DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Softening of PEO–LiTFSI/LLZTO Composite Polymer Electrolytes for Solid-State Batteries under Cyclic Compression

Journal Article · · ACS Applied Energy Materials
 [1];  [2];  [2];  [2];  [1]; ORCiD logo [3]; ORCiD logo [4];  [5]; ORCiD logo [1]; ORCiD logo [2]
  1. Department of Chemical and Materials Engineering, San Jose State University, One Washington Square, San Jose, California 95192-0082, United States
  2. Department of Mechanical Engineering, San Jose State University, One Washington Square, San Jose, California 95192-0087, United States
  3. Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, United States
  4. Department of Mechanical Engineering, University of California, Merced, 5200 Lake Road, Merced, California 95340, United States
  5. Department of Materials Science and Engineering, Stanford University, 496 Lomita Mall, Stanford, California 94305, United States

Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
1999295
Alternate ID(s):
OSTI ID: 2471719
Journal Information:
ACS Applied Energy Materials, Journal Name: ACS Applied Energy Materials Vol. 6 Journal Issue: 18; ISSN 2574-0962
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (52)

A review of composite polymer-ceramic electrolytes for lithium batteries journal January 2021
Safety-reinforced rechargeable Li-CO2 battery based on a composite solid state electrolyte journal August 2019
Cyclic fatigue of polymer nanocomposites journal December 2009
PEO based polymer-ceramic hybrid solid electrolytes: a review journal January 2021
Polyethylene Oxide-Based Solid-State Composite Polymer Electrolytes for Rechargeable Lithium Batteries journal May 2021
Modified Li7La3Zr2O12 (LLZO) and LLZO-polymer composites for solid-state lithium batteries journal August 2021
Poly(ethylene oxide)-based electrolytes for lithium-ion batteries journal January 2015
The Critical Role of Fillers in Composite Polymer Electrolytes for Lithium Battery journal March 2023
Challenges and perspectives of garnet solid electrolytes for all solid-state lithium batteries journal June 2018
Electro–Chemo–Mechanical Issues at the Interfaces in Solid‐State Lithium Metal Batteries journal April 2019
An all coupled electrochemical-mechanical model for all-solid-state Li-ion batteries considering the effect of contact area loss and compressive pressure journal January 2022
The heat build-up of a polymer matrix composite under cyclic loading: Experimental assessment and numerical simulation journal November 2018
Morphological alterations during texture-producing plastic plane strain compression of high-density polyethylene journal October 1992
Flexible and ion-conducting membrane electrolytes for solid-state lithium batteries: Dispersion of garnet nanoparticles in insulating polyethylene oxide journal October 2016
Lithium Ionic Conductive Mechanism in PEO Polymer Electrolytes Enhanced by Nano/Micron Size LLZO Fillers journal October 2022
Modeling of nano-reinforced polymer composites: Microstructure effect on Young’s modulus journal July 2012
Electrochemical performance of all-solid-state lithium batteries using inorganic lithium garnets particulate reinforced PEO/LiClO4 electrolyte journal November 2017
Optical sensors for operando stress monitoring in lithium-based batteries containing solid-state or liquid electrolytes journal March 2022
How Electrolytes Influence Battery Safety journal January 2012
Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate–polymer composites journal September 2008
Fatigue-induced stress-softening in cross-linked multi-network elastomers: Effect of damage accumulation journal July 2021
Self heating and thermal failure of polymers sustaining a compressive cyclic loading journal September 1996
Electro-Chemo-Mechanical Challenges and Perspective in Lithium Metal Batteries journal January 2023
Effect of external pressure and internal stress on battery performance and lifespan journal November 2022
Challenges for and Pathways toward Li-Metal-Based All-Solid-State Batteries journal March 2021
A review on modified polymer composite electrolytes for solid-state lithium batteries journal January 2022
A machine-learning prediction method of lithium-ion battery life based on charge process for different applications journal June 2021
Electrochemo-mechanical effects as a critical design factor for all-solid-state batteries journal February 2022
SciPy 1.0: fundamental algorithms for scientific computing in Python journal February 2020
20 μm-Thick Li6.4La3Zr1.4Ta0.6O12-Based Flexible Solid Electrolytes for All-Solid-State Lithium Batteries journal July 2022
In Situ Study of Strain-Dependent Ion Conductivity of Stretchable Polyethylene Oxide Electrolyte journal February 2016
The relationship between structure and properties in titanium dioxide filled polypropylene journal March 1993
Atomistic investigation of the nanoparticle size and shape effects on ionic conductivity of solid polymer electrolytes journal December 2014
TXM-Wizard : a program for advanced data collection and evaluation in full-field transmission X-ray microscopy journal January 2012
Enhanced ion transport behaviors in composite polymer electrolyte: the case of a looser chain folding structure journal January 2022
Solvent-free synthesis of PEO/garnet composite electrolyte for high-safety all-solid-state lithium batteries journal April 2021
Garnet-Type Solid-State Electrolytes: Materials, Interfaces, and Batteries journal April 2020
Mechanics-based design of lithium-ion batteries: a perspective journal January 2022
Toward Sustainable Solid Polymer Electrolytes for Lithium-Ion Batteries journal April 2022
Transport and mechanical behavior in PEO-LLZO composite electrolytes journal July 2022
Rate dependence of swelling in lithium-ion cells journal December 2014
Anisotropic Mechanical Responses of Poly(Ethylene Oxide)‐Based Lithium Ions Containing Solid Polymer Electrolytes journal October 2019
Contiguous High-Mobility Interphase Surrounding Nano-Precipitates in Polymer Matrix Solid Electrolyte journal December 2022
Leveraging Molecular Architecture To Design New, All-Polymer Solid Electrolytes with Simultaneous Enhancement in Modulus and Ionic Conductivity journal March 2018
Chemo-mechanical expansion of lithium electrode materials – on the route to mechanically optimized all-solid-state batteries journal January 2018
Status, promises, and challenges of nanocomposite solid-state electrolytes for safe and high performance lithium batteries journal December 2018
A Modeling Framework of Electrochemo-mechanics of Lithium-ion Battery: Part II. Porous Electrodes with Contact Stress Effect journal September 2022
Free-Standing PEO/LiTFSI/LAGP Composite Electrolyte Membranes for Applications to Flexible Solid-State Lithium-Based Batteries journal January 2019
A review of the effect of external pressure on all-solid-state batteries journal January 2023
Reducing crystallinity in solid polymer electrolytes for lithium-metal batteries via statistical copolymerization journal August 2021
Rational Design of Hierarchical “Ceramic‐in‐Polymer” and “Polymer‐in‐Ceramic” Electrolytes for Dendrite‐Free Solid‐State Batteries journal March 2019
A quantitative correlation between macromolecular crystallinity and ionic conductivity in polymer-ceramic composite solid electrolytes journal September 2020