Evidence of Long-Range and Short-Range Magnetic Ordering in the Honeycomb Na3Mn2SbO6 Oxide

Yadav, Dileep Kumar; Zhang, Qiang; Gofryk, Krzysztof; Nair, Harikrishnan S.; Uma, Sitharaman

doi:10.1021/acs.inorgchem.3c00666

Title: Evidence of Long-Range and Short-Range Magnetic Ordering in the Honeycomb Na₃Mn₂SbO₆ Oxide

Journal Article · 03 May 2023 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.3c00666 · OSTI ID:2000319

Yadav, Dileep Kumar ^[1];

^[2];

^[3];

^[4];

^[1]

Univ. of Delhi, New Delhi (India)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Idaho National Laboratory (INL), Idaho Falls, ID (United States)
Univ. of Texas at El Paso, TX (United States)

We present a comprehensive study of the synthesis, structure, and magnetic properties of the honeycomb oxide Na₃Mn₂SbO₆ supported by neutron diffraction, heat capacity, and magnetization measurements. The refinements of the neutron diffraction patterns (150, 50, and 45 K) using the Rietveld method confirm the monoclinic (S. G. C2/m) structure. Temperature-dependent magnetic susceptibilities measured at varying fields along with the heat capacity measurements demonstrate the coexistence of long-range ordering (∼42 K) and short-range ordering (∼65 K). The field-dependent isothermal magnetization measurements at 5 K indicate a spin-flop transition around 5 T. Rietveld refinements of the low-temperature (below 45 K) neutron diffraction data further confirm the long-range magnetic ordering. In addition, the temperature variation of the lattice parameters obtained from the neutron powder diffraction analysis exhibited a distinct anomaly near the antiferromagnetic transition temperature. The appearance of the concomitant broadened backgrounds in the neutron powder diffraction data collected at 80, 50, and 45 K supports the short-range ordering. The resultant magnetic structure consists of spins that are aligned antiparallel with the nearest neighbors and also with the spins of the adjacent honeycomb layers. The occurrence of a fully ordered magnetic ground state (Neel antiferromagnetic (AFM)) in Na3Mn₂SbO₆ consolidates the significance of fabricating new honeycomb oxides.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: SERB (Govt. of India); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES); University of Delhi

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2000319

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 19 Vol. 62; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Layers
Neutron diffraction
Oxides
Quantum mechanics
Transition metals

Title: Evidence of Long-Range and Short-Range Magnetic Ordering in the Honeycomb Na3Mn2SbO6 Oxide

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