Impact of Indium Chloride Treatment on the Properties of CuInSe2 Thin Films

Poudel, Deewakar; Masters, Adam; Belfore, Benjamin; Palmiotti, Elizabeth; Rockett, Angus; Marsillac, Sylvain

doi:10.1109/pvsc48317.2022.9938814

Title: Impact of Indium Chloride Treatment on the Properties of CuInSe₂ Thin Films

Journal Article · 04 June 2022 · Conference Record of the Photovoltaics Specialists Conference

DOI: https://doi.org/10.1109/pvsc48317.2022.9938814 · OSTI ID:1991386

Poudel, Deewakar ^[1]; Masters, Adam ^[2]; Belfore, Benjamin ^[2]; Palmiotti, Elizabeth ^[3]; Rockett, Angus ^[3]; Marsillac, Sylvain ^[2]

Old Dominion University, Norfolk, VA (United States); Colorado School of Mines
Old Dominion University, Norfolk, VA (United States)
Colorado School of Mines, Golden, CO (United States)

Copper Indium diselenide (CIS) semiconductor thin films were deposited by single-stage process. Following the deposition, annealing and recrystallization of CIS was carried out in the presence of InCl₃ at different temperatures. Increase in grain size was observed by SEM in all cases. Increase in peak intensity was observed by XRD after treatment, correlating well with the SEM results. Measurements of the composition by both XRF and EDS indicate significant changes, notably a decrease in copper content. Here, this will likely be an issue for device performance and will need to be addressed.

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Research Organization:: Colorado School of Mines, Golden, CO (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: EE0007551

OSTI ID:: 1991386

Journal Information:: Conference Record of the Photovoltaics Specialists Conference, Journal Name: Conference Record of the Photovoltaics Specialists Conference Vol. 2022; ISSN 0742-6666

Publisher:: IEEECopyright Statement

Country of Publication:: United States

Language:: English

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