Revealing the closed pore formation of waste wood-derived hard carbon for advanced sodium-ion battery

Tang, Zheng; Zhang, Rui; Wang, Haiyan; Zhou, Siyu; Pan, Zhiyi; Huang, Yuancheng; Sun, Dan; Tang, Yougen; Ji, Xiaobo; Amine, Khalil; Shao, Minhua

doi:10.1038/s41467-023-39637-5

Title: Revealing the closed pore formation of waste wood-derived hard carbon for advanced sodium-ion battery

Journal Article · 27 September 2023 · Nature Communications

DOI: https://doi.org/10.1038/s41467-023-39637-5 · OSTI ID:2006683

Tang, Zheng; Zhang, Rui;

; Zhou, Siyu; Pan, Zhiyi; Huang, Yuancheng;

; Tang, Yougen; Ji, Xiaobo;

;

Abstract Although the closed pore structure plays a key role in contributing low-voltage plateau capacity of hard carbon anode for sodium-ion batteries, the formation mechanism of closed pores is still under debate. Here, we employ waste wood-derived hard carbon as a template to systematically establish the formation mechanisms of closed pores and their effect on sodium storage performance. We find that the high crystallinity cellulose in nature wood decomposes to long-range carbon layers as the wall of closed pore, and the amorphous component can hinder the graphitization of carbon layer and induce the crispation of long-range carbon layers. The optimized sample demonstrates a high reversible capacity of 430 mAh g ⁻¹ at 20 mA g ⁻¹ (plateau capacity of 293 mAh g ⁻¹ for the second cycle), as well as good rate and stable cycling performances (85.4% after 400 cycles at 500 mA g ⁻¹ ). Deep insights into the closed pore formation will greatly forward the rational design of hard carbon anode with high capacity.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2006683

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 14; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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