Highly Conductive Polyoxanorbornene‐Based Polymer Electrolyte for Lithium‐Metal Batteries

An, So Young; Wu, Xinsheng; Zhao, Yuqi; Liu, Tong; Yin, Rongguan; Ahn, Jung Hyun; Walker, Lynn M.; Whitacre, Jay F.; Matyjaszewski, Krzysztof

doi:10.1002/advs.202302932

Title: Highly Conductive Polyoxanorbornene‐Based Polymer Electrolyte for Lithium‐Metal Batteries

Journal Article · 16 July 2023 · Advanced Science

DOI: https://doi.org/10.1002/advs.202302932 · OSTI ID:1989981

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Department of Chemistry Carnegie Mellon University 4400 Fifth Avenue Pittsburgh PA 15213 USA
Department of Materials Science and Engineering Carnegie Mellon University 5000 Forbes Avenue Pittsburgh PA 15213 USA
Department of Chemical Engineering Carnegie Mellon University 5000 Forbes Avenue Pittsburgh PA 15213 USA
Department of Materials Science and Engineering Carnegie Mellon University 5000 Forbes Avenue Pittsburgh PA 15213 USA, Scott Institute for Energy Innovation Carnegie Mellon University 5000 Forbes Avenue Pittsburgh PA 15213 USA

Abstract This present study illustrates the synthesis and preparation of polyoxanorbornene‐based bottlebrush polymers with poly(ethylene oxide) (PEO) side chains by ring‐opening metathesis polymerization for solid polymer electrolytes (SPE). In addition to the conductive PEO side chains, the polyoxanorbornene backbones may act as another ion conductor to further promote Li‐ion movement within the SPE matrix. These results suggest that these bottlebrush polymer electrolytes provide impressively high ionic conductivity of 7.12 × 10 ⁻⁴ S cm ⁻¹ at room temperature and excellent electrochemical performance, including high‐rate capabilities and cycling stability when paired with a Li metal anode and a LiFePO ₄ cathode. The new design paradigm, which has dual ionic conductive pathways, provides an unexplored avenue for inventing new SPEs and emphasizes the importance of molecular engineering to develop highly stable and conductive polymer electrolytes for lithium‐metal batteries (LMB).

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Research Organization:: Carnegie Mellon Univ., Pittsburgh, PA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0018784

OSTI ID:: 1989981

Journal Information:: Advanced Science, Journal Name: Advanced Science Journal Issue: 27 Vol. 10; ISSN 2198-3844

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Title: Highly Conductive Polyoxanorbornene‐Based Polymer Electrolyte for Lithium‐Metal Batteries

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