Room temperature polar and weak-ferromagnetic oxide with low dielectric loss

Katragadda, Nagamalleswari; Mandal, Pranab; Yanda, Premakumar; Sundaresan, A.; Kaushik, S. D.; Zhang, Weiguo; Shiv Halasyamani, P.; Manjón-Sanz, Alicia María

doi:10.1016/j.mseb.2023.116869

Title: Room temperature polar and weak-ferromagnetic oxide with low dielectric loss

Journal Article · 15 September 2023 · Materials Science and Engineering. B, Solid-State Materials for Advanced Technology

DOI: https://doi.org/10.1016/j.mseb.2023.116869 · OSTI ID:2001371

Katragadda, Nagamalleswari ^[1];

^[1]; Yanda, Premakumar ^[2]; Sundaresan, A. ^[2]; Kaushik, S. D. ^[3]; Zhang, Weiguo ^[4]; Shiv Halasyamani, P. ^[4]; Manjón-Sanz, Alicia María ^[5]

SRM University-AP, Andhra Pradesh (India)
Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Jakkur, Bangalore (India)
UGC-DAE Consortium for Scientific Research Mumbai Centre, Mumbai (India)
Univ. of Houston, TX (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Single-phase materials that are simultaneously ferroelectric and ferromagnetic at room temperature are promising for devices such as non-volatile random-access memory. Perovskite BiFeO₃ which crystallizes in the polar rhombohedral structure (R3c) is ferroelectric and antiferromagnetic at room temperature. Here, we report a family of perovskite oxides in the BiFeO₃ – Bi_2/3TiO₃ – ATiO₃ (where A²⁺ is divalent alkaline earth metal ions e.g., Ca²⁺, Sr²⁺, Ba²⁺) ternary phase diagram that is polar as well as weak ferromagnetic above room temperature. The composition (Bi_0.9167A_0.075)(Fe_0.9Ti_0.1)O₃ crystallizes in the polar rhombohedral structure space group R3c as corroborated by powder X-ray and neutron diffraction analysis. The nearly pure A-site perovskite possesses a long-range magnetic ordering above room temperature. Finally, these perovskites show a low dielectric loss, and the electrical response is dominated by grain contributions below 723 K.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC); Science and Engineering Research Board (SERB), India; Welch Foundation; National Science Foundation (NSF)

Grant/Contract Number:: AC05-00OR22725; ECR/2018/001252; E-1457; DMR-2002319

OSTI ID:: 2001371

Journal Information:: Materials Science and Engineering. B, Solid-State Materials for Advanced Technology, Vol. 298; ISSN 0921-5107

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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perovskites
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weak ferromagnetic
polar
impedance
spectroscopy

Title: Room temperature polar and weak-ferromagnetic oxide with low dielectric loss

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