Significant charge transport effects due to subtle molecular changes in nitroxide radical single crystals

Liang, Zihao; Hsu, Sheng-Ning; Tan, Ying; Tahir, Hamas; Kim, Ho Joong; Liu, Kangying; Stoehr, Jacob F.; Zeller, Matthias; Dou, Letian; Savoie, Brett M.; Boudouris, Bryan W.

doi:10.1016/j.xcrp.2023.101409

Title: Significant charge transport effects due to subtle molecular changes in nitroxide radical single crystals

Journal Article · 04 May 2023 · Cell Reports Physical Science

DOI: https://doi.org/10.1016/j.xcrp.2023.101409 · OSTI ID:1991494

Liang, Zihao ^[1]; Hsu, Sheng-Ning ^[2]; Tan, Ying ^[2]; Tahir, Hamas ^[2]; Kim, Ho Joong ^[2]; Liu, Kangying ^[2]; Stoehr, Jacob F. ^[2]; Zeller, Matthias ^[2]; Dou, Letian ^[2]; Savoie, Brett M. ^[2];

^[2]

Purdue University, West Lafayette, IN (United States); Purdue University
Purdue University, West Lafayette, IN (United States)

Radical-containing materials have received renewed interest due to their charge-conducting properties. However, most work focuses on macromolecules, while less attention has been paid to radical-containing small molecules. Here, we quantify the electrical conductivity in two organic radical single crystals and demonstrate that a subtle change in atomic connectivity drastically alters the macroscopic electronic properties of the materials. One radical crystal has an electrical conductivity of 3S m^–1, which is the among the highest values for nonconjugated radical conductors over a 1 μm scale. However, the other radical crystal has a 1,000-fold lower conductivity, despite their extremely similar molecular structures. The temperature-dependent conductivity follows the variable range hopping mechanism for both radical crystals, and the difference in effective charge mobility is the reason for the conductivity difference. These results present a clear picture of the design rules and charge transport mechanism for radical-based small-molecule materials.

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Research Organization:: Purdue University, West Lafayette, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0021967

OSTI ID:: 1991494

Journal Information:: Cell Reports Physical Science, Journal Name: Cell Reports Physical Science Journal Issue: 5 Vol. 4; ISSN 2666-3864

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (77)

Innovation of Materials, Devices, and Functionalized Interfaces in Organic Spintronics Li, Dong; Yu, Gui Advanced Functional Materials, Vol. 31, Issue 28 https://doi.org/10.1002/adfm.202100550	journal	April 2021
Emerging N-Type Redox-Active Radical Polymer for a Totally Organic Polymer-Based Rechargeable Battery Suga, Takeo; Ohshiro, Hiroki; Sugita, Shuhei Advanced Materials, Vol. 21, Issue 16 https://doi.org/10.1002/adma.200803073	journal	April 2009
Radical Polymers for Organic Electronic Devices: A Radical Departure from Conjugated Polymers? Oyaizu, Kenichi; Nishide, Hiroyuki Advanced Materials, Vol. 21, Issue 22 https://doi.org/10.1002/adma.200803554	journal	June 2009
Electronic Transport in Organic Materials: Comparison of Band Theory with Percolation/(Variable Range) Hopping Theory Stallinga, P. Advanced Materials, Vol. 23, Issue 30 https://doi.org/10.1002/adma.201101129	journal	June 2011
Air‐Stable Organic Radicals: New‐Generation Materials for Flexible Electronics? Ji, Lei; Shi, Junqing; Wei, Juan Advanced Materials, Vol. 32, Issue 32 https://doi.org/10.1002/adma.201908015	journal	June 2020
Polymers Based on Stable Phenoxyl Radicals for the Use in Organic Radical Batteries Jähnert, Thomas; Häupler, Bernhard; Janoschka, Tobias Macromolecular Rapid Communications, Vol. 35, Issue 9 https://doi.org/10.1002/marc.201300791	journal	March 2014
Recent advances in the syntheses of radical-containing macromolecules Wingate, Adam J.; Boudouris, Bryan W. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 54, Issue 13 https://doi.org/10.1002/pola.28088	journal	March 2016
Suppressing the environmental dependence of the open-circuit voltage in inverted polymer solar cells through a radical polymer anodic modifier Rostro, Lizbeth; Galicia, Lucio; Boudouris, Bryan W. Journal of Polymer Science Part B: Polymer Physics, Vol. 53, Issue 5 https://doi.org/10.1002/polb.23640	journal	November 2014
Controlling open-shell loading in norbornene-based radical polymers modulates the solid-state charge transport exponentially Hay, Martha E.; Hui Wong, Si; Mukherjee, Sanjoy Journal of Polymer Science Part B: Polymer Physics, Vol. 55, Issue 20 https://doi.org/10.1002/polb.24406	journal	August 2017
Sequential Codoping Making Nonconjugated Organic Radicals Conduct Ionically Electronically Jo, Yerin; Yu, Ilhwan; Ko, Jaehyoung Small Science, Vol. 2, Issue 1 https://doi.org/10.1002/smsc.202100081	journal	October 2021
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
The magnetochemistry of verdazyl radical-based materials Koivisto, Bryan D.; Hicks, Robin G. Coordination Chemistry Reviews, Vol. 249, Issue 23 https://doi.org/10.1016/j.ccr.2005.03.012	journal	December 2005
Persistent and Stable Organic Radicals: Design, Synthesis, and Applications Chen, Z. X.; Li, Y.; Huang, F. Chem, Vol. 7, Issue 2 https://doi.org/10.1016/j.chempr.2020.09.024	journal	February 2021
Magnetic behavior in metal-free radical thin films Junghoefer, Tobias; Calzolari, Arrigo; Baev, Ivan Chem, Vol. 8, Issue 3 https://doi.org/10.1016/j.chempr.2021.11.021	journal	March 2022
VASPKIT: A user-friendly interface facilitating high-throughput computing and analysis using VASP code Wang, Vei; Xu, Nan; Liu, Jin-Cheng Computer Physics Communications, Vol. 267 https://doi.org/10.1016/j.cpc.2021.108033	journal	October 2021
Organic radical battery: nitroxide polymers as a cathode-active material Nishide, Hiroyuki; Iwasa, Shigeyuki; Pu, Yong-Jin Electrochimica Acta, Vol. 50, Issue 2-3, p. 827-831 https://doi.org/10.1016/j.electacta.2004.02.052	journal	November 2004
Distinct mechanisms of the newborn innate immunity Kumar, S. Kingsley Manoj; Bhat, B. Vishnu Immunology Letters, Vol. 173 https://doi.org/10.1016/j.imlet.2016.03.009	journal	May 2016
Radical polymers improve the metal-semiconductor interface in organic field-effect transistors Sung, Seung Hyun; Bajaj, Nikhil; Rhoads, Jeffrey F. Organic Electronics, Vol. 37 https://doi.org/10.1016/j.orgel.2016.06.020	journal	October 2016
Modifying field-effect transistor response in a conjugated polymer upon the addition of radical dopants Wilcox, Daniel A.; Boudouris, Bryan W. Thin Solid Films, Vol. 714 https://doi.org/10.1016/j.tsf.2020.138391	journal	November 2020
Magnetic Characterization of Open-Shell Donor–Acceptor Conjugated Polymers Adams, Daniel J.; Mayer, Kevin S.; Steelman, Michael The Journal of Physical Chemistry C, Vol. 126, Issue 12 https://doi.org/10.1021/acs.jpcc.1c10020	journal	March 2022
Density of States and the Role of Energetic Disorder in Charge Transport in an Organic Radical Polymer in the Solid State Kemper, Travis W.; Larsen, Ross E.; Gennett, Thomas The Journal of Physical Chemistry C, Vol. 119, Issue 37 https://doi.org/10.1021/acs.jpcc.5b06368	journal	September 2015
Design of Mixed Electron- and Ion-Conducting Radical Polymer-Based Blends Akkiraju, Siddhartha; Vergados, John; Hoagland, Laura Macromolecules, Vol. 54, Issue 11 https://doi.org/10.1021/acs.macromol.1c00113	journal	May 2021
Top–Down Coarse-Grained Framework for Characterizing Mixed Conducting Polymers Khot, Aditi; Savoie, Brett M. Macromolecules, Vol. 54, Issue 10 https://doi.org/10.1021/acs.macromol.1c00219	journal	May 2021
Thermoelectric Performance of an Open-Shell Donor–Acceptor Conjugated Polymer Doped with a Radical-Containing Small Molecule Joo, Yongho; Huang, Lifeng; Eedugurala, Naresh Macromolecules, Vol. 51, Issue 10 https://doi.org/10.1021/acs.macromol.8b00582	journal	May 2018
Making Nonconjugated Small-Molecule Organic Radicals Conduct Yu, Ilhwan; Jo, Yerin; Ko, Jaehyoung Nano Letters, Vol. 20, Issue 7 https://doi.org/10.1021/acs.nanolett.0c01730	journal	June 2020
Large Magnetoresistance in Single-Radical Molecular Junctions Hayakawa, Ryoma; Karimi, Mohammad Amin; Wolf, Jannic Nano Letters, Vol. 16, Issue 8 https://doi.org/10.1021/acs.nanolett.6b01595	journal	August 2016
Tuning the Thermoelectric Properties of a Conducting Polymer through Blending with Open-Shell Molecular Dopants Tomlinson, Edward P.; Willmore, Matthew J.; Zhu, Xiaoqin ACS Applied Materials & Interfaces, Vol. 7, Issue 33 https://doi.org/10.1021/acsami.5b05860	journal	August 2015
Quantifying TEMPO Redox Polymer Charge Transport toward the Organic Radical Battery Karlsson, Christoffer; Suga, Takeo; Nishide, Hiroyuki ACS Applied Materials & Interfaces, Vol. 9, Issue 12 https://doi.org/10.1021/acsami.7b00403	journal	March 2017
Highly Transparent Crosslinkable Radical Copolymer Thin Film as the Ion Storage Layer in Organic Electrochromic Devices He, Jiazhi; Mukherjee, Sanjoy; Zhu, Xingrui ACS Applied Materials & Interfaces, Vol. 10, Issue 22 https://doi.org/10.1021/acsami.8b03235	journal	May 2018
100th Anniversary of Macromolecular Science Viewpoint: Recent Advances and Opportunities for Mixed Ion and Charge Conducting Polymers Chung, Jaeyub; Khot, Aditi; Savoie, Brett M. ACS Macro Letters, Vol. 9, Issue 5 https://doi.org/10.1021/acsmacrolett.0c00037	journal	April 2020
100th Anniversary of Macromolecular Science Viewpoint: Fundamentals for the Future of Macromolecular Nitroxide Radicals Wang, Shaoyang; Easley, Alexandra D.; Lutkenhaus, Jodie L. ACS Macro Letters, Vol. 9, Issue 3 https://doi.org/10.1021/acsmacrolett.0c00063	journal	February 2020
Radical Polymer-Based Organic Electrochemical Transistors Kim, Ho Joong; Perera, Kuluni; Liang, Zihao ACS Macro Letters, Vol. 11, Issue 2 https://doi.org/10.1021/acsmacrolett.1c00695	journal	January 2022
Controlled Radical Polymerization and Quantification of Solid State Electrical Conductivities of Macromolecules Bearing Pendant Stable Radical Groups Rostro, Lizbeth; Baradwaj, Aditya G.; Boudouris, Bryan W. ACS Applied Materials & Interfaces, Vol. 5, Issue 20 https://doi.org/10.1021/am403223s	journal	October 2013
Strong Ferromagnetic and Antiferromagnetic Exchange Coupling between Transition Metals and Coordinated Verdazyl Radicals Hicks, Robin G.; Lemaire, Martin T.; Thompson, Laurence K. Journal of the American Chemical Society, Vol. 122, Issue 33 https://doi.org/10.1021/ja001627k	journal	August 2000
Cavity-Induced Spin−Spin Interaction between Organic Radicals within a Self-Assembled Coordination Cage Nakabayashi, Koji; Kawano, Masaki; Yoshizawa, Michito Journal of the American Chemical Society, Vol. 126, Issue 51 https://doi.org/10.1021/ja044445p	journal	November 2004
Battery-Inspired, Nonvolatile, and Rewritable Memory Architecture: a Radical Polymer-Based Organic Device Yonekuta, Yasunori; Susuki, Kentaro; Oyaizu, Kenichi Journal of the American Chemical Society, Vol. 129, Issue 46 https://doi.org/10.1021/ja075553p	journal	November 2007
Electronic Structure Investigations of Neutral and Charged Ruthenium Bis(β-diketonate) Complexes of Redox-Active Verdazyl Radicals McKinnon, Stephen D. J.; Patrick, Brian O.; Lever, A. B. P. Journal of the American Chemical Society, Vol. 133, Issue 34 https://doi.org/10.1021/ja204575u	journal	August 2011
Synthesis and Thin Films of Thermally Robust Quartet ( S = 3/2) Ground State Triradical Shu, Chan; Pink, Maren; Junghoefer, Tobias Journal of the American Chemical Society, Vol. 143, Issue 14 https://doi.org/10.1021/jacs.1c01305	journal	March 2021
Molecular Design Features for Charge Transport in Nonconjugated Radical Polymers Tan, Ying; Casetti, Nicholas C.; Boudouris, Bryan W. Journal of the American Chemical Society, Vol. 143, Issue 31 https://doi.org/10.1021/jacs.1c02571	journal	July 2021
Electronic and Spintronic Open-Shell Macromolecules, Quo Vadis? Tan, Ying; Hsu, Sheng-Ning; Tahir, Hamas Journal of the American Chemical Society, Vol. 144, Issue 2 https://doi.org/10.1021/jacs.1c09815	journal	January 2022
High-Spin (S = 1) Blatter-Based Diradical with Robust Stability and Electrical Conductivity Zhang, Shuyang; Pink, Maren; Junghoefer, Tobias Journal of the American Chemical Society, Vol. 144, Issue 13 https://doi.org/10.1021/jacs.2c01141	journal	March 2022
High-Spin S = 3/2 Ground-State Aminyl Triradicals: Toward High-Spin Oligo-Aza Nanographenes Zhang, Hui; Pink, Maren; Wang, Ying Journal of the American Chemical Society, Vol. 144, Issue 42 https://doi.org/10.1021/jacs.2c09241	journal	October 2022
S = 1 Tetraazacyclophane Diradical Dication with Robust Stability: A Case of Low-Temperature One-Dimensional Antiferromagnetic Chain Wang, Wenqing; Chen, Chao; Shu, Chan Journal of the American Chemical Society, Vol. 140, Issue 25 https://doi.org/10.1021/jacs.8b02415	journal	May 2018
Thermally and Magnetically Robust Triplet Ground State Diradical Gallagher, Nolan; Zhang, Hui; Junghoefer, Tobias Journal of the American Chemical Society, Vol. 141, Issue 11 https://doi.org/10.1021/jacs.9b00558	journal	February 2019
High-Spin Diradical Dication of Chiral π-Conjugated Double Helical Molecule Shu, Chan; Zhang, Hui; Olankitwanit, Arnon Journal of the American Chemical Society, Vol. 141, Issue 43 https://doi.org/10.1021/jacs.9b08711	journal	October 2019
High-Spin Organic Molecules Gallagher, Nolan M.; Olankitwanit, Arnon; Rajca, Andrzej The Journal of Organic Chemistry, Vol. 80, Issue 3 https://doi.org/10.1021/jo502505r	journal	January 2015
Relationship between Molecular Structure and Electron Transfer in a Polymeric Nitroxyl-Radical Energy Storage Material Kemper, Travis W.; Larsen, Ross E.; Gennett, Thomas The Journal of Physical Chemistry C, Vol. 118, Issue 31 https://doi.org/10.1021/jp501628z	journal	July 2014
Cathode- and Anode-Active Poly(nitroxylstyrene)s for Rechargeable Batteries: p- and n-Type Redox Switching via Substituent Effects Suga, Takeo; Pu, Yong-Jin; Kasatori, Shinji Macromolecules, Vol. 40, Issue 9 https://doi.org/10.1021/ma0628578	journal	May 2007
Synthesis and Charge Transport Properties of Redox-Active Nitroxide Polyethers with Large Site Density Oyaizu, Kenichi; Kawamoto, Takeshi; Suga, Takeo Macromolecules, Vol. 43, Issue 24 https://doi.org/10.1021/ma1020159	journal	December 2010
Solid State Electrical Conductivity of Radical Polymers as a Function of Pendant Group Oxidation State Rostro, Lizbeth; Wong, Si Hui; Boudouris, Bryan W. Macromolecules, Vol. 47, Issue 11 https://doi.org/10.1021/ma500626t	journal	May 2014
A new spin on bistability Hicks, Robin G. Nature Chemistry, Vol. 3, Issue 3 https://doi.org/10.1038/nchem.997	journal	February 2011
Spin-enhanced organic bulk heterojunction photovoltaic solar cells Zhang, Ye; Basel, Tek P.; Gautam, Bhoj R. Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms2057	journal	January 2012
Intrinsic glassy-metallic transport in an amorphous coordination polymer Xie, Jiaze; Ewing, Simon; Boyn, Jan-Niklas Nature, Vol. 611, Issue 7936 https://doi.org/10.1038/s41586-022-05261-4	journal	October 2022
Playing with organic radicals as building blocks for functional molecular materials Ratera, Imma; Veciana, Jaume Chem. Soc. Rev., Vol. 41, Issue 1 https://doi.org/10.1039/C1CS15165G	journal	January 2012
6-Oxoverdazyl radical polymers with tunable electrochemical properties Price, Jacquelyn T.; Paquette, Joseph A.; Harrison, Christopher S. Polym. Chem., Vol. 5, Issue 18 https://doi.org/10.1039/C4PY00829D	journal	January 2014
Stable organic radical polymers: synthesis and applications Zhang, Kai; Monteiro, Michael J.; Jia, Zhongfan Polymer Chemistry, Vol. 7, Issue 36 https://doi.org/10.1039/C6PY00996D	journal	January 2016
Synthesis and redox reactions of bis(verdazyl)palladium complexes Sanz, Corey A.; McKay, Zach R.; MacLean, Shaun W. C. Dalton Transactions, Vol. 46, Issue 37 https://doi.org/10.1039/C7DT02646C	journal	January 2017
Design of a three-state switchable chromogenic radical-based moiety and its translation to molecular logic systems Mukherjee, Sanjoy; Boudouris, Bryan W. Molecular Systems Design & Engineering, Vol. 2, Issue 2 https://doi.org/10.1039/C7ME00010C	journal	January 2017
Nitroxide radical polymers – a versatile material class for high-tech applications Hansen, Kai-Anders; Blinco, James P. Polymer Chemistry, Vol. 9, Issue 13 https://doi.org/10.1039/C7PY02001E	journal	January 2018
Radical polymers as interfacial layers in inverted hybrid perovskite solar cells Zheng, Luyao; Mukherjee, Sanjoy; Wang, Kai Journal of Materials Chemistry A, Vol. 5, Issue 45 https://doi.org/10.1039/C7TA07732G	journal	January 2017
Nitroxide radical polymers for emerging plastic energy storage and organic electronics: fundamentals, materials, and applications Xie, Yuan; Zhang, Kai; Yamauchi, Yusuke Materials Horizons, Vol. 8, Issue 3 https://doi.org/10.1039/D0MH01391A	journal	January 2021
Design of an n-type low glass transition temperature radical polymer Chi, Teng; Akkiraju, Siddhartha; Liang, Zihao Polymer Chemistry, Vol. 12, Issue 10 https://doi.org/10.1039/D0PY01645D	journal	January 2021
Insights into the magnetism and phase transitions of organic radical-based materials Deumal, Mercè; Vela, Sergi; Fumanal, Maria Journal of Materials Chemistry C, Vol. 9, Issue 33 https://doi.org/10.1039/D1TC01376A	journal	January 2021
Charge transport and antiferromagnetic ordering in nitroxide radical crystals Liang, Zihao; Tan, Ying; Hsu, Sheng-Ning Molecular Systems Design & Engineering, Vol. 8, Issue 4 https://doi.org/10.1039/D2ME00202G	journal	January 2023
What's new in stable radical chemistry? Hicks, Robin G. Organic & Biomolecular Chemistry, Vol. 5, Issue 9 https://doi.org/10.1039/b617142g	journal	January 2006
Interplay between magnetism and conductivity derived from spin-polarized donor radicals Sugawara, Tadashi; Komatsu, Hideji; Suzuki, Kentaro Chemical Society Reviews, Vol. 40, Issue 6 https://doi.org/10.1039/c0cs00157k	journal	January 2011
An overview of the magnetoresistance phenomenon in molecular systems Gu, Hongbo; Zhang, Xi; Wei, Huige Chemical Society Reviews, Vol. 42, Issue 13 https://doi.org/10.1039/c3cs60074b	journal	January 2013
The first “Kuhn verdazyl” ligand and comparative studies of its PdCl2 complex with analogous 6-oxoverdazyl ligands Johnston, Cooper W.; McKinnon, Stephen D. J.; Patrick, Brian O. Dalton Transactions, Vol. 42, Issue 48 https://doi.org/10.1039/c3dt52191e	journal	January 2013
Technique for conductivity measurements on single crystals of organic materials Coleman, L. B. Review of Scientific Instruments, Vol. 46, Issue 8 https://doi.org/10.1063/1.1134370	journal	August 1975
Preparation and Properties of Biphenyl and Cholesterol Derivatives with Nitroxide Radicals Nakatsuji, Shin'ichi; Mizumoto, Masako; Kitamura, Kohei Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol. 356, Issue 1 https://doi.org/10.1080/10587250108023684	journal	February 2001
Application of Bravais-Friedel-Donnay-Harker, attachment energy and Ising models to predicting and understanding the morphology of molecular crystals Docherty, R.; Clydesdale, G.; Roberts, K. J. Journal of Physics D: Applied Physics, Vol. 24, Issue 2 https://doi.org/10.1088/0022-3727/24/2/001	journal	February 1991
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/PhysRevB.47.558	journal	January 1993
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium Kresse, G.; Hafner, J. Physical Review B, Vol. 49, Issue 20, p. 14251-14269 https://doi.org/10.1103/PhysRevB.49.14251	journal	May 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
CrystalExplorer : a program for Hirshfeld surface analysis, visualization and quantitative analysis of molecular crystals Spackman, Peter R.; Turner, Michael J.; McKinnon, Joshua J. Journal of Applied Crystallography, Vol. 54, Issue 3 https://doi.org/10.1107/S1600576721002910	journal	April 2021
A nonconjugated radical polymer glass with high electrical conductivity Joo, Yongho; Agarkar, Varad; Sung, Seung Hyun Science, Vol. 359, Issue 6382 https://doi.org/10.1126/science.aao7287	journal	March 2018

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Title: Significant charge transport effects due to subtle molecular changes in nitroxide radical single crystals

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