XFEL Microcrystallography of Self-Assembling Silver n-Alkanethiolates

Aleksich, Mariya; Paley, Daniel W.; Schriber, Elyse A.; Linthicum, Will; Oklejas, Vanessa; Mittan-Moreau, David W.; Kelly, Ryan P.; Kotei, Patience A.; Ghodsi, Anita; Sierra, Raymond G.; Aquila, Andrew; Poitevin, Frédéric; Blaschke, Johannes P.; Vakili, Mohammad; Milne, Christopher J.; Dall’Antonia, Fabio; Khakhulin, Dmitry; Ardana-Lamas, Fernando; Lima, Frederico; Valerio, Joana; Han, Huijong; Gallo, Tamires; Yousef, Hazem; Turkot, Oleksii; Bermudez Macias, Ivette J.; Kluyver, Thomas; Schmidt, Philipp; Gelisio, Luca; Round, Adam R.; Jiang, Yifeng; Vinci, Doriana; Uemura, Yohei; Kloos, Marco; Hunter, Mark; Mancuso, Adrian P.; Huey, Bryan D.; Parent, Lucas R.; Sauter, Nicholas K.; Brewster, Aaron S.; Hohman, J. Nathan

doi:10.1021/jacs.3c02183

Title: XFEL Microcrystallography of Self-Assembling Silver n-Alkanethiolates

Journal Article · 30 July 2023 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.3c02183 · OSTI ID:2001516

^[1]; Paley, Daniel W. ^[2]; Schriber, Elyse A. ^[3]; Linthicum, Will ^[3]; Oklejas, Vanessa ^[2]; Mittan-Moreau, David W. ^[2]; Kelly, Ryan P. ^[3];

^[3]; Ghodsi, Anita ^[3]; Sierra, Raymond G. ^[4]; Aquila, Andrew ^[4]; Poitevin, Frédéric ^[4]; Blaschke, Johannes P. ^[5];

^[6]; Milne, Christopher J. ^[6]; Dall’Antonia, Fabio ^[6]; Khakhulin, Dmitry ^[6]; Ardana-Lamas, Fernando ^[6]; Lima, Frederico ^[6]; Valerio, Joana ^[6] more »

Univ. of Connecticut, Storrs, CT (United States); SLAC
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Univ. of Connecticut, Storrs, CT (United States)
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States). Linac Coherent Light Source (LCLS)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)
European XFEL, Schenefeld (Germany)
European XFEL, Schenefeld (Germany); Lund Univ. (Sweden)
European XFEL, Schenefeld (Germany); La Trobe Univ., Melbourne, VIC (Australia); Science and Technology Facilities Council (STFC), Oxford (United Kingdom). Diamond Light Source, Ltd.

New synthetic hybrid materials and their increasing complexity have placed growing demands on crystal growth for single-crystal X-ray diffraction analysis. Unfortunately, not all chemical systems are conducive to the isolation of single crystals for traditional characterization. Here, small-molecule serial femtosecond crystallography (smSFX) at atomic resolution (0.833 Å) is employed to characterize microcrystalline silver n-alkanethiolates with various alkyl chain lengths at X-ray free electron laser facilities, resolving long-standing controversies regarding the atomic connectivity and odd–even effects of layer stacking. smSFX provides high-quality crystal structures directly from the powder of the true unknowns, a capability that is particularly useful for systems having notoriously small or defective crystals. We present crystal structures of silver n-butanethiolate (C4), silver n-hexanethiolate (C6), and silver n-nonanethiolate (C9). We show that an odd–even effect originates from the orientation of the terminal methyl group and its role in packing efficiency. We also propose a secondary odd–even effect involving multiple mosaic blocks in the crystals containing even-numbered chains, identified by selected-area electron diffraction measurements. Finally, we conclude with a discussion of the merits of the synthetic preparation for the preparation of microdiffraction specimens and compare the long-range order in these crystals to that of self-assembled monolayers.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: National Institutes of Health (NIH); USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231; AC02-06CH11357; AC02-76SF00515; SC0022215

OSTI ID:: 2001516

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 31 Vol. 145; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited By (1)

Microcrystallography of the Self-Assembling Silver (I) n-Alkanethiolates Aleksich, Aleksich; Paley, Paley; Schriber, Schriber Coherent X-ray Imaging Data Bank (Lawrence Berkeley National Laboratory); LBNL https://doi.org/10.11577/1993555	dataset	January 2023

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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