Karnatak, R. C.; Esteva, J. -M. Physical Review B, Vol. 36, Issue 3 https://doi.org/10.1103/PhysRevB.36.1750	journal	July 1987
The Structure of the Plutonium Oxide Nanocluster [Pu38O56Cl54(H2O)8]14− Soderholm, L.; Almond, Philip M.; Skanthakumar, S. Angewandte Chemie International Edition, Vol. 47, Issue 2 https://doi.org/10.1002/anie.200704420	journal	January 2008
Understanding and Controlling the Emission Brightness and Color of Molecular Cerium Luminophores Qiao, Yusen; Sergentu, Dumitru-Claudiu; Yin, Haolin Journal of the American Chemical Society, Vol. 140, Issue 13 https://doi.org/10.1021/jacs.7b13339	journal	January 2018
Thorium(IV) Molecular Clusters with a Hexanuclear Th Core Knope, Karah E.; Wilson, Richard E.; Vasiliu, Monica Inorganic Chemistry, Vol. 50, Issue 19 https://doi.org/10.1021/ic2014946	journal	October 2011
Cerium compounds in the fashion of the light actinides Koelling, D. D. Physica B+C, Vol. 130, Issue 1-3 https://doi.org/10.1016/0378-4363(85)90204-9	journal	May 1985
SeltenerdethenidhalogenideLn2n+6(C₂)_n₊₄X2n+2: Darstellung, Struktur, Verwachsung und Verzwilligung Mattausch, Hansjürgen; Kienle, Lorenz; Duppel, Viola Zeitschrift für anorganische und allgemeine Chemie, Vol. 635, Issue 11 https://doi.org/10.1002/zaac.200900289	journal	September 2009
Chloride templated formation of {Dy12(OH)16}20+ cluster core incorporating 1,10-phenanthroline-2,9-dicarboxylate Miao, Yan-Li; Liu, Jun-Liang; Leng, Ji-Dong CrystEngComm, Vol. 13, Issue 10 https://doi.org/10.1039/c1ce05211j	journal	January 2011
Lanthanide oxochalcogenido clusters Norton, Kieran; Banerjee, Santanu; Das, Sayantani Dalton Transactions, Vol. 39, Issue 29 https://doi.org/10.1039/c001812k	journal	January 2010
Truly Monodisperse Molecular Nanoparticles of Cerium Dioxide of 2.4 nm dimensions: A {Ce ₁₀₀ O ₁₆₇ } Cluster Russell‐Webster, Bradley; Lopez‐Nieto, Javi; Abboud, Khalil A. Angewandte Chemie International Edition, Vol. 60, Issue 22 https://doi.org/10.1002/anie.202103110	journal	April 2021
Tetravalent Ce in the Nitrate-Decorated Hexanuclear Cluster [Ce ₆ (μ ₃ -O) ₄ (μ ₃ -OH) ₄ ] ¹²⁺ : A Structural End Point for Ceria Nanoparticles Estes, Shanna L.; Antonio, Mark R.; Soderholm, L. The Journal of Physical Chemistry C, Vol. 120, Issue 10 https://doi.org/10.1021/acs.jpcc.6b00644	journal	January 2016
2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid‐State Metathesis Reactions Senevirathna, Dimuthu C.; Werrett, Melissa V.; Blair, Victoria L. Chemistry – A European Journal, Vol. 24, Issue 26 https://doi.org/10.1002/chem.201705981	journal	April 2018
Hydrolysis Studies on Bismuth Nitrate: Synthesis and Crystallization of Four Novel Polynuclear Basic Bismuth Nitrates Miersch, L.; Rüffer, T.; Schlesinger, M. Inorganic Chemistry, Vol. 51, Issue 17 https://doi.org/10.1021/ic301148p	journal	August 2012
Use of CeO2-based oxides in the three-way catalysis Kašpar, J.; Fornasiero, P.; Graziani, M. Catalysis Today, Vol. 50, Issue 2 https://doi.org/10.1016/S0920-5861(98)00510-0	journal	April 1999
The interpretation of real-space information from small-angle scattering experiments Glatter, O. Journal of Applied Crystallography, Vol. 12, Issue 2 https://doi.org/10.1107/S0021889879012139	journal	April 1979
Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway Thuijs, Annaliese E.; Li, Xiang-Guo; Wang, Yun-Peng Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00642-0	journal	September 2017
Schiff-base coordination complexes with plutonium( iv ) and cerium( iv ) Klamm, Bonnie E.; Windorff, Cory J.; Marsh, Matthew L. Chemical Communications, Vol. 54, Issue 62 https://doi.org/10.1039/C8CC03571G	journal	January 2018
Science-based cleanup of Rocky Flats Clark, David L.; Janecky, David R.; Lane, Leonard J. Physics Today, Vol. 59, Issue 9 https://doi.org/10.1063/1.2364243	journal	September 2006
Mixed valency versus covalency in rare-earth core-electron spectroscopy Kaindl, G.; Wertheim, G. K.; Schmiester, G. Physical Review Letters, Vol. 58, Issue 6 https://doi.org/10.1103/PhysRevLett.58.606	journal	February 1987
Cerium under the lens Schelter, Eric J. Nature Chemistry, Vol. 5, Issue 4 https://doi.org/10.1038/nchem.1602	journal	March 2013
Expansion of the Family of Molecular Nanoparticles of Cerium Dioxide and Their Catalytic Scavenging of Hydroxyl Radicals Mitchell, Kylie J.; Goodsell, Justin L.; Russell-Webster, Bradley Inorganic Chemistry, Vol. 60, Issue 3 https://doi.org/10.1021/acs.inorgchem.0c03133	journal	January 2021
Electrically Driven Redox Process in Cerium Oxides Gao, Peng; Kang, Zhenchuan; Fu, Wangyang Journal of the American Chemical Society, Vol. 132, Issue 12 https://doi.org/10.1021/ja9086616	journal	March 2010
ShelXle : a Qt graphical user interface for SHELXL Hübschle, Christian B.; Sheldrick, George M.; Dittrich, Birger Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811043202	journal	November 2011
Solvent-Driven Association and Dissociation of the Hydrogen-Bonded Protonated Decavanadates Kojima, Tatsuhiro; Antonio, Mark R.; Ozeki, Tomoji Journal of the American Chemical Society, Vol. 133, Issue 19 https://doi.org/10.1021/ja110781f	journal	May 2011
Reactivity of a Chloride Decorated, Mixed Valent Ce^III/IV₃₈–Oxo Cluster Wacker, Jennifer N.; Ditter, Alexander S.; Cary, Samantha K. Inorganic Chemistry, Vol. 61, Issue 1 https://doi.org/10.1021/acs.inorgchem.1c02705	journal	December 2021
Biomimetic nanomaterials: Development of protein coated nanoceria as a potential antioxidative nano-agent for the effective scavenging of reactive oxygen species in vitro and in zebrafish model Bhushan, Bharat; Nandhagopal, Soundharapandiyan; Rajesh Kannan, Rajaretinam Colloids and Surfaces B: Biointerfaces, Vol. 146 https://doi.org/10.1016/j.colsurfb.2016.06.035	journal	October 2016
Multiparameter High-Throughput and in Situ X-ray Diffraction Study of Six New Bismuth Sulfonatocarboxylates: Discovery, Phase Transformation, and Reaction Trends Albat, Martin; Stock, Norbert Inorganic Chemistry, Vol. 57, Issue 16 https://doi.org/10.1021/acs.inorgchem.8b01563	journal	August 2018
Bond-valence parameters for solids Brese, N. E.; O'Keeffe, M. Acta Crystallographica Section B Structural Science, Vol. 47, Issue 2 https://doi.org/10.1107/S0108768190011041	journal	April 1991
Controlled Redox Chemistry at Cerium within a Tripodal Nitroxide Ligand Framework Bogart, Justin A.; Lippincott, Connor A.; Carroll, Patrick J. Chemistry - A European Journal, Vol. 21, Issue 49 https://doi.org/10.1002/chem.201502952	journal	October 2015
Catalytic Influence of Various Cerium Precursors on the Hydrogen Sorption Properties of NaAlH4 Hu, Jianjiang; Ren, Shuhua; Witter, Raiker Advanced Energy Materials, Vol. 2, Issue 5 https://doi.org/10.1002/aenm.201100724	journal	March 2012
Two hexanuclear lanthanide Ln₆^III clusters featuring remarkable magnetocaloric effect and slow magnetic relaxation behavior Wang, Wen-Min; Xue, Cai-Long; Jing, Ru-Yi New Journal of Chemistry, Vol. 44, Issue 41 https://doi.org/10.1039/D0NJ03442H	journal	January 2020
Cerium oxide nanoclusters: commensurate with concepts of polyoxometalate chemistry? Malaestean, Iurii L.; Ellern, Arkady; Baca, Svetlana Chem. Commun., Vol. 48, Issue 10 https://doi.org/10.1039/C1CC14725K	journal	January 2012
Structures and Properties of Porous Coordination Polymers Based on Lanthanide Carboxylate Building Units Han, Yinfeng; Li, Xiaoyan; Li, Liqing Inorganic Chemistry, Vol. 49, Issue 23 https://doi.org/10.1021/ic902194g	journal	October 2010
Luminescence spectroscopy of europium(III) and terbium(III) penta-, octa- and nonanuclear clusters with β-diketonate ligands Petit, Sarah; Baril-Robert, François; Pilet, Guillaume Dalton Transactions, Issue 34 https://doi.org/10.1039/b822883c	journal	January 2009
Synthesis, Crystal Structure, and Thermal Behavior of Cerium(IV) Oxide Nitrate Ce2O(NO3)6(H2O)6 · 2H2O Guillou, N.; Auffrédic, J. P.; Louër, D. Journal of Solid State Chemistry, Vol. 112, Issue 1 https://doi.org/10.1006/jssc.1994.1262	journal	September 1994
Synthesis and Structural Characterization of a Series of Carboxylic Acid Modified Cerium(III) Alkoxides Boyle, Timothy J.; Tribby, Louis J.; Bunge, Scott D. European Journal of Inorganic Chemistry, Vol. 2006, Issue 22 https://doi.org/10.1002/ejic.200600616	journal	November 2006
Ratiometric fluorescent Zn²⁺and In³⁺receptors of fused pyrazine with an aminopropanol chain in acetonitrile Ostrowska, Katarzyna; Kaźmierska, Alicja; Rąpała-Kozik, Maria New J. Chem., Vol. 38, Issue 1 https://doi.org/10.1039/C3NJ00750B	journal	January 2014
Chemical mechanical glass polishing with cerium oxide: Effect of selected physico-chemical characteristics on polishing efficiency Janoš, Pavel; Ederer, Jakub; Pilařová, Věra Wear, Vol. 362-363 https://doi.org/10.1016/j.wear.2016.05.020	journal	September 2016
Colloid-Facilitated Transport of Plutonium at the Nevada Test Site, NV, USA Kersting, Annie B.; Zavarin, Mavrik Actinide Nanoparticle Research https://doi.org/10.1007/978-3-642-11432-8_15	book	January 2011
An improved laboratory-based x-ray absorption fine structure and x-ray emission spectrometer for analytical applications in materials chemistry research Jahrman, Evan P.; Holden, William M.; Ditter, Alexander S. Review of Scientific Instruments, Vol. 90, Issue 2 https://doi.org/10.1063/1.5049383	journal	February 2019
Identification of a physical metallurgy surrogate for the plutonium—1 wt. % gallium alloy Gibbs, Frank E. Plutonium futures-The science (Topical conference on Plutonium and actinides), AIP Conference Proceedings https://doi.org/10.1063/1.1292217	conference	January 2000
Emergence of Thorium-Based Polyoxo Clusters as a Platform for Selective X-ray Dosimetry Lu, Huangjie; Xu, Miaomiao; Zheng, Zhaofa Inorganic Chemistry, Vol. 60, Issue 24 https://doi.org/10.1021/acs.inorgchem.1c03182	journal	December 2021
Unveiling the Unique Roles of Metal Coordination and Modulator in the Polymorphism Control of Metal‐Organic Frameworks Li, Zi‐Jian; Ju, Yu; Zhang, Zeya Chemistry – A European Journal, Vol. 27, Issue 70 https://doi.org/10.1002/chem.202103062	journal	November 2021
Stabilization of Tetravalent 4f (Ce), 5d (Hf), or 5f (Th, U) Clusters by the [α-SiW ₉ O ₃₄ ] ^10– Polyoxometalate Duval, Sylvain; Béghin, Sébastien; Falaise, Clément Inorganic Chemistry, Vol. 54, Issue 17 https://doi.org/10.1021/acs.inorgchem.5b00786	journal	August 2015
In situ synthesis of ceria nanoparticles in the ordered mesoporous carbon as a novel electrochemical sensor for the determination of hydrazine Liu, Yue; Li, Yijun; He, Xiwen Analytica Chimica Acta, Vol. 819 https://doi.org/10.1016/j.aca.2014.02.025	journal	March 2014
Ultraporous, Water Stable, and Breathing Zirconium-Based Metal–Organic Frameworks with ftw Topology Deria, Pravas; Gómez-Gualdrón, Diego A.; Bury, Wojciech Journal of the American Chemical Society, Vol. 137, Issue 40 https://doi.org/10.1021/jacs.5b08860	journal	September 2015
Extension of the Plutonium Oxide Nanocluster Family to Include {Pu ₁₆ } and {Pu ₂₂ } Sigmon, Ginger E.; Hixon, Amy E. Chemistry - A European Journal, Vol. 25, Issue 10 https://doi.org/10.1002/chem.201805605	journal	January 2019
Cerium(IV) Hexanuclear Clusters from Cerium(III) Precursors: Molecular Models for Oxidative Growth of Ceria Nanoparticles Mathey, Laurent; Paul, Mitali; Copéret, Christophe Chemistry - A European Journal, Vol. 21, Issue 38 https://doi.org/10.1002/chem.201501731	journal	July 2015
Mononuclear to Polynuclear U ^IV Structural Units: Effects of Reaction Conditions on U‐Furoate Phase Formation Vanagas, Nicole A.; Higgins, Robert F.; Wacker, Jennifer N. Chemistry – A European Journal, Vol. 26, Issue 26 https://doi.org/10.1002/chem.201905759	journal	April 2020
Irena : tool suite for modeling and analysis of small-angle scattering Ilavsky, Jan; Jemian, Peter R. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889809002222	journal	February 2009
Heterometallic Ce ^IV / V ^V Oxo Clusters with Adjustable Catalytic Reactivities Wang, Xingjie; Brunson, Kieran; Xie, Haomiao Journal of the American Chemical Society, Vol. 143, Issue 49 https://doi.org/10.1021/jacs.1c11208	journal	December 2021
The electronic structure of oxygen vacancy defects at the low index surfaces of ceria Nolan, Michael; Parker, Stephen C.; Watson, Graeme W. Surface Science, Vol. 595, Issue 1-3 https://doi.org/10.1016/j.susc.2005.08.015	journal	December 2005
Reaction of a tetranuclear N,N-di-iso-propylcarbamato complex of cerium(III) with dioxygen: synthesis and X-ray characterization of both the oxidation product and its precursor Baisch, U. Journal of Molecular Catalysis A: Chemical, Vol. 204-205 https://doi.org/10.1016/S1381-1169(03)00307-8	journal	September 2003
Experimental evidence of an electronic transition in CeP under pressure using Ce L 3 XAS Joseph, B.; Torchio, R.; Benndorf, C. Physical Chemistry Chemical Physics, Vol. 19, Issue 27 https://doi.org/10.1039/C7CP03022C	journal	January 2017
Ce(IV) Complexes with Donor-Functionalized Alkoxide Ligands: Improved Precursors for Chemical Vapor Deposition of CeO ₂ Aspinall, Helen C.; Bacsa, John; Jones, Anthony C. Inorganic Chemistry, Vol. 50, Issue 22 https://doi.org/10.1021/ic201593s	journal	November 2011
The Cambridge Structural Database Groom, Colin R.; Bruno, Ian J.; Lightfoot, Matthew P. Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 72, Issue 2, p. 171-179 https://doi.org/10.1107/S2052520616003954	journal	April 2016
One-dimensional chain structures of hexanuclear uranium( iv ) clusters bridged by formate ligands Ling, Jie; Lu, Huangjie; Wang, Yaxing RSC Advances, Vol. 8, Issue 61 https://doi.org/10.1039/C8RA06330C	journal	January 2018
Formation of Uranium(IV) Oxide Clusters from Uranocene [U(η ⁸ -C ₈ H ₈ ) ₂ ] and Uranyl [UO ₂ X ₂ ] Compounds Berthet, Jean-Claude; Thuéry, Pierre; Ephritikhine, Michel Inorganic Chemistry, Vol. 49, Issue 17 https://doi.org/10.1021/ic101310z	journal	September 2010
Crystal structure of dodecacerium heptadecaiodide triethanide, Ce12I17(C2)3 Mattausch, Hj.; Simon, A.; Hoch, C. Zeitschrift für Kristallographie - New Crystal Structures, Vol. 220, Issue 1-4 https://doi.org/10.1524/ncrs.2005.220.14.321	journal	April 2005
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
Plutonium(IV) Sequestration: Structural and Thermodynamic Evaluation of the Extraordinarily Stable Cerium(IV) Hydroxypyridinonate Complexes¹ Xu, Jide; Radkov, Emil; Ziegler, Marco Inorganic Chemistry, Vol. 39, Issue 18, p. 4156-4164 https://doi.org/10.1021/ic000063i	journal	September 2000
Nanostructured Cerium Oxide “Ecocatalysts” Flytzani-Stephanopoulos, Maria MRS Bulletin, Vol. 26, Issue 11 https://doi.org/10.1557/mrs2001.229	journal	November 2001
Crystal Structure and Solution Species of Ce(III) and Ce(IV) Formates: From Mononuclear to Hexanuclear Complexes Hennig, Christoph; Ikeda-Ohno, Atsushi; Kraus, Werner Inorganic Chemistry, Vol. 52, Issue 20 https://doi.org/10.1021/ic400999j	journal	September 2013
Ferromagnetic quantum critical point in CePd 2 P 2 with Pd → Ni substitution Lai, Y.; Bone, S. E.; Minasian, S. Physical Review B, Vol. 97, Issue 22 https://doi.org/10.1103/PhysRevB.97.224406	journal	June 2018
Present Status of Cerium(IV)-Cerium(III) Potentials Wadsworth, Earl.; Duke, F. R.; Goetz, C. A. Analytical Chemistry, Vol. 29, Issue 12 https://doi.org/10.1021/ac60132a046	journal	December 1957
Self-Contained Kondo Effect in Single Molecules Booth, C. H.; Walter, M. D.; Daniel, M. Physical Review Letters, Vol. 95, Issue 26 https://doi.org/10.1103/PhysRevLett.95.267202	journal	December 2005
Cerium-oxo clusters for photocatalytic aerobic oxygenation of sulfides to sulfoxides Lv, Xinjie; Zhao, Xiao-li; Zhao, Qixin Dalton Transactions, Vol. 51, Issue 23 https://doi.org/10.1039/D2DT00856D	journal	January 2022
Crystallographic and Spectroscopic Investigations on Oxidative Coordination in the Heteroleptic Mononuclear Complex of Cerium and Benzoxazine Dimer Wattanathana, Worawat; Suetrong, Natapol; Kongsamai, Peetikamol Molecules, Vol. 26, Issue 17 https://doi.org/10.3390/molecules26175410	journal	September 2021
X-ray diffraction "fingerprinting" of DNA structure in solution for quantitative evaluation of molecular dynamics simulation Zuo, X.; Cui, G.; Merz, K. M. Proceedings of the National Academy of Sciences, Vol. 103, Issue 10 https://doi.org/10.1073/pnas.0600022103	journal	February 2006
Fluorite-like hydrolyzed hexanuclear coordination clusters of Zr(IV) and Hf(IV) with syn-syn bridging N,N,N-trimethylglycine in soft crystal structures exhibiting cold-crystallization Matsuoka, Moe; Tsushima, Satoru; Takao, Koichiro Inorganica Chimica Acta, Vol. 528 https://doi.org/10.1016/j.ica.2021.120622	journal	December 2021
To form or not to form: PuO₂ nanoparticles at acidic pH Gerber, Evgeny; Romanchuk, Anna Yu.; Weiss, Stephan Environmental Science: Nano, Vol. 9, Issue 4 https://doi.org/10.1039/D1EN00666E	journal	January 2022
The extended chain compounds Ln12(C2)3I17 (Ln=Pr, Nd, Gd, Dy): Synthesis, structure and physical properties Ryazanov, Mikhail; Mattausch, Hansjürgen; Simon, Arndt Journal of Solid State Chemistry, Vol. 180, Issue 4 https://doi.org/10.1016/j.jssc.2007.01.029	journal	April 2007
Effect of solvation on the intrinsic relative acidity of methanol and ethanol McIver, Robert T.; Scott, Judith A.; Riveros, Jose M. Journal of the American Chemical Society, Vol. 95, Issue 8 https://doi.org/10.1021/ja00789a061	journal	April 1973
Specific intermediate-valence state of insulating 4 f compounds detected by L 3 x-ray absorption Bianconi, A.; Marcelli, A.; Dexpert, H. Physical Review B, Vol. 35, Issue 2 https://doi.org/10.1103/PhysRevB.35.806	journal	January 1987
Anionic Bismuth-Oxido Carboxylate Clusters with Transition Metal Countercations Loera Fernandez, Ismael I.; Donaldson, Samantha L.; Schipper, Desmond E. Inorganic Chemistry, Vol. 55, Issue 21 https://doi.org/10.1021/acs.inorgchem.6b02092	journal	October 2016
Colloid Transport of Plutonium in the Far-Field of the Mayak Production Association, Russia Novikov, A. P.; Kalmykov, S. N.; Utsunomiya, S. Science, Vol. 314, Issue 5799 https://doi.org/10.1126/science.1131307	journal	October 2006
Coordination-Driven Self-Assembly of a 2D Graphite-Like Framework Constructed from High-Nuclear Ce ₁₀ Cluster Encapsulated Polyoxotungstates Ma, Pengtao; Wan, Rong; Wang, Yueyan Inorganic Chemistry, Vol. 55, Issue 2 https://doi.org/10.1021/acs.inorgchem.5b02473	journal	January 2016
Cerium acetylacetonates—new aspects, including the lamellar clathrate [Ce(acac)4]·10H2O Behrsing, Thomas; Bond, Alan M.; Deacon, Glen B. Inorganica Chimica Acta, Vol. 352 https://doi.org/10.1016/S0020-1693(03)00147-6	journal	August 2003
Phosphorus-based ligand effects on the structure and radical scavenging ability of molecular nanoparticles of CeO₂ Russell-Webster, Bradley; Lopez-Nieto, Javi; Abboud, Khalil A. Dalton Transactions, Vol. 50, Issue 43 https://doi.org/10.1039/D1DT02667D	journal	January 2021
Supramolecular Porous Assemblies of Atomically Precise Catalytically Active Cerium-Based Clusters Wasson, Megan C.; Zhang, Xuan; Otake, Ken-ichi Chemistry of Materials, Vol. 32, Issue 19 https://doi.org/10.1021/acs.chemmater.0c02740	journal	September 2020
Synthesis of a large dodecameric cerium cluster stabilized by the [SiW9O34]10− polyoxometalate Duval, Sylvain; Roussel, Pascal; Loiseau, Thierry Inorganic Chemistry Communications, Vol. 83 https://doi.org/10.1016/j.inoche.2017.06.015	journal	September 2017
Efficient Oxidative Cleavage of 1,3‐Dicarbonyl Derivatives with Hydrogen Peroxide Catalyzed by Quaternary Ammonium Iodide Yuan, Yu; Ji, Xiang; Zhao, Dongbo European Journal of Organic Chemistry, Vol. 2010, Issue 27 https://doi.org/10.1002/ejoc.201000666	journal	July 2010
Base-Driven Assembly of Large Uranium Oxo/Hydroxo Clusters Biswas, Biplab; Mougel, Victor; Pécaut, Jacques Angewandte Chemie International Edition, Vol. 50, Issue 25 https://doi.org/10.1002/anie.201101327	journal	May 2011
{Ce ₁₀ Mn ₈ }: Cerium Analogues of the Decavanadate Archetype Malaestean, Iurie L.; Ellern, Arkady; Kögerler, Paul European Journal of Inorganic Chemistry, Vol. 2013, Issue 10-11 https://doi.org/10.1002/ejic.201201247	journal	November 2012
A pseudo-icosahedral cage {Gd₁₂} based on aminomethylphosphonate Zhang, Ze-Min; Zangana, Karzan H.; Kostopoulos, Andreas K. Dalton Transactions, Vol. 45, Issue 22 https://doi.org/10.1039/C6DT00876C	journal	January 2016
Coordination of Tetravalent Actinides (An=Th ^IV , U ^IV , Np ^IV , Pu ^IV ) with DOTA: From Dimers to Hexamers Tamain, Christelle; Dumas, Thomas; Hennig, Christoph Chemistry - A European Journal, Vol. 23, Issue 28 https://doi.org/10.1002/chem.201700493	journal	April 2017
Systematic Structural Coordination Chemistry ofp‐tert‐Butyltetrathiacalix[4]arene: Further Complexes of Lanthanide Metal Ions Bilyk, Alexander; Dunlop, John W.; Fuller, Rebecca O. European Journal of Inorganic Chemistry, Vol. 2010, Issue 14 https://doi.org/10.1002/ejic.200901070	journal	April 2010
Mn^II/III and Ce^III/IV Units Supported on an Octahedral Molecular Nanoparticle of CeO₂ Das Gupta, Sayak; Thuijs, Annaliese E.; Fisher, Ethan G. Inorganic Chemistry, Vol. 61, Issue 17 https://doi.org/10.1021/acs.inorgchem.1c03719	journal	February 2022
Kinetics and mechanism of the oxidation of acetylacetone by permanganate ion Jáky, Miklós; Szammer, János; Simon-Trompler, Edit International Journal of Chemical Kinetics, Vol. 38, Issue 7 https://doi.org/10.1002/kin.20177	journal	July 2006
Retrosynthesis of multi-component metal−organic frameworks Yuan, Shuai; Qin, Jun-Sheng; Li, Jialuo Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03102-5	journal	February 2018
Molecular nanoparticles of cerium dioxide: structure-directing effect of halide ions Russell-Webster, Bradley; Abboud, Khalil A.; Christou, George Chemical Communications, Vol. 56, Issue 40 https://doi.org/10.1039/C9CC08419C	journal	January 2020
Recent Developments in the Methods and Applications of the Bond Valence Model Brown, Ian David Chemical Reviews, Vol. 109, Issue 12 https://doi.org/10.1021/cr900053k	journal	December 2009
Atomically-precise colloidal nanoparticles of cerium dioxide Mitchell, Kylie J.; Abboud, Khalil A.; Christou, George Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01672-4	journal	November 2017
Mono-, Di-, and Trimetallic Methacrylate-substituted Metal Oxide Clusters Derived from Hafnium Butoxide Kickelbick, Guido; Puchberger, Michael; Schubert, Ulrich Monatshefte f�r Chemie / Chemical Monthly, Vol. 134, Issue 8 https://doi.org/10.1007/s00706-003-0031-3	journal	August 2003
Plutonium(IV) Cluster with a Hexanuclear [Pu ₆ (OH) ₄ O ₄ ] ¹²⁺ Core Knope, Karah E.; Soderholm, L. Inorganic Chemistry, Vol. 52, Issue 12 https://doi.org/10.1021/ic4007185	journal	May 2013
A Novel Water‐Soluble Hexanuclear Bismuth Oxido Cluster – Synthesis, Structure and Complexation with Polyacrylate Miersch, Linda; Rüffer, Tobias; Lang, Heinrich European Journal of Inorganic Chemistry, Vol. 2010, Issue 30 https://doi.org/10.1002/ejic.201000753	journal	September 2010
Effective ionic radii in oxides and fluorides Shannon, R. D.; Prewitt, C. T. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 25, Issue 5 https://doi.org/10.1107/S0567740869003220	journal	May 1969
The crystal structure of cerium(IV) acetylacetonate Matković, B.; Grdenić, D. Acta Crystallographica, Vol. 16, Issue 6 https://doi.org/10.1107/S0365110X63001286	journal	June 1963
Synthesis, Structure, and Magnetism of a Family of Heterometallic {Cu₂Ln₇} and {Cu₄Ln₁₂} (Ln = Gd, Tb, and Dy) Complexes: The Gd Analogues Exhibiting a Large Magnetocaloric Effect Langley, Stuart K.; Moubaraki, Boujemaa; Tomasi, Corrado Inorganic Chemistry, Vol. 53, Issue 24 https://doi.org/10.1021/ic5023467	journal	November 2014
Ligand K-edge X-ray absorption spectroscopy: covalency of ligand–metal bonds Solomon, Edward I.; Hedman, Britt; Hodgson, Keith O. Coordination Chemistry Reviews, Vol. 249, Issue 1-2 https://doi.org/10.1016/j.ccr.2004.03.020	journal	January 2005
Synthesis of two new Hf‐MOFs with UiO‐66 and CAU‐22 structure employing 2,5‐pyrazinedicarboxylic acid as linker molecule. Poschmann, Mirjam P. M.; Waitschat, Steve; Reinsch, Helge Zeitschrift für anorganische und allgemeine Chemie, Vol. 647, Issue 22 https://doi.org/10.1002/zaac.202100184	journal	August 2021

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