Encapsulation of Nanoparticle Organic Hybrid Materials within Electrospun Hydrophobic Polymer/Ceramic Fibers for Enhanced CO2 Capture

Kersey, Kyle D.; Lee, Gahyun Annie; Xu, Jeffrey H.; Kidder, Michelle K.; Park, Ah‐Hyung A.; Joo, Yong Lak

doi:10.1002/adfm.202301649

Title: Encapsulation of Nanoparticle Organic Hybrid Materials within Electrospun Hydrophobic Polymer/Ceramic Fibers for Enhanced CO₂ Capture

Journal Article · 15 May 2023 · Advanced Functional Materials

DOI: https://doi.org/10.1002/adfm.202301649 · OSTI ID:1999068

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Cornell University, Ithaca, NY (United States)
Columbia University, NY (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Liquid-like nanoparticle organic hybrid materials (NOHMs) consisting of a silica core with ionically grafted branched polyethyleneimine chains (referred to as NIPEI) are encapsulated within submicron-scale polyacrylonitrile (PAN)/polymer-derived-ceramic electrospun fibers. The addition of a room-temperature curable, liquid-phase organopolysilazane (OPSZ) ceramic precursor to the PAN/NOHM solution enhances the internal dispersion of NOHMs and forms a thin ceramic sheath layer on the fiber exterior, shielding the hydrophilic NIPEI to produce near-superhydrophobic non-woven fiber mats with contact angles exceeding 140°. 60:40 loadings of NOHMs to PAN/OPSZ can be reliably achieved with low OPSZ percentages required, and up to 4:1 NOHM:polymer loadings are possible before losing hydrophobicity. These fibers demonstrate up to ≈2 mmol CO₂ g^-1 fiber capture capacities in a pure CO₂ atmosphere through the nonwoven fibrous networks and the permeability of the OPSZ shell. In conclusion, the hybrid fibers additionally show enhanced capture kinetics under pure CO₂ and 400 ppm CO₂ conditions, indicating their promising application as a direct air capture platform.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Fossil Energy and Carbon Management (FECM)

Grant/Contract Number:: AC05-00OR22725; FE0031963

OSTI ID:: 1999068

Journal Information:: Advanced Functional Materials, Journal Name: Advanced Functional Materials Journal Issue: 32 Vol. 33; ISSN 1616-301X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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CO2 capture
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Title: Encapsulation of Nanoparticle Organic Hybrid Materials within Electrospun Hydrophobic Polymer/Ceramic Fibers for Enhanced CO2 Capture

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Title: Encapsulation of Nanoparticle Organic Hybrid Materials within Electrospun Hydrophobic Polymer/Ceramic Fibers for Enhanced CO₂ Capture