Investigation of the effects of ternary deep eutectic solvent composition on pretreatment of sorghum stover

Wang, Yunxuan; Ryu, Jiae; Kim, Kwang Ho; Meng, Xianzhi; Pu, Yunqiao; Tian, Yang; Eudes, Aymerick; Leem, Gyu; Ragauskas, Arthur J.; Yoo, Chang Geun

doi:10.1002/aic.18227

Title: Investigation of the effects of ternary deep eutectic solvent composition on pretreatment of sorghum stover

Journal Article · 27 August 2023 · AIChE Journal

DOI: https://doi.org/10.1002/aic.18227 · OSTI ID:2001380

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State Univ. of New York (SUNY), Syracuse, NY (United States). College of Environmental Science and Forestry; Univ. of Tennessee, Knoxville, TN (United States)
State Univ. of New York (SUNY), Syracuse, NY (United States). College of Environmental Science and Forestry
Korea Inst. of Science and Technology, Seoul (Korea, Republic of)
Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Joint BioEnergy Institute (JBEI), Emeryville, CA (United States)
State Univ. of New York (SUNY), Syracuse, NY (United States). College of Environmental Science and Forestry; The Michael M. Szwarc Polymer Research Inst., Syracuse, NY (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Biomass‐derived deep eutectic solvents (DESs) have been introduced as promising pretreatment and fractionation solvents because of their mild processing conditions, easy synthesis, and green solvent components from biomass. In recent DES studies, solvent‐based third constituents like water, ethanol, and others improve the processibility of typical binary DESs. However, the impacts of these components are not well understood. Here, two solvent‐based constituents, including water and ethylene glycol, were applied to 3,4‐dihydroxybenzoic acid (DHBA)‐based DES system for improving the conversion efficiency of cellulose‐rich fraction and the properties of lignin fraction. Chemical composition, enzymatic digestibility, degree of polymerization of cellulose and physicochemical properties of lignin were used to evaluate the impact of each third constituent on biomass processing. Ternary ChCl‐DHBA DESs exhibited better performances in delignification, fermentable sugar production, and preservation of β‐O‐4 ether linkage in lignin compared with binary ChCl‐DHBA DES.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC02-05CH11231; AC05-00OR22725

OSTI ID:: 2001380

Journal Information:: AIChE Journal, Journal Name: AIChE Journal Journal Issue: TBD Vol. TBD; ISSN 0001-1541

Publisher:: American Institute of Chemical EngineersCopyright Statement

Country of Publication:: United States

Language:: English

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09 BIOMASS FUELS
3
4-dihydroxybenzoic acid
engineered plant
pretreatment
sorghum stover
ternary deep eutectic solvent

Title: Investigation of the effects of ternary deep eutectic solvent composition on pretreatment of sorghum stover

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