A Crosslinked Ionic Organic Framework for Efficient Iodine and Iodide Remediation in Water

Zhang, Mingshi; Samanta, Jayanta; Atterberry, Benjamin A.; Staples, Richard; Rossini, Aaron J.; Ke, Chenfeng

doi:10.1002/ange.202214189

Title: A Crosslinked Ionic Organic Framework for Efficient Iodine and Iodide Remediation in Water

Journal Article · 23 November 2022 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.202214189 · OSTI ID:1995932

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Department of Chemistry Dartmouth College 41 College Street Hanover NH 03755 USA
United States Department of Energy Ames National Laboratory Ames IA 50011 USA, Department of Chemistry Iowa State University Ames IA 50011 USA
Department of Chemistry Michigan State University 578 S. Shaw Lane East Lansing MI 48824 USA

Abstract Iodine is widely used as an antimicrobial reagent for water disinfection in the wilderness and outer space, but residual iodine and iodide need to be removed for health reasons. Currently, it is challenging to remove low concentrations of iodine and iodide in water (≈5 ppm). Furthermore, the remediation of iodine and iodide across a broad temperature range (up to 90 °C) has not previously been investigated. In this work, we report a nitrate dimer‐directed synthesis of a single‐crystalline ionic hydrogen‐bonded crosslinked organic framework (H _C OF‐7). H _C OF‐7 removes iodine and iodide species in water efficiently through halogen bonding and anion exchange, reducing the total iodine concentration to 0.22 ppm at room temperature. Packed H _C OF‐7 columns were employed for iodine/iodide breakthrough experiments between 23 and 90 °C, and large breakthrough volumes were recorded (≥18.3 L g ⁻¹ ). The high iodine/iodide removal benchmarks recorded under practical conditions make H _C OF‐7 a promising adsorbent for water treatment.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1995932

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 52 Vol. 134; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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