Reaction‐induced morphology control in block copolymers

Robertson, Mark; Dunn, Carmen B.; Qiang, Zhe

doi:10.1002/pi.6562

Title: Reaction‐induced morphology control in block copolymers

Journal Article · 20 July 2023 · Polymer International

DOI: https://doi.org/10.1002/pi.6562 · OSTI ID:1991985

^[1]; Dunn, Carmen B. ^[1];

^[1]

School of Polymer Science and Engineering, University of Southern Mississippi Hattiesburg MS USA

Abstract Controlling the self‐assembly behaviors of block copolymers (BCPs) is a focal point of many research thrusts due to their broad use in various applications. While BCP molecular weight, volume fraction, and chemical identities are key thermodynamic parameters to determine their morphology, an emergent method in this area is through reaction‐induced changes to the characteristics of a BCP in situ , which provides access to multiple morphologies and domain sizes from a single parent polymer, as well as enabling the formation of metastable morphologies which may be difficult to attain otherwise. This work provides a focused review about the current state of reaction‐induced morphology control in BCPs in both solution and solid states. Furthermore, we provide a forward‐looking perspective on the future opportunities of understanding and employing reaction engineering to manipulate and advance BCP self‐assembly. © 2023 Society of Industrial Chemistry.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 1991985

Journal Information:: Polymer International, Journal Name: Polymer International Journal Issue: 12 Vol. 72; ISSN 0959-8103

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (102)

Graphoepitaxy of Spherical Domain Block Copolymer Films Segalman, R. A.; Yokoyama, H.; Kramer, E. J. Advanced Materials, Vol. 13, Issue 15, p. 1152-1155 https://doi.org/10.1002/1521-4095(200108)13:15<1152::AID-ADMA1152>3.0.CO;2-5	journal	August 2001
Atomic Layer Deposition Assisted Pattern Multiplication of Block Copolymer Lithography for 5 nm Scale Nanopatterning Moon, Hyoung-Seok; Kim, Ju Young; Jin, Hyeong Min Advanced Functional Materials, Vol. 24, Issue 27 https://doi.org/10.1002/adfm.201304248	journal	April 2014
Widely Tunable Morphologies in Block Copolymer Thin Films Through Solvent Vapor Annealing Using Mixtures of Selective Solvents Chavis, Michelle A.; Smilgies, Detlef-M.; Wiesner, Ulrich B. Advanced Functional Materials, Vol. 25, Issue 20 https://doi.org/10.1002/adfm.201404053	journal	April 2015
Integration of Polymer Synthesis and Self‐Assembly for Controlled Periodicity and Photonic Properties Zhang, Ruimeng; Qiang, Zhe; Wang, Muzhou Advanced Functional Materials, Vol. 31, Issue 1 https://doi.org/10.1002/adfm.202005819	journal	September 2020
Thermally Switchable Aligned Nanopores by Magnetic-Field Directed Self-Assembly of Block Copolymers Gopinadhan, Manesh; Deshmukh, Prashant; Choo, Youngwoo Advanced Materials, Vol. 26, Issue 30 https://doi.org/10.1002/adma.201401569	journal	June 2014
Photoinitiated Polymerization-Induced Self-Assembly (Photo-PISA): New Insights and Opportunities Yeow, Jonathan; Boyer, Cyrille Advanced Science, Vol. 4, Issue 7 https://doi.org/10.1002/advs.201700137	journal	May 2017
Predicting Monomers for Use in Polymerization-Induced Self-Assembly Foster, Jeffrey C.; Varlas, Spyridon; Couturaud, Benoit Angewandte Chemie, Vol. 130, Issue 48 https://doi.org/10.1002/ange.201809614	journal	November 2018
Small‐Angle X‐Ray Scattering Studies of Block Copolymer Nano‐Objects: Formation of Ordered Phases in Concentrated Solution During Polymerization‐Induced Self‐Assembly Rymaruk, Matthew J.; O'Brien, Cate T.; György, Csilla Angewandte Chemie, Vol. 133, Issue 23 https://doi.org/10.1002/ange.202101851	journal	May 2021
From Precision Synthesis of Block Copolymers to Properties and Applications of Nanoparticles Li, Xiao; Iocozzia, James; Chen, Yihuang Angewandte Chemie International Edition, Vol. 57, Issue 8 https://doi.org/10.1002/anie.201705019	journal	January 2018
RAFT‐Mediated Polymerization‐Induced Self‐Assembly D'Agosto, Franck; Rieger, Jutta; Lansalot, Muriel Angewandte Chemie International Edition, Vol. 59, Issue 22 https://doi.org/10.1002/anie.201911758	journal	March 2020
Biorenewable Thermoplastic Elastomeric Triblock Copolymers Containing Salicylic Acid-Derived End-Blocks and a Fatty Acid-Derived Midblock Wang, Shu; Ding, Wenyue; Yang, Guozhen Macromolecular Chemistry and Physics, Vol. 217, Issue 2 https://doi.org/10.1002/macp.201500274	journal	November 2015
Tailor‐Made Vinylogous Urethane Vitrimers Based on Binary and Ternary Block and Random Copolymers: An Approach toward Reprocessable Materials Weerathaworn, Siraphat; Abetz, Volker Macromolecular Chemistry and Physics, Vol. 224, Issue 1 https://doi.org/10.1002/macp.202200248	journal	September 2022
Photoresponsive Amphiphilic Macrocycles Containing Main-Chain Azobenzene Polymers Sun, Yadong; Wang, Zhao; Li, Yiwen Macromolecular Rapid Communications, Vol. 36, Issue 14 https://doi.org/10.1002/marc.201500136	journal	May 2015
Application of Bottlebrush Block Copolymers as Photonic Crystals Liberman-Martin, Allegra L.; Chu, Crystal K.; Grubbs, Robert H. Macromolecular Rapid Communications, Vol. 38, Issue 13 https://doi.org/10.1002/marc.201700058	journal	May 2017
Polymerization-Induced Self-Assembly for Artificial Biology: Opportunities and Challenges Cheng, Gong; Pérez-Mercader, Juan Macromolecular Rapid Communications, Vol. 40, Issue 2 https://doi.org/10.1002/marc.201800513	journal	September 2018
Modelling of the High-Impact Polystyrene Morphogenesis Vonka, Michal; Šeda, Libor; Kosek, Juraj Macromolecular Symposia, Vol. 302, Issue 1 https://doi.org/10.1002/masy.201000062	journal	March 2011
Block copolymer solution self‐assembly: Recent advances, emerging trends, and applications Karayianni, Maria; Pispas, Stergios Journal of Polymer Science, Vol. 59, Issue 17 https://doi.org/10.1002/pol.20210430	journal	July 2021
Mesoporous carbons from self‐assembled polymers Robertson, Mark; Zagho, Moustafa M.; Nazarenko, Sergei Journal of Polymer Science, Vol. 60, Issue 14 https://doi.org/10.1002/pol.20220122	journal	April 2022
Electric-Field-Induced Alignment of Block Copolymer/Nanoparticle Blends Liedel, Clemens; Schindler, Kerstin A.; Pavan, Mariela J. Small https://doi.org/10.1002/smll.201202380	journal	March 2013
Thermal annealing of roll-cast triblock copolymer films Albalak, Ramon J.; Thomas, Edwin L.; Capel, Malcolm S. Polymer, Vol. 38, Issue 15 https://doi.org/10.1016/S0032-3861(96)00938-X	journal	July 1997
Block copolymer micelles for drug delivery: Design, characterization and biological significance Kataoka, Kazunori; Harada, Atsushi; Nagasaki, Yukio Advanced Drug Delivery Reviews, Vol. 64 https://doi.org/10.1016/j.addr.2012.09.013	journal	December 2012
On the evolution of particle size distributions during the bulk synthesis of high-impact polystyrene using PBM: Towards morphology and phase inversion prediction Maffi, J. M.; Estenoz, D. A. Chemical Engineering Science, Vol. 247 https://doi.org/10.1016/j.ces.2021.117027	journal	January 2022
Block copolymer micelles: preparation, characterization and application in drug delivery Gaucher, Geneviève; Dufresne, Marie-Hélène; Sant, Vinayak P. Journal of Controlled Release, Vol. 109, Issue 1-3 https://doi.org/10.1016/j.jconrel.2005.09.034	journal	December 2005
Synthesis of block copolymers used in polymersome fabrication: Application in drug delivery Hasannia, Maliheh; Aliabadi, Ali; Abnous, Khalil Journal of Controlled Release, Vol. 341 https://doi.org/10.1016/j.jconrel.2021.11.010	journal	January 2022
Probing Thermoresponsive Polymerization-Induced Self-Assembly with Variable-Temperature Liquid-Cell Transmission Electron Microscopy Scheutz, Georg M.; Touve, Mollie A.; Carlini, Andrea S. Matter, Vol. 4, Issue 2 https://doi.org/10.1016/j.matt.2020.11.017	journal	February 2021
Evolution of the morphology of HIPS particles Leal, G. Patricia; Asua, José M. Polymer, Vol. 50, Issue 1 https://doi.org/10.1016/j.polymer.2008.10.035	journal	January 2009
Polymerization-induced self-assembly of acrylonitrile via ICAR ATRP Wang, Guowei; Wang, Zongyu; Lee, Bongjoon Polymer, Vol. 129 https://doi.org/10.1016/j.polymer.2017.09.029	journal	October 2017
Thermomechanical activation achieving orthogonal working/healing conditions of nanostructured tri-block copolymer thermosets Clarke, Ryan W.; McGraw, Michael L.; Newell, Brian S. Cell Reports Physical Science, Vol. 2, Issue 7 https://doi.org/10.1016/j.xcrp.2021.100483	journal	July 2021
Nanopatterning via Solvent Vapor Annealing of Block Copolymer Thin Films Jin, Cong; Olsen, Brian C.; Luber, Erik J. Chemistry of Materials, Vol. 29, Issue 1 https://doi.org/10.1021/acs.chemmater.6b02967	journal	September 2016
Rational Design and Modification of High-k Bis(double-stranded) Block Copolymer for High Electrical Energy Storage Capability Chen, Jie; Wang, Yuxin; Li, Hongfei Chemistry of Materials, Vol. 30, Issue 3 https://doi.org/10.1021/acs.chemmater.7b05042	journal	January 2018
Block Copolymer Micelles in Nanomedicine Applications Cabral, Horacio; Miyata, Kanjiro; Osada, Kensuke Chemical Reviews, Vol. 118, Issue 14 https://doi.org/10.1021/acs.chemrev.8b00199	journal	June 2018
Precise Mesoscopic Model Providing Insights into Polymerization-Induced Self-Assembly Wang, Junfeng; Fang, Timing; Li, Jiawei Langmuir, Vol. 36, Issue 27 https://doi.org/10.1021/acs.langmuir.0c01404	journal	June 2020
Exploration of a Living Anionic Polymerization Mechanism into Polymerization-Induced Self-Assembly and Site-Specific Stabilization of the Formed Nano-Objects Wang, Jian; Cao, Mengya; Zhou, Peng Macromolecules, Vol. 53, Issue 8 https://doi.org/10.1021/acs.macromol.0c00371	journal	April 2020
Mechanical and Structural Consequences of Associative Dynamic Cross-Linking in Acrylic Diblock Copolymers Ishibashi, Jacob S. A.; Pierce, Ian C.; Chang, Alice B. Macromolecules, Vol. 54, Issue 9 https://doi.org/10.1021/acs.macromol.0c02744	journal	April 2021
Intermicellar Polymerization and Intramicellar Cyclization: A Supramolecular Ring–Chain Competition Reaction Hu, Rui; Gao, Liang; Cai, Chunhua Macromolecules, Vol. 54, Issue 11 https://doi.org/10.1021/acs.macromol.1c01020	journal	May 2021
Hydrolysis-Induced Self-Assembly of High-χ–Low-N Bottlebrush Copolymers Hu, Mingqiu; Li, Xindi; Rzayev, Javid Macromolecules, Vol. 54, Issue 24 https://doi.org/10.1021/acs.macromol.1c02061	journal	December 2021
Polymerization-Induced Self-Assembly (PISA) Generated Cholesterol-Based Block Copolymer Nano-Objects in a Nonpolar Solvent: Combined Experimental and Simulation Study Sahoo, Subhasish; Gordievskaya, Yulia D.; Bauri, Kamal Macromolecules, Vol. 55, Issue 4 https://doi.org/10.1021/acs.macromol.1c02081	journal	February 2022
Direct Visualization of Polymerization-Induced Self-Assembly of Amphiphilic Copolymers Jabbari, Vahid; Phakatkar, Abhijit H.; Amiri, Azadeh Macromolecules, Vol. 56, Issue 8 https://doi.org/10.1021/acs.macromol.2c02318	journal	April 2023
Electric-Field-Induced Order–Order Transition from Hexagonally Perforated Lamellae to Lamellae Pester, Christian W.; Schmidt, Kristin; Ruppel, Markus Macromolecules, Vol. 48, Issue 17 https://doi.org/10.1021/acs.macromol.5b01336	journal	August 2015
A Critical Appraisal of RAFT-Mediated Polymerization-Induced Self-Assembly Canning, Sarah L.; Smith, Gregory N.; Armes, Steven P. Macromolecules, Vol. 49, Issue 6 https://doi.org/10.1021/acs.macromol.5b02602	journal	March 2016
Biobased Plastics and Elastomers from Renewable Rosin via “Living” Ring-Opening Metathesis Polymerization Ganewatta, Mitra S.; Ding, Wenyue; Rahman, Md Anisur Macromolecules, Vol. 49, Issue 19 https://doi.org/10.1021/acs.macromol.6b01496	journal	September 2016
Polymerization-Induced Self-Assembly (PISA) Using ICAR ATRP at Low Catalyst Concentration Wang, Guowei; Schmitt, Michael; Wang, Zongyu Macromolecules, Vol. 49, Issue 22 https://doi.org/10.1021/acs.macromol.6b01966	journal	November 2016
Tuning Hydrophobicity To Program Block Copolymer Assemblies from the Inside Out Figg, C. Adrian; Carmean, R. Nicholas; Bentz, Kyle C. Macromolecules, Vol. 50, Issue 3 https://doi.org/10.1021/acs.macromol.6b02754	journal	January 2017
Realizing 5.4 nm Full Pitch Lamellar Microdomains by a Solid-State Transformation Jeong, Gajin; Yu, Duk Man; Mapas, Jose Kenneth D. Macromolecules, Vol. 50, Issue 18 https://doi.org/10.1021/acs.macromol.7b01443	journal	September 2017
Evaluation of the Interaction Parameter for Poly(solketal methacrylate)- block -polystyrene Copolymers Yu, Duk Man; Mapas, Jose Kenneth D.; Kim, Hyeyoung Macromolecules, Vol. 51, Issue 3 https://doi.org/10.1021/acs.macromol.7b02221	journal	January 2018
Influence of Solvophilic Homopolymers on RAFT Polymerization-Induced Self-Assembly Zhang, Yuan; Han, Guang; Cao, Mengjiao Macromolecules, Vol. 51, Issue 11 https://doi.org/10.1021/acs.macromol.8b00690	journal	June 2018
Morphological Evolution of Poly(solketal methacrylate)- block -polystyrene Copolymers in Thin Films Yu, Duk Man; Smith, Darren M.; Kim, Hyeyoung Macromolecules, Vol. 52, Issue 10 https://doi.org/10.1021/acs.macromol.9b00488	journal	May 2019
Insight into the Polymerization-Induced Self-Assembly via a Realistic Computer Simulation Strategy Yan, Yu-Dou; Xue, Yao-Hong; Zhao, Huan-Yu Macromolecules, Vol. 52, Issue 16 https://doi.org/10.1021/acs.macromol.9b01051	journal	August 2019
Synthesis of Nanowires via Temperature-Induced Supramolecular Step-Growth Polymerization Gao, Hongbing; Ma, Xiaodong; Lin, Jiaping Macromolecules, Vol. 52, Issue 20 https://doi.org/10.1021/acs.macromol.9b01358	journal	October 2019
Deciphering the Complex Phase Behavior during Polymerization-Induced Nanostructural Transitions of a Block Polymer/Monomer Blend Zofchak, Everett S.; LaNasa, Jacob A.; Torres, Vincent M. Macromolecules, Vol. 53, Issue 3 https://doi.org/10.1021/acs.macromol.9b01695	journal	January 2020
Block Copolymer Nanopatterning for Nonsemiconductor Device Applications Yang, Geon Gug; Choi, Hee Jae; Han, Kyu Hyo ACS Applied Materials & Interfaces, Vol. 14, Issue 10 https://doi.org/10.1021/acsami.1c22836	journal	March 2022
Polymerization-Induced Self-Assembly of Micelles Observed by Liquid Cell Transmission Electron Microscopy Touve, Mollie A.; Figg, C. Adrian; Wright, Daniel B. ACS Central Science, Vol. 4, Issue 5 https://doi.org/10.1021/acscentsci.8b00148	journal	April 2018
100th Anniversary of Macromolecular Science Viewpoint: Enabling Advances in Fluorescence Microscopy Techniques Qiang, Zhe; Wang, Muzhou ACS Macro Letters, Vol. 9, Issue 9 https://doi.org/10.1021/acsmacrolett.0c00506	journal	August 2020
Modulating Boronic Ester Stability in Block Copolymer Micelles via the Neighbor Effect of Copolymerized Tertiary Amines for Controlled Release of Polyphenolic Drugs Prossnitz, Alexander N.; Pun, Suzie H. ACS Macro Letters, Vol. 11, Issue 3 https://doi.org/10.1021/acsmacrolett.1c00751	journal	February 2022
Star Architecture Promoting Morphological Transitions during Polymerization-Induced Self-Assembly Wang, Xiao; Figg, C. Adrian; Lv, Xiaoqing ACS Macro Letters, Vol. 6, Issue 4 https://doi.org/10.1021/acsmacrolett.7b00099	journal	March 2017
Simultaneous In-Film Polymer Synthesis and Self-Assembly for Hierarchical Nanopatterns Qiang, Zhe; Akolawala, Sahil A.; Wang, Muzhou ACS Macro Letters, Vol. 7, Issue 5 https://doi.org/10.1021/acsmacrolett.8b00119	journal	April 2018
Polymerization-Induced Nanostructural Transitions Driven by In Situ Polymer Grafting Zofchak, Everett S.; LaNasa, Jacob A.; Mei, Wenwen ACS Macro Letters, Vol. 7, Issue 7 https://doi.org/10.1021/acsmacrolett.8b00378	journal	June 2018
Functionalization-Induced Self-Assembly of Block Copolymers for Nanoparticle Synthesis Howe, David H.; Hart, James L.; McDaniel, Riki M. ACS Macro Letters, Vol. 7, Issue 12 https://doi.org/10.1021/acsmacrolett.8b00815	journal	December 2018
Sequence-Controlled Polymerization-Induced Self-Assembly Wang, Lei; Ding, Yi; Liu, Qizhou ACS Macro Letters https://doi.org/10.1021/acsmacrolett.9b00305	journal	May 2019
Emerging Trends in Polymerization-Induced Self-Assembly Penfold, Nicholas J. W.; Yeow, Jonathan; Boyer, Cyrille ACS Macro Letters, Vol. 8, Issue 8 https://doi.org/10.1021/acsmacrolett.9b00464	journal	July 2019
Polymer-Ligated Nanocrystals Enabled by Nonlinear Block Copolymer Nanoreactors: Synthesis, Properties, and Applications Liu, Yijiang; Wang, Jialin; Zhang, Mingyue ACS Nano, Vol. 14, Issue 10 https://doi.org/10.1021/acsnano.0c06936	journal	September 2020
A Family of Highly Ordered Mesoporous Polymer Resin and Carbon Structures from Organic−Organic Self-Assembly Meng, Yan; Gu, Dong; Zhang, Fuqiang Chemistry of Materials, Vol. 18, Issue 18 https://doi.org/10.1021/cm060921u	journal	September 2006
In Situ SAXS Study on a New Mechanism for Mesostructure Formation of Ordered Mesoporous Carbons: Thermally Induced Self-Assembly Schuster, Jörg; Köhn, Ralf; Döblinger, Markus Journal of the American Chemical Society, Vol. 134, Issue 27 https://doi.org/10.1021/ja208941s	journal	June 2012
Polymerization-Induced Self-Assembly of Block Copolymer Nano-objects via RAFT Aqueous Dispersion Polymerization Warren, Nicholas J.; Armes, Steven P. Journal of the American Chemical Society, Vol. 136, Issue 29 https://doi.org/10.1021/ja502843f	journal	July 2014
Hierarchically Porous Polymers from Hyper-cross-linked Block Polymer Precursors Seo, Myungeun; Kim, Soobin; Oh, Jaehoon Journal of the American Chemical Society, Vol. 137, Issue 2 https://doi.org/10.1021/ja511581w	journal	January 2015
Using Dynamic Covalent Chemistry To Drive Morphological Transitions: Controlled Release of Encapsulated Nanoparticles from Block Copolymer Vesicles Deng, Renhua; Derry, Matthew J.; Mable, Charlotte J. Journal of the American Chemical Society, Vol. 139, Issue 22 https://doi.org/10.1021/jacs.7b02642	journal	May 2017
In Situ Small-Angle X-ray Scattering Studies During Reversible Addition–Fragmentation Chain Transfer Aqueous Emulsion Polymerization Brotherton, Emma E.; Hatton, Fiona L.; Cockram, Amy A. Journal of the American Chemical Society, Vol. 141, Issue 34 https://doi.org/10.1021/jacs.9b06788	journal	July 2019
Block Copolymer Vitrimers Lessard, Jacob J.; Scheutz, Georg M.; Sung, Seung Hyun Journal of the American Chemical Society, Vol. 142, Issue 1 https://doi.org/10.1021/jacs.9b10360	journal	December 2019
Nanoporous Nonwoven Fibril-Like Morphology by Cooperative Self-Assembly of Poly(ethylene oxide)- block -Poly(ethyl acrylate)- block -Polystyrene and Phenolic Resin Deng, Guodong; Qiang, Zhe; Lecorchick, Willis Langmuir, Vol. 30, Issue 9 https://doi.org/10.1021/la404964c	journal	February 2014
Cross-Linked Nanoporous Materials from Reactive and Multifunctional Block Polymers Seo, Myungeun; Amendt, Mark A.; Hillmyer, Marc A. Macromolecules, Vol. 44, Issue 23 https://doi.org/10.1021/ma2013942	journal	December 2011
Solvent Vapor Annealing of Block Polymer Thin Films Sinturel, Christophe; Vayer, Marylène; Morris, Michael Macromolecules, Vol. 46, Issue 14 https://doi.org/10.1021/ma400735a	journal	June 2013
Directed Block Copolymer Thin Film Self-Assembly: Emerging Trends in Nanopattern Fabrication Luo, Ming; Epps, Thomas H. Macromolecules, Vol. 46, Issue 19 https://doi.org/10.1021/ma401112y	journal	August 2013
On the Evolution of Phase Patterns during the High-Impact-Modified Polystyrene Process Fischer, M.; Hellmann, G. P. Macromolecules, Vol. 29, Issue 7 https://doi.org/10.1021/ma950779a	journal	January 1996
Unifying Weak- and Strong-Segregation Block Copolymer Theories Matsen, M. W.; Bates, F. S. Macromolecules, Vol. 29, Issue 4 https://doi.org/10.1021/ma951138i	journal	January 1996
Origins of Complex Self-Assembly in Block Copolymers Matsen, M. W.; Bates, F. S. Macromolecules, Vol. 29, Issue 23 https://doi.org/10.1021/ma960744q	journal	January 1996
Morphogenic Effect of Solvent on Crew-Cut Aggregates of Apmphiphilic Diblock Copolymers Yu, Yisong; Zhang, Lifeng; Eisenberg, Adi Macromolecules, Vol. 31, Issue 4 https://doi.org/10.1021/ma971254g	journal	February 1998
Long-Range Ordering of Block Copolymer Cylinders Driven by Combining Thermal Annealing and Substrate Functionalization She, Ming-Shiuan; Lo, Ting-Ya; Ho, Rong-Ming ACS Nano, Vol. 7, Issue 3 https://doi.org/10.1021/nn305725q	journal	March 2013
Arbitrary lattice symmetries via block copolymer nanomeshes Majewski, Pawel W.; Rahman, Atikur; Black, Charles T. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8448	journal	June 2015
Hierarchical patterns of three-dimensional block-copolymer films formed by electrohydrodynamic jet printing and self-assembly Onses, M. Serdar; Song, Chiho; Williamson, Lance Nature Nanotechnology, Vol. 8, Issue 9 https://doi.org/10.1038/nnano.2013.160	journal	August 2013
Direct synthesis of ordered mesoporous materials from thermoplastic elastomers Robertson, Mark; Guillen-Obando, Alejandro; Barbour, Andrew Nature Communications, Vol. 14, Issue 1 https://doi.org/10.1038/s41467-023-36362-x	journal	February 2023
Super-resolution imaging of non-fluorescent reactions via competition Mao, Xianwen; Liu, Chunming; Hesari, Mahdi Nature Chemistry, Vol. 11, Issue 8 https://doi.org/10.1038/s41557-019-0288-8	journal	July 2019
Bicontinuous mesoporous carbon thin films via an order–order transition Deng, Guodong; Zhang, Yuanzhong; Ye, Changhuai Chem. Commun., Vol. 50, Issue 84 https://doi.org/10.1039/C4CC02471K	journal	January 2014
In situ small-angle X-ray scattering studies of sterically-stabilized diblock copolymer nanoparticles formed during polymerization-induced self-assembly in non-polar media Derry, Matthew J.; Fielding, Lee A.; Warren, Nicholas J. Chemical Science, Vol. 7, Issue 8 https://doi.org/10.1039/C6SC01243D	journal	January 2016
Block copolymer derived 3-D interpenetrating multifunctional gyroidal nanohybrids for electrical energy storage Werner, J. G.; Rodríguez-Calero, G. G.; Abruña, H. D. Energy & Environmental Science, Vol. 11, Issue 5 https://doi.org/10.1039/C7EE03571C	journal	January 2018
Polymerization-induced self-assembly based on ATRP in supercritical carbon dioxide Alzahrani, Abdullah; Zhou, Dewen; Kuchel, Rhiannon P. Polymer Chemistry, Vol. 10, Issue 21 https://doi.org/10.1039/C9PY00498J	journal	January 2019
Time-resolved small-angle neutron scattering studies of the thermally-induced exchange of copolymer chains between spherical diblock copolymer nanoparticles prepared via polymerization-induced self-assembly Cornel, Erik J.; Smith, Gregory N.; Rogers, Sarah E. Soft Matter, Vol. 16, Issue 15 https://doi.org/10.1039/C9SM02425E	journal	January 2020
Self-assembly of block copolymers towards mesoporous materials for energy storage and conversion systems Li, Chen; Li, Qian; Kaneti, Yusuf Valentino Chemical Society Reviews, Vol. 49, Issue 14 https://doi.org/10.1039/D0CS00021C	journal	January 2020
A polymerization-induced self-assembly process for all-styrenic nano-objects using the living anionic polymerization mechanism Zhou, Chengcheng; Wang, Jian; Zhou, Peng Polymer Chemistry, Vol. 11, Issue 15 https://doi.org/10.1039/D0PY00296H	journal	January 2020
Polymerization techniques in polymerization-induced self-assembly (PISA) Liu, Chao; Hong, Chun-Yan; Pan, Cai-Yuan Polymer Chemistry, Vol. 11, Issue 22 https://doi.org/10.1039/D0PY00455C	journal	January 2020
Reaction-induced phase transitions with block copolymers in solution and bulk Lequieu, Joshua; Magenau, Andrew J. D. Polymer Chemistry, Vol. 12, Issue 1 https://doi.org/10.1039/D0PY00722F	journal	January 2021
Precursor design for efficient synthesis of large-pore, sulfur-doped ordered mesoporous carbon through direct pyrolysis Robertson, Mark; Griffin, Anthony; Obando, Alejandro Guillen Molecular Systems Design & Engineering https://doi.org/10.1039/D3ME00043E	journal	January 2023
Smart block copolymer masks with molecule-transport channels for total wet nanopatterning Watanabe, Ryoko; Kamata, Kaori; Iyoda, Tomokazu Journal of Materials Chemistry, Vol. 18, Issue 45 https://doi.org/10.1039/b806378h	journal	January 2008
Recent advances in stimuli-responsive degradable block copolymer micelles: synthesis and controlled drug delivery applications Zhang, Qian; Re Ko, Na; Kwon Oh, Jung Chemical Communications, Vol. 48, Issue 61 https://doi.org/10.1039/c2cc32408c	journal	January 2012
Photo-responsive block copolymer micelles: design and behavior Gohy, Jean-François; Zhao, Yue Chemical Society Reviews, Vol. 42, Issue 17 https://doi.org/10.1039/c3cs35469e	journal	January 2013
Evolutionary pattern design for copolymer directed self-assembly Qin, Jian; Khaira, Gurdaman S.; Su, Yongrui Soft Matter, Vol. 9, Issue 48 https://doi.org/10.1039/c3sm51971f	journal	January 2013
A general route to nanocrystal kebabs periodically assembled on stretched flexible polymer shish Xu, Hui; Xu, Yuci; Pang, Xinchang Science Advances, Vol. 1, Issue 2 https://doi.org/10.1126/sciadv.1500025	journal	March 2015
Uniform metal nanostructures with long-range order via three-step hierarchical self-assembly Erb, Denise J.; Schlage, Kai; Röhlsberger, Ralf Science Advances, Vol. 1, Issue 10 https://doi.org/10.1126/sciadv.1500751	journal	November 2015
Reticulated Nanoporous Polymers by Controlled Polymerization-Induced Microphase Separation Seo, M.; Hillmyer, M. A. Science, Vol. 336, Issue 6087 https://doi.org/10.1126/science.1221383	journal	June 2012
Polymer-Polymer Phase Behavior Bates, Frank S. Science, Vol. 251, Issue 4996, p. 898-905 https://doi.org/10.1126/science.251.4996.898	journal	February 1991
1D nanocrystals with precisely controlled dimensions, compositions, and architectures Pang, X.; He, Y.; Jung, J. Science, Vol. 353, Issue 6305 https://doi.org/10.1126/science.aad8279	journal	September 2016
Controlling Order in Block Copolymer Thin Films for Nanopatterning Applications Marencic, Andrew P.; Register, Richard A. Annual Review of Chemical and Biomolecular Engineering, Vol. 1, Issue 1 https://doi.org/10.1146/annurev-chembioeng-073009-101007	journal	June 2010
Block Copolymer Thermodynamics: Theory and Experiment Bates, Frank S.; Fredrickson, Glenn H. Annual Review of Physical Chemistry, Vol. 41, Issue 1 https://doi.org/10.1146/annurev.pc.41.100190.002521	journal	October 1990

Similar Records

A simple route to prepare supramolecular block copolymers using telechelic polystyrene/polydimethylsiloxane pairs

Journal Article · 2021 · Polymer International · OSTI ID:1828428

Güillen Obando, Alejandro; Chen, Yuwei; Qiang, Zhe

Highly oriented and ordered microstructures in block copolymer films

Journal Article · 2018 · Journal of Polymer Science. Part B, Polymer Physics · OSTI ID:1472177

Zhao, Wei; Zhang, Yi; Wang, Xiao; +4 more

Beyond native block copolymer morphologies

Journal Article · 2017 · Molecular Systems Design & Engineering · OSTI ID:1399668

Doerk, Gregory S.; Yager, Kevin G.

Title: Reaction‐induced morphology control in block copolymers

Citation Formats

References (102)

Similar Records

Related Subjects