Evidence of Long-Range and Short-Range Magnetic Ordering in the Honeycomb Na3Mn2SbO6 Oxide

Yadav, Dileep Kumar; Zhang, Qiang; Gofryk, Krzysztof; Nair, Harikrishnan S.; Uma, Sitharaman

doi:10.1021/acs.inorgchem.3c00666

Title: Evidence of Long-Range and Short-Range Magnetic Ordering in the Honeycomb Na₃Mn₂SbO₆ Oxide

Journal Article · 04 May 2023 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.3c00666 · OSTI ID:2000319

Yadav, Dileep Kumar ^[1];

^[2];

^[3];

^[4];

^[1]

Univ. of Delhi, New Delhi (India)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Idaho National Laboratory (INL), Idaho Falls, ID (United States)
Univ. of Texas at El Paso, TX (United States)

We present a comprehensive study of the synthesis, structure, and magnetic properties of the honeycomb oxide Na₃Mn₂SbO₆ supported by neutron diffraction, heat capacity, and magnetization measurements. The refinements of the neutron diffraction patterns (150, 50, and 45 K) using the Rietveld method confirm the monoclinic (S. G. C2/m) structure. Temperature-dependent magnetic susceptibilities measured at varying fields along with the heat capacity measurements demonstrate the coexistence of long-range ordering (∼42 K) and short-range ordering (∼65 K). The field-dependent isothermal magnetization measurements at 5 K indicate a spin-flop transition around 5 T. Rietveld refinements of the low-temperature (below 45 K) neutron diffraction data further confirm the long-range magnetic ordering. In addition, the temperature variation of the lattice parameters obtained from the neutron powder diffraction analysis exhibited a distinct anomaly near the antiferromagnetic transition temperature. The appearance of the concomitant broadened backgrounds in the neutron powder diffraction data collected at 80, 50, and 45 K supports the short-range ordering. The resultant magnetic structure consists of spins that are aligned antiparallel with the nearest neighbors and also with the spins of the adjacent honeycomb layers. The occurrence of a fully ordered magnetic ground state (Neel antiferromagnetic (AFM)) in Na3Mn₂SbO₆ consolidates the significance of fabricating new honeycomb oxides.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES); SERB (Govt. of India); University of Delhi

Grant/Contract Number:: AC05-00OR22725; CRG/2021/003714; IoE/2021/12/FRP

OSTI ID:: 2000319

Journal Information:: Inorganic Chemistry, Vol. 62, Issue 19; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (56)

Crystal structure of Li4ZnTeO6 and revision of Li3Cu2SbO6 Nalbandyan, V. B.; Avdeev, M.; Evstigneeva, M. A. Journal of Solid State Chemistry, Vol. 199 https://doi.org/10.1016/j.jssc.2012.11.027	journal	March 2013
Li4NiTeO6 as a positive electrode for Li-ion batteries Sathiya, M.; Ramesha, K.; Rousse, G. Chemical Communications, Vol. 49, Issue 97 https://doi.org/10.1039/c3cc46842a	journal	January 2013
Static and Dynamic Magnetic Response of Fragmented Haldane-like Spin Chains in Layered Li ₃ Cu ₂ SbO ₆ Koo, Changhyun; Zvereva, Elena A.; Shukaev, Igor L. Journal of the Physical Society of Japan, Vol. 85, Issue 8 https://doi.org/10.7566/JPSJ.85.084702	journal	August 2016
Structure and Magnetic Properties of Cu ₃ Ni ₂ SbO ₆ and Cu ₃ Co ₂ SbO ₆ Delafossites with Honeycomb Lattices Roudebush, J. H.; Andersen, N. H.; Ramlau, R. Inorganic Chemistry, Vol. 52, Issue 10 https://doi.org/10.1021/ic400415h	journal	April 2013
Anomalous Ferromagnetic Behavior in Orthorhombic Li₃Co₂SbO₆ Duan, Qianhui; Bu, Huanpeng; Pomjakushin, Vladimir Inorganic Chemistry, Vol. 61, Issue 28 https://doi.org/10.1021/acs.inorgchem.2c01293	journal	July 2022
Structure and basic magnetic properties of the honeycomb lattice compounds Na2Co2TeO6 and Na3Co2SbO6 Viciu, L.; Huang, Q.; Morosan, E. Journal of Solid State Chemistry, Vol. 180, Issue 3 https://doi.org/10.1016/j.jssc.2007.01.002	journal	March 2007
Zigzag antiferromagnetic quantum ground state in monoclinic honeycomb lattice antimonates A 3 N i 2 Sb O 6 ( A = Li , Na ) Zvereva, E. A.; Stratan, M. I.; Ovchenkov, Y. A. Physical Review B, Vol. 92, Issue 14 https://doi.org/10.1103/PhysRevB.92.144401	journal	October 2015
A review of cation-ordered rock salt superstructure oxides Mather, Glenn C.; Dussarrat, Christian; Etourneau, Jean Journal of Materials Chemistry, Vol. 10, Issue 10 https://doi.org/10.1039/b000817f	journal	January 2000
Honeycomb Compound Na₃Ni₂BiO₆as Positive Electrode Material in Na Cells Zheng, Lituo; Obrovac, M. N. Journal of The Electrochemical Society, Vol. 163, Issue 10 https://doi.org/10.1149/2.0991610jes	journal	January 2016
Spin-Gap Behavior of Na ₃ Cu ₂ SbO ₆ with Distorted Honeycomb Structure Miura, Yoko; Hirai, Riu; Kobayashi, Yoshiaki Journal of the Physical Society of Japan, Vol. 75, Issue 8 https://doi.org/10.1143/JPSJ.75.084707	journal	August 2006
Na 2 Ni 2 TeO 6 : Evaluation as a cathode for sodium battery Gupta, Asha; Buddie Mullins, C.; Goodenough, John B. Journal of Power Sources, Vol. 243 https://doi.org/10.1016/j.jpowsour.2013.06.073	journal	December 2013
Nuclear and incommensurate magnetic structure of NaFeGe2O6 between 5 K and 298 K and new data on multiferroic NaFeSi2O6 Redhammer, Günther J.; Senyshyn, Anatoliy; Meven, Martin Physics and Chemistry of Minerals, Vol. 38, Issue 2 https://doi.org/10.1007/s00269-010-0390-3	journal	August 2010
New P2-Type Honeycomb-Layered Sodium-Ion Conductor: Na₂Mg₂TeO₆ Li, Yuyu; Deng, Zhi; Peng, Jian ACS Applied Materials & Interfaces, Vol. 10, Issue 18 https://doi.org/10.1021/acsami.8b03938	journal	April 2018
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811038970	journal	October 2011
Synthesis and characterization of O3-Na3LiFeSbO6: A new honeycomb ordered layered oxide Schmidt, Whitney; Berthelot, Romain; Etienne, Laetitia Materials Research Bulletin, Vol. 50 https://doi.org/10.1016/j.materresbull.2013.10.049	journal	February 2014
Phase diagram of the J 1 − J 2 − J 3 Heisenberg model on the honeycomb lattice: A series expansion study Oitmaa, J.; Singh, R. R. P. Physical Review B, Vol. 84, Issue 9 https://doi.org/10.1103/PhysRevB.84.094424	journal	September 2011
Zigzag antiferromagnetic ground state with anisotropic correlation lengths in the quasi-two-dimensional honeycomb lattice compound N a 2 C o 2 Te O 6 Bera, A. K.; Yusuf, S. M.; Kumar, Amit Physical Review B, Vol. 95, Issue 9 https://doi.org/10.1103/PhysRevB.95.094424	journal	March 2017
Neutron scattering lengths and cross sections Sears, Varley F. Neutron News, Vol. 3, Issue 3 https://doi.org/10.1080/10448639208218770	journal	January 1992
Long-range and short-range ordering in 2D honeycomb-lattice magnet Na2Ni2TeO6 Kurbakov, Alexander I.; Korshunov, Artem N.; Podchezertsev, Stanislav Yu Journal of Alloys and Compounds, Vol. 820 https://doi.org/10.1016/j.jallcom.2019.153354	journal	April 2020
High-resolution X-ray diffraction, DIFFaX, NMR and first principles study of disorder in the Li₂MnO₃–Li[Ni_1/2Mn_1/2]O₂ solid solution Bréger, Julien; Jiang, Meng; Dupré, Nicolas Journal of Solid State Chemistry, Vol. 178, Issue 9, p. 2575-2585 https://doi.org/10.1016/j.jssc.2005.05.027	journal	September 2005
Mixed oxides of sodium, antimony (5+) and divalent metals (Ni, Co, Zn or Mg) Politaev, V. V.; Nalbandyan, V. B.; Petrenko, A. A. Journal of Solid State Chemistry, Vol. 183, Issue 3 https://doi.org/10.1016/j.jssc.2009.12.002	journal	March 2010
On AgRhO2, and the new quaternary delafossites AgLi1/3M2/3O2, syntheses and analyses of real structures Todorova, V.; Leineweber, A.; Kienle, L. Journal of Solid State Chemistry, Vol. 184, Issue 5 https://doi.org/10.1016/j.jssc.2011.03.014	journal	May 2011
Magnetic and electrode properties, structure and phase relations of the layered triangular-lattice tellurate Li4NiTeO6 Zvereva, Elena A.; Nalbandyan, Vladimir B.; Evstigneeva, Maria A. Journal of Solid State Chemistry, Vol. 225 https://doi.org/10.1016/j.jssc.2014.12.003	journal	May 2015
A new layered triangular antiferromagnet Li ₄ FeSbO ₆ : spin order, field-induced transitions and anomalous critical behavior Zvereva, E. A.; Savelieva, O. A.; Titov, Ya. D. Dalton Trans., Vol. 42, Issue 5 https://doi.org/10.1039/C2DT31938A	journal	January 2013
New series of honeycomb ordered oxides, Na₃M₂SbO₆ (M(ii) = Mn, Fe, (Mn, Fe), (Mn, Co)): synthesis, structure and magnetic properties Yadav, Dileep Kumar; Sethi, Aanchal; Shalu, Shalu Dalton Transactions, Vol. 48, Issue 24 https://doi.org/10.1039/C9DT01194C	journal	January 2019
Honeycomb layered oxides: structure, energy storage, transport, topology and relevant insights Kanyolo, Godwill Mbiti; Masese, Titus; Matsubara, Nami Chemical Society Reviews, Vol. 50, Issue 6 https://doi.org/10.1039/D0CS00320D	journal	January 2021
Phase diagram of a frustrated Heisenberg antiferromagnet on the honeycomb lattice: The J 1 - J 2 - J 3 model Li, P. H. Y.; Bishop, R. F.; Farnell, D. J. J. Physical Review B, Vol. 86, Issue 14 https://doi.org/10.1103/PhysRevB.86.144404	journal	October 2012
Synthesis, Crystal Structure, and Magnetic Properties of Bi ₃ Mn ₄ O ₁₂ (NO ₃ ) Oxynitrate Comprising S = 3/2 Honeycomb Lattice Smirnova, Olga; Azuma, Masaki; Kumada, Nobuhiro Journal of the American Chemical Society, Vol. 131, Issue 23 https://doi.org/10.1021/ja901922p	journal	June 2009
Influence of oxidation state and ionic size in the formation of honeycomb ordered structures, Li3Mn2SbO6 and Li4CoSbO6 Yadav, Dileep Kumar; Pal, Sachin; Uma, Sitharaman Journal of Physics and Chemistry of Solids, Vol. 163 https://doi.org/10.1016/j.jpcs.2021.110559	journal	April 2022
Temperature-Dependent Na-Ion Conduction and Its Pathways in the Crystal Structure of the Layered Battery Material Na ₂ Ni ₂ TeO ₆ Bera, Anup Kumar; Yusuf, Seikh M. The Journal of Physical Chemistry C, Vol. 124, Issue 8 https://doi.org/10.1021/acs.jpcc.9b11191	journal	January 2020
Absence of long-range magnetic order in lithium-containing honeycombs in the Li–Cr–Sb(Te)–O phases Mandujano, H. Cein; Gonzalez, Sandra L.; Episcopo, Nathan Journal of Physics: Condensed Matter, Vol. 33, Issue 29 https://doi.org/10.1088/1361-648X/abff90	journal	June 2021
Electrochemical Properties of Three Li ₂ Ni ₂ TeO ₆ Structural Polymorphs Grundish, Nicholas S.; Seymour, Ieuan D.; Henkelman, Graeme Chemistry of Materials, Vol. 31, Issue 22 https://doi.org/10.1021/acs.chemmater.9b02956	journal	October 2019
Monoclinic honeycomb-layered compound Li3Ni2SbO6: preparation, crystal structure and magnetic properties Zvereva, Elena A.; Evstigneeva, Maria A.; Nalbandyan, Vladimir B. Dalton Trans., Vol. 41, Issue 2 https://doi.org/10.1039/C1DT11322D	journal	January 2012
Spin ¹ / ₂ Delafossite Honeycomb Compound Cu ₅ SbO ₆ Climent-Pascual, E.; Norby, P.; Andersen, N. H. Inorganic Chemistry, Vol. 51, Issue 1 https://doi.org/10.1021/ic202066n	journal	December 2011
Ordering, metastability and phase transitions in two-dimensional systems Kosterlitz, J M; Thouless, D J Journal of Physics C: Solid State Physics, Vol. 6, Issue 7, p. 1181-1203 https://doi.org/10.1088/0022-3719/6/7/010	journal	April 1973
New Layered Compounds with Honeycomb Ordering: Li ₃ Ni ₂ BiO ₆ , Li ₃ NiM′BiO ₆ (M′ = Mg, Cu, Zn), and the Delafossite Ag ₃ Ni ₂ BiO ₆ Berthelot, Romain; Schmidt, Whitney; Muir, Sean Inorganic Chemistry, Vol. 51, Issue 9 https://doi.org/10.1021/ic300351t	journal	April 2012
Crucial Role of Site Disorder and Frustration in Unusual Magnetic Properties of Quasi-2D Triangular Lattice Antimonate Na4FeSbO6 Zvereva, Elena A.; Presniakov, Igor A.; Whangbo, Myung-Hwan Applied Magnetic Resonance, Vol. 46, Issue 10 https://doi.org/10.1007/s00723-015-0700-5	journal	June 2015
Structure and Magnetic Properties of the α-NaFeO ₂ -Type Honeycomb Compound Na ₃ Ni ₂ BiO ₆ Seibel, Elizabeth M.; Roudebush, J. H.; Wu, Hui Inorganic Chemistry, Vol. 52, Issue 23 https://doi.org/10.1021/ic402131e	journal	November 2013
Zig-zag magnetic ordering in honeycomb-layered Na3Co2SbO6 Wong, Cheryl; Avdeev, Maxim; Ling, Chris D. Journal of Solid State Chemistry, Vol. 243 https://doi.org/10.1016/j.jssc.2016.07.032	journal	November 2016
Rechargeable potassium-ion batteries with honeycomb-layered tellurates as high voltage cathodes and fast potassium-ion conductors Masese, Titus; Yoshii, Kazuki; Yamaguchi, Yoichi Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06343-6	journal	September 2018
Evidence of cationic mixing and ordering in the honeycomb layer of Li ₄ MSbO ₆ (M( iii ) = Cr, Mn, Al, Ga) (S.G. C2/c) oxides Bhardwaj, Neha; Gupta, Akanksha; Uma, S. Dalton Trans., Vol. 43, Issue 31 https://doi.org/10.1039/C4DT00887A	journal	January 2014
Disordered Ground State and Magnetic Field-Induced Long-Range Order in an S = 3 / 2 Antiferromagnetic Honeycomb Lattice Compound Bi 3 Mn 4 O 12 ( NO 3 ) Matsuda, M.; Azuma, M.; Tokunaga, M. Physical Review Letters, Vol. 105, Issue 18 https://doi.org/10.1103/PhysRevLett.105.187201	journal	October 2010
A New Family of Fast Sodium Ion Conductors: Na ₂ M ₂ TeO ₆ (M = Ni, Co, Zn, Mg) Evstigneeva, Maria A.; Nalbandyan, Vladimir B.; Petrenko, Aleksandr A. Chemistry of Materials, Vol. 23, Issue 5 https://doi.org/10.1021/cm102629g	journal	March 2011
Synthesis-Controlled Polymorphism and Magnetic and Electrochemical Properties of Li ₃ Co ₂ SbO ₆ Brown, Alex J.; Xia, Qingbo; Avdeev, Maxim Inorganic Chemistry, Vol. 58, Issue 20 https://doi.org/10.1021/acs.inorgchem.9b01708	journal	October 2019
Magnetic structure, excitations and short-range order in honeycomb Na₂Ni₂TeO₆ Episcopo, Nathan; Chang, Po-Hao; Heitmann, Thomas W. Journal of Physics: Condensed Matter, Vol. 33, Issue 37 https://doi.org/10.1088/1361-648X/ac0ea6	journal	July 2021
Novel Lithium-Containing Honeycomb Structures Kumar, Vinod; Bhardwaj, Neha; Tomar, Nobel Inorganic Chemistry, Vol. 51, Issue 20 https://doi.org/10.1021/ic301125n	journal	October 2012
The Specific Heat of Matter at Low Temperatures Tari, A. https://doi.org/10.1142/p254	book	August 2003
Antiferromagnetic Order and Spin-Canting Transition in the Corrugated Square Net Compound Cu₃(TeO₄)(SO₄)·H₂O Wang, Zhi-Cheng; Thanabalasingam, Kulatheepan; Scheifers, Jan P. Inorganic Chemistry, Vol. 60, Issue 14 https://doi.org/10.1021/acs.inorgchem.1c01220	journal	June 2021
A Honeycomb-Layered Na ₃ Ni ₂ SbO ₆ : A High-Rate and Cycle-Stable Cathode for Sodium-Ion Batteries Yuan, Dingding; Liang, Xinmiao; Wu, Lin Advanced Materials, Vol. 26, Issue 36 https://doi.org/10.1002/adma.201401946	journal	July 2014
Microscopic magnetic modeling for the S = 1 2 alternating-chain compounds Na 3 Cu 2 SbO 6 and Na 2 Cu 2 TeO 6 Schmitt, M.; Janson, O.; Golbs, S. Physical Review B, Vol. 89, Issue 17 https://doi.org/10.1103/PhysRevB.89.174403	journal	May 2014
Synthesis, Structure, and Magnetic Properties of the Layered Copper(II) Oxide Na ₂ Cu ₂ TeO ₆ Xu, Jianxiao; Assoud, Abdeljalil; Soheilnia, Navid Inorganic Chemistry, Vol. 44, Issue 14 https://doi.org/10.1021/ic0502832	journal	July 2005
Formation of honeycomb ordered monoclinic Li2M2TeO6 (M = Cu, Ni) and disordered orthorhombic Li2Ni2TeO6 oxides Kumar, Vinod; Gupta, Akanksha; Uma, S. Dalton Transactions, Vol. 42, Issue 42 https://doi.org/10.1039/c3dt51604k	journal	January 2013
X-Ray Diffraction in Random Layer Lattices Warren, B. E. Physical Review, Vol. 59, Issue 9 https://doi.org/10.1103/PhysRev.59.693	journal	May 1941
Solid solution studies of layered honeycomb-ordered phases O3–Na3M2SbO6 (M=Cu, Mg, Ni, Zn) Schmidt, Whitney; Berthelot, Romain; Sleight, A. W. Journal of Solid State Chemistry, Vol. 201 https://doi.org/10.1016/j.jssc.2013.02.035	journal	May 2013
Magnetism of two-dimensional honeycomb layered Na2Ni2TeO6 driven by intermediate Na-layer crystal structure Bera, A. K.; Yusuf, S. M.; Keller, L. Physical Review B, Vol. 105, Issue 1 https://doi.org/10.1103/PhysRevB.105.014410	journal	January 2022

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Layers
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Title: Evidence of Long-Range and Short-Range Magnetic Ordering in the Honeycomb Na₃Mn₂SbO₆ Oxide