Tetrathiafulvalene-2,3,6,7-tetrathiolate linker redox-state elucidation via S K-edge X-ray absorption spectroscopy

Jiang, Ningxin; Boyn, Jan-Niklas; Ramanathan, Arun; La Pierre, Henry S.; Anderson, John S.

doi:10.1039/D3CC02325G

Title: Tetrathiafulvalene-2,3,6,7-tetrathiolate linker redox-state elucidation via S K-edge X-ray absorption spectroscopy

Journal Article · 01 August 2023 · ChemComm

DOI: https://doi.org/10.1039/D3CC02325G · OSTI ID:1989735

Jiang, Ningxin ^[1];

^[2];

^[3];

^[1]

Department of Chemistry and The James Franck Institute, University of Chicago, Chicago, Illinois, 60637, USA
Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey, 08544-5263, USA
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia, 30332-0400, USA

S K-edge XAS data reveal decreasing covalency upon oxidation and a distinct signature for doubly oxidized TTF cores in NiTTFtt based complexes and materials.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; SC0019215; AC02-76SF00515

OSTI ID:: 1989735

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 62 Vol. 59; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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