Porous and Water Stable 2D Hybrid Metal Halide with Broad Light Emission and Selective H 2 O Vapor Sorption

Azmy, Ali; Li, Shunran; Angeli, Giasemi K.; Welton, Claire; Raval, Parth; Li, Min; Zibouche, Nourdine; Wojtas, Lukasz; Reddy, G. N. Manjunatha; Guo, Peijun; Trikalitis, Pantelis N.; Spanopoulos, Ioannis

doi:10.1002/ange.202218429

Title: Porous and Water Stable 2D Hybrid Metal Halide with Broad Light Emission and Selective H ₂ O Vapor Sorption

Journal Article · Fri Feb 10 00:00:00 UTC 2023 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.202218429 · OSTI ID:1983433

Azmy, Ali ^[1]; Li, Shunran ^[2];

^[3]; Welton, Claire ^[4]; Raval, Parth ^[4]; Li, Min ^[5]; Zibouche, Nourdine ^[6]; Wojtas, Lukasz ^[1]; Reddy, G. N. Manjunatha ^[4]; Guo, Peijun ^[2]; Trikalitis, Pantelis N. ^[3];

^[1]

Department of Chemistry University of South Florida Tampa FL 33620 USA
Department of Chemical and Environmental Engineering Yale University 9 Hillhouse Avenue New Haven CT 06520 USA, Energy Sciences Institute Yale University 810 West Campus Drive West Haven CT 06516 USA
Department of Chemistry University of Crete 71003 Heraklion Greece
University of Lille, CNRS, Centrale Lille Institut Univ. Artois, UMR8181-UCCS-Unité de Catalyse et Chimie du Solide 59000 Lille France
West Campus Materials Characterization Core Yale University New Haven CT 06520 USA
Department of Chemistry University of Bath Bath BA2 7AY UK

Abstract In this work we report a strategy for generating porosity in hybrid metal halide materials using molecular cages that serve as both structure‐directing agents and counter‐cations. Reaction of the [2.2.2] cryptand (DHS) linker with Pb ^II in acidic media gave rise to the first porous and water‐stable 2D metal halide semiconductor (DHS) ₂ Pb ₅ Br ₁₄ . The corresponding material is stable in water for a year, while gas and vapor‐sorption studies revealed that it can selectively and reversibly adsorb H ₂ O and D ₂ O at room temperature (RT). Solid‐state NMR measurements and DFT calculations verified the incorporation of H ₂ O and D ₂ O in the organic linker cavities and shed light on their molecular configuration. In addition to porosity, the material exhibits broad light emission centered at 617 nm with a full width at half‐maximum (FWHM) of 284 nm (0.96 eV). The recorded water stability is unparalleled for hybrid metal halide and perovskite materials, while the generation of porosity opens new pathways towards unexplored applications ( e.g . solid‐state batteries) for this class of hybrid semiconductors.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1983433

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 12 Vol. 135; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (132)

CsPbX ₃ Quantum Dots for Lighting and Displays: Room-Temperature Synthesis, Photoluminescence Superiorities, Underlying Origins and White Light-Emitting Diodes Li, Xiaoming; Wu, Ye; Zhang, Shengli Advanced Functional Materials, Vol. 26, Issue 15 https://doi.org/10.1002/adfm.201600109	journal	February 2016
Broadband Defects Emission and Enhanced Ligand Raman Scattering in 0D Cs ₃ Bi ₂ I ₉ Colloidal Nanocrystals Paternò, Giuseppe M.; Mishra, Nimai; Barker, Alex J. Advanced Functional Materials, Vol. 29, Issue 21 https://doi.org/10.1002/adfm.201805299	journal	November 2018
Solution‐Processable Perovskite Solar Cells toward Commercialization: Progress and Challenges Wang, Peng; Wu, Yihui; Cai, Bing Advanced Functional Materials, Vol. 29, Issue 47 https://doi.org/10.1002/adfm.201807661	journal	April 2019
Pores in III–V Semiconductors Föll, H.; Langa, S.; Carstensen, J. Advanced Materials, Vol. 15, Issue 3 https://doi.org/10.1002/adma.200390043	journal	February 2003
Unique Properties of Halide Perovskites as Possible Origins of the Superior Solar Cell Performance Yin, Wan-Jian; Shi, Tingting; Yan, Yanfa Advanced Materials, Vol. 26, Issue 27 https://doi.org/10.1002/adma.201306281	journal	May 2014
Halogenated‐Methylammonium Based 3D Halide Perovskites Huang, Sheng; Huang, Peng; Wang, Lei Advanced Materials, Vol. 31, Issue 42 https://doi.org/10.1002/adma.201903830	journal	September 2019
Halide Perovskites: A New Era of Solution‐Processed Electronics Younis, Adnan; Lin, Chun‐Ho; Guan, Xinwei Advanced Materials, Vol. 33, Issue 23 https://doi.org/10.1002/adma.202005000	journal	May 2021
Methylphosphonium Tin Bromide: A 3D Perovskite Molecular Ferroelectric Semiconductor Zhang, Han‐Yue; Chen, Xiao‐Gang; Zhang, Zhi‐Xu Advanced Materials, Vol. 32, Issue 47 https://doi.org/10.1002/adma.202005213	journal	October 2020
Reversible Crystal–Glass Transition in a Metal Halide Perovskite Singh, Akash; Jana, Manoj K.; Mitzi, David B. Advanced Materials, Vol. 33, Issue 3 https://doi.org/10.1002/adma.202005868	journal	December 2020
Stabilization of Metastable Halide Perovskite Lattices in the 2D Limit Fu, Yongping Advanced Materials, Vol. 34, Issue 9 https://doi.org/10.1002/adma.202108556	journal	January 2022
Reentrant Structural and Optical Properties and Large Positive Thermal Expansion in Perovskite Formamidinium Lead Iodide Fabini, Douglas H.; Stoumpos, Constantinos C.; Laurita, Geneva Angewandte Chemie, Vol. 128, Issue 49 https://doi.org/10.1002/ange.201609538	journal	November 2016
Adaptive Behavior of Dynamic Orthoester Cryptands Shyshov, Oleksandr; Brachvogel, René‐Chris; Bachmann, Tobias Angewandte Chemie, Vol. 129, Issue 3 https://doi.org/10.1002/ange.201609855	journal	December 2016
Intrinsic Broadband White-Light Emission from Ultrastable, Cationic Lead Halide Layered Materials Zhuang, Zewen; Peng, Chengdong; Zhang, Guiyang Angewandte Chemie, Vol. 129, Issue 46 https://doi.org/10.1002/ange.201706660	journal	October 2017
Reversible Band Gap Narrowing of Sn-Based Hybrid Perovskite Single Crystal with Excellent Phase Stability Ju, Dianxing; Zheng, Xiaopeng; Liu, Jialiang Angewandte Chemie, Vol. 130, Issue 45 https://doi.org/10.1002/ange.201810481	journal	October 2018
Hydrophobic Metal Halide Perovskites for Visible‐Light Photoredox C−C Bond Cleavage and Dehydrogenation Catalysis Hong, Zonghan; Chong, Wee Kiang; Ng, Andrew Yun Ru Angewandte Chemie, Vol. 131, Issue 11 https://doi.org/10.1002/ange.201812225	journal	March 2019
A Three‐Dimensional Porous Organic Semiconductor Based on Fully sp ² ‐Hybridized Graphitic Polymer Byun, Yearin; Xie, Lilia S.; Fritz, Patrick Angewandte Chemie, Vol. 132, Issue 35 https://doi.org/10.1002/ange.202005069	journal	June 2020
Water‐Stable DMASnBr₃Lead‐Free Perovskite for Effective Solar‐Driven Photocatalysis Romani, Lidia; Speltini, Andrea; Ambrosio, Francesco Angewandte Chemie, Vol. 133, Issue 7 https://doi.org/10.1002/ange.202007584	journal	December 2020
Reentrant Structural and Optical Properties and Large Positive Thermal Expansion in Perovskite Formamidinium Lead Iodide Fabini, Douglas H.; Stoumpos, Constantinos C.; Laurita, Geneva Angewandte Chemie International Edition, Vol. 55, Issue 49 https://doi.org/10.1002/anie.201609538	journal	November 2016
Adaptive Behavior of Dynamic Orthoester Cryptands Shyshov, Oleksandr; Brachvogel, René‐Chris; Bachmann, Tobias Angewandte Chemie International Edition, Vol. 56, Issue 3 https://doi.org/10.1002/anie.201609855	journal	December 2016
Intrinsic Broadband White-Light Emission from Ultrastable, Cationic Lead Halide Layered Materials Zhuang, Zewen; Peng, Chengdong; Zhang, Guiyang Angewandte Chemie International Edition, Vol. 56, Issue 46 https://doi.org/10.1002/anie.201706660	journal	October 2017
Reversible Band Gap Narrowing of Sn-Based Hybrid Perovskite Single Crystal with Excellent Phase Stability Ju, Dianxing; Zheng, Xiaopeng; Liu, Jialiang Angewandte Chemie International Edition, Vol. 57, Issue 45 https://doi.org/10.1002/anie.201810481	journal	October 2018
Hydrophobic Metal Halide Perovskites for Visible-Light Photoredox C−C Bond Cleavage and Dehydrogenation Catalysis Hong, Zonghan; Chong, Wee Kiang; Ng, Andrew Yun Ru Angewandte Chemie International Edition, Vol. 58, Issue 11 https://doi.org/10.1002/anie.201812225	journal	February 2019
A Three‐Dimensional Porous Organic Semiconductor Based on Fully sp ² ‐Hybridized Graphitic Polymer Byun, Yearin; Xie, Lilia S.; Fritz, Patrick Angewandte Chemie International Edition, Vol. 59, Issue 35 https://doi.org/10.1002/anie.202005069	journal	June 2020
Water‐Stable DMASnBr ₃ Lead‐Free Perovskite for Effective Solar‐Driven Photocatalysis Romani, Lidia; Speltini, Andrea; Ambrosio, Francesco Angewandte Chemie International Edition, Vol. 60, Issue 7 https://doi.org/10.1002/anie.202007584	journal	December 2020
A 3D Haloplumbate Framework Constructed From Unprecedented Lindqvist-like Highly Coordinated [Pb ₆ Br ₂₅ ] ¹³⁻ Nanoclusters with Temperature-Dependent Emission Li, Xinxiong; Do, T. Thu Ha; Granados del Águila, A. Chemistry - An Asian Journal, Vol. 13, Issue 21 https://doi.org/10.1002/asia.201801292	journal	October 2018
A 3D Iodoplumbate Semiconducting Open Framework with Visible‐light‐induced Photocatalytic Performance Ge, Bang‐Di; Wei, Qi; Sun, Ai‐Huan Chemistry – An Asian Journal, Vol. 14, Issue 12 https://doi.org/10.1002/asia.201900392	journal	May 2019
CsPb ₂ Br ₅ Single Crystals: Synthesis and Characterization Dursun, Ibrahim; De Bastiani, Michele; Turedi, Bekir ChemSusChem, Vol. 10, Issue 19 https://doi.org/10.1002/cssc.201701131	journal	August 2017
Dynamic Directing Effect and Symmetric Correlation in Three pH‐Modulated 1,4‐Diazabicyclo[2.2.2]octane/Iodoargentate Hybrids Yu, Tanlai; Li, Huihui; Hao, Pengfei European Journal of Inorganic Chemistry, Vol. 2016, Issue 30 https://doi.org/10.1002/ejic.201600757	journal	September 2016
Vibrational study of lead bromide perovskite materials with variable cations based on Raman spectroscopy and density functional theory Ghosh, Supriya; Rana, Debkumar; Pradhan, Bapi Journal of Raman Spectroscopy, Vol. 52, Issue 12 https://doi.org/10.1002/jrs.6141	journal	May 2021
Mesoporous Germanium Anode Materials for Lithium-Ion Battery with Exceptional Cycling Stability in Wide Temperature Range Choi, Sinho; Cho, Yoon-Gyo; Kim, Jieun Small, Vol. 13, Issue 13 https://doi.org/10.1002/smll.201603045	journal	January 2017
Molecular‐Level Insight into Correlation between Surface Defects and Stability of Methylammonium Lead Halide Perovskite Under Controlled Humidity Akhavan Kazemi, Mohammad Ali; Raval, Parth; Cherednichekno, Kirill Small Methods, Vol. 5, Issue 2 https://doi.org/10.1002/smtd.202000834	journal	November 2020
Toward Eco‐Friendly Lead‐Free Low‐Dimensional Perovskites Gao, Xinying; Luo, Jiawei; Wu, Yilei Small Structures, Vol. 3, Issue 7 https://doi.org/10.1002/sstr.202100219	journal	April 2022
[1,2-P₂S₈]²⁻- a New Member of the Thiophosphate Family: Synthesis, Crystal Structure and Vibrational Spectrum of [NH₄(2.2.2-cryptand)]₂[1,2-P₂S₈] and [NH₄(18-crown-6)]₂[1,2-P₂S₈]·H₂O Gjikaj, Mimoza; Wu, Peng Zeitschrift für anorganische und allgemeine Chemie, Vol. 634, Issue 10 https://doi.org/10.1002/zaac.200800183	journal	August 2008
Die Gesetze der Krystallochemie Goldschmidt, V. M. Die Naturwissenschaften, Vol. 14, Issue 21 https://doi.org/10.1007/BF01507527	journal	May 1926
One- and two-step metal ion templated syntheses of the cryptands Krakowiak, Krzysztof E.; Bradshaw, Jerald S.; Kou, Xiaolan Tetrahedron, Vol. 51, Issue 6 https://doi.org/10.1016/0040-4020(94)01051-Z	journal	February 1995
Approaches to improvement of metal ion selectivity by cryptands Zhang, Xian Xin; Izatt, Reed M.; Bradshaw, Jerald S. Coordination Chemistry Reviews, Vol. 174, Issue 1 https://doi.org/10.1016/S0010-8545(98)00050-2	journal	July 1998
Cryptand ligands for selective lithium coordination Formica, M.; Fusi, V.; Micheloni, M. Coordination Chemistry Reviews, Vol. 184, Issue 1 https://doi.org/10.1016/S0010-8545(99)00052-1	journal	April 1999
Porous silicon—mechanisms of growth and applications Parkhutik, V. Solid-State Electronics, Vol. 43, Issue 6 https://doi.org/10.1016/S0038-1101(99)00036-2	journal	June 1999
Ordered porous metal oxide semiconductors for gas sensing Zhou, Xinran; Cheng, Xiaowei; Zhu, Yongheng Chinese Chemical Letters, Vol. 29, Issue 3 https://doi.org/10.1016/j.cclet.2017.06.021	journal	March 2018
Three-dimensional metal-halide open frameworks Li, Xin-Xiong; Zheng, Shou-Tian Coordination Chemistry Reviews, Vol. 430 https://doi.org/10.1016/j.ccr.2020.213663	journal	March 2021
Reticular Chemistry in Action: A Hydrolytically Stable MOF Capturing Twice Its Weight in Adsorbed Water Towsif Abtab, Sk Md; Alezi, Dalal; Bhatt, Prashant M. Chem, Vol. 4, Issue 1 https://doi.org/10.1016/j.chempr.2017.11.005	journal	January 2018
Metal-Organic Frameworks for the Capture of Trace Aromatic Volatile Organic Compounds Xie, Lin-Hua; Liu, Xiao-Min; He, Tao Chem, Vol. 4, Issue 8 https://doi.org/10.1016/j.chempr.2018.05.017	journal	August 2018
A new corner-shared 1D hybrid lead halide: Broad-band photoluminescence and semiconductive properties Wen, Yingyi; Chiranjeevulu, Kashi; Ye, Xiaoliang Inorganic Chemistry Communications, Vol. 134 https://doi.org/10.1016/j.inoche.2021.109042	journal	December 2021
The effects of deposition manner and rate on structure and morphology of porous ZnSe nanolayers: Modification of Phonon Confinement Model for resonant Raman conditions Nesheva, D.; Grujić-Brojčin, M.; Šćepanović, M. J. Journal of Alloys and Compounds, Vol. 927 https://doi.org/10.1016/j.jallcom.2022.166942	journal	December 2022
Perovskite and Organic Solar Cells on a Rocket Flight Reb, Lennart K.; Böhmer, Michael; Predeschly, Benjamin Joule, Vol. 4, Issue 9 https://doi.org/10.1016/j.joule.2020.07.004	journal	September 2020
Order-disorder structural phase transition and magnetocaloric effect in organic-inorganic halide hybrid (C2H5NH3)2CoCl4 Sen, Abhijit; Roy, Soumyabrata; Peter, Sebastian C. Journal of Solid State Chemistry, Vol. 258 https://doi.org/10.1016/j.jssc.2017.10.036	journal	February 2018
Structural diversity in hybrid lead halides templated by 4-methylimidazolium Elliott, Clement; McNulty, Jason A.; Cordes, David B. Journal of Solid State Chemistry, Vol. 303 https://doi.org/10.1016/j.jssc.2021.122466	journal	November 2021
3D Inorganic Cuprous Iodide Open-Framework Templated by In Situ N-Methylated 2,4,6-Tri(4-pyridyl)-1,3,5-triazine Sun, Ai-Huan; Han, Song-De; Pan, Jie Crystal Growth & Design, Vol. 17, Issue 7 https://doi.org/10.1021/acs.cgd.7b00296	journal	June 2017
Large Conjugated Organic Cations Sensitized Hybrid Lead Halides as Visible Light Driven Photocatalysts Yue, Cheng-Yang; Zhao, Hui-Fang; Jiang, Hao Crystal Growth & Design, Vol. 19, Issue 8 https://doi.org/10.1021/acs.cgd.9b00395	journal	June 2019
Three-Dimensional Perovskite Methylhydrazinium Lead Chloride with Two Polar Phases and Unusual Second-Harmonic Generation Bistability above Room Temperature Ma̧czka, Mirosław; Gagor, Anna; Zarȩba, Jan K. Chemistry of Materials, Vol. 32, Issue 9 https://doi.org/10.1021/acs.chemmater.0c00973	journal	April 2020
Cesium Substitution Disrupts Concerted Cation Dynamics in Formamidinium Hybrid Perovskites Mozur, Eve M.; Hope, Michael A.; Trowbridge, Julia C. Chemistry of Materials, Vol. 32, Issue 14 https://doi.org/10.1021/acs.chemmater.0c01862	journal	May 2020
Dynamic Motion of Organic Spacer Cations in Ruddlesden–Popper Lead Iodide Perovskites Probed by Solid-State NMR Spectroscopy Dahlman, Clayton J.; Kennard, Rhiannon M.; Paluch, Piotr Chemistry of Materials, Vol. 33, Issue 2 https://doi.org/10.1021/acs.chemmater.0c03958	journal	January 2021
Expanding the Cage of 2D Bromide Perovskites by Large A-Site Cations Li, Xiaotong; Cuthriell, Shelby A.; Bergonzoni, Ashanti Chemistry of Materials, Vol. 34, Issue 3 https://doi.org/10.1021/acs.chemmater.1c03605	journal	January 2022
Stabilizing Perovskite Structures by Tuning Tolerance Factor: Formation of Formamidinium and Cesium Lead Iodide Solid-State Alloys Li, Zhen; Yang, Mengjin; Park, Ji-Sang Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04107	journal	December 2015
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J. Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867 https://doi.org/10.1021/acs.chemmater.6b00847	journal	April 2016
Morphology-Independent Stable White-Light Emission from Self-Assembled Two-Dimensional Perovskites Driven by Strong Exciton–Phonon Coupling to the Organic Framework Thirumal, Krishnamoorthy; Chong, Wee Kiang; Xie, Wei Chemistry of Materials, Vol. 29, Issue 9 https://doi.org/10.1021/acs.chemmater.7b00073	journal	April 2017
Broadband Emission with a Massive Stokes Shift from Sulfonium Pb–Br Hybrids Smith, Matthew D.; Watson, Brian L.; Dauskardt, Reinhold H. Chemistry of Materials, Vol. 29, Issue 17 https://doi.org/10.1021/acs.chemmater.7b02594	journal	August 2017
Unveiling Solvent-Related Effect on Phase Transformations in CsBr–PbBr ₂ System: Coordination and Ratio of Precursors Liu, Mei; Zhao, Jiangtao; Luo, Zhenlin Chemistry of Materials, Vol. 30, Issue 17 https://doi.org/10.1021/acs.chemmater.8b00537	journal	August 2018
Efficient Broad-Band Emission from Contorted Purely Corner-Shared One Dimensional (1D) Organic Lead Halide Perovskite Biswas, Anupam; Bakthavatsalam, Rangarajan; Shaikh, Samir R. Chemistry of Materials, Vol. 31, Issue 7 https://doi.org/10.1021/acs.chemmater.9b00069	journal	March 2019
Methylhydrazinium Lead Bromide: Noncentrosymmetric Three-Dimensional Perovskite with Exceptionally Large Framework Distortion and Green Photoluminescence Ma̧czka, Mirosl̷aw; Ptak, Maciej; Ga̧gor, Anna Chemistry of Materials, Vol. 32, Issue 4 https://doi.org/10.1021/acs.chemmater.9b05273	journal	January 2020
The 2D Halide Perovskite Rulebook: How the Spacer Influences Everything from the Structure to Optoelectronic Device Efficiency Li, Xiaotong; Hoffman, Justin M.; Kanatzidis, Mercouri G. Chemical Reviews, Vol. 121, Issue 4 https://doi.org/10.1021/acs.chemrev.0c01006	journal	January 2021
Porous Silicon Carbide (SiC): A Chance for Improving Catalysts or Just Another Active-Phase Carrier? Tuci, Giulia; Liu, Yuefeng; Rossin, Andrea Chemical Reviews, Vol. 121, Issue 17 https://doi.org/10.1021/acs.chemrev.1c00269	journal	July 2021
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design Saparov, Bayrammurad; Mitzi, David B. Chemical Reviews, Vol. 116, Issue 7 https://doi.org/10.1021/acs.chemrev.5b00715	journal	March 2016
(C₅H₆N)Pb₂X₅ (X = Cl, Br): Hybrid Lead Halides Based on Seven-Coordinate Pb(II) Chow, Alyssa S.; Zhong, Xinyue; Fabini, Douglas H. Inorganic Chemistry, Vol. 61, Issue 17 https://doi.org/10.1021/acs.inorgchem.2c00351	journal	April 2022
Two-Dimensional and Emission-Tunable: An Unusual Perovskite Constructed from Lindqvist-Type [Pb ₆ Br ₁₉ ] ^7– Nanoclusters Li, Xinxiong; Ha Do, T. Thu; Granados del Águila, A. Inorganic Chemistry, Vol. 57, Issue 22 https://doi.org/10.1021/acs.inorgchem.8b02535	journal	November 2018
Highly Efficient Broadband Green Emission of (TPA)CuCl₂ Single Crystals: Understanding the Formation of Self-Trapped States Peng, Hui; Tian, Ye; Wang, Xinxin The Journal of Physical Chemistry C, Vol. 126, Issue 19 https://doi.org/10.1021/acs.jpcc.2c02114	journal	May 2022
Broadband Photoluminescence in 2D Organic–Inorganic Hybrid Perovskites: (C ₇ H ₁₈ N ₂ )PbBr ₄ and (C ₉ H ₂₂ N ₂ )PbBr ₄ Deng, Chenkai; Zhou, Guojun; Chen, Da The Journal of Physical Chemistry Letters, Vol. 11, Issue 8 https://doi.org/10.1021/acs.jpclett.0c00578	journal	March 2020
Highly Efficient Self-Trapped Exciton Emission of a (MA) ₄ Cu ₂ Br ₆ Single Crystal Peng, Hui; Yao, Shangfei; Guo, Yongchang The Journal of Physical Chemistry Letters, Vol. 11, Issue 12 https://doi.org/10.1021/acs.jpclett.0c01162	journal	May 2020
Proton Irradiation Tolerance of High-Efficiency Perovskite Absorbers for Space Applications Kanaya, Shusaku; Kim, Gyu Min; Ikegami, Masashi The Journal of Physical Chemistry Letters, Vol. 10, Issue 22 https://doi.org/10.1021/acs.jpclett.9b02665	journal	October 2019
Out-of-Plane Mechanical Properties of 2D Hybrid Organic–Inorganic Perovskites by Nanoindentation Tu, Qing; Spanopoulos, Ioannis; Hao, Shiqiang ACS Applied Materials & Interfaces, Vol. 10, Issue 26 https://doi.org/10.1021/acsami.8b05138	journal	June 2018
Incorporating Large A Cations into Lead Iodide Perovskite Cages: Relaxed Goldschmidt Tolerance Factor and Impact on Exciton–Phonon Interaction Fu, Yongping; Hautzinger, Matthew P.; Luo, Ziyu ACS Central Science, Vol. 5, Issue 8 https://doi.org/10.1021/acscentsci.9b00367	journal	July 2019
Understanding Instability in Formamidinium Lead Halide Perovskites: Kinetics of Transformative Reactions at Grain and Subgrain Boundaries Raval, Parth; Kennard, Rhiannon M.; Vasileiadou, Eugenia S. ACS Energy Letters, Vol. 7, Issue 4 https://doi.org/10.1021/acsenergylett.2c00140	journal	March 2022
Perovskite Photovoltaics: The Path to a Printable Terawatt-Scale Technology Berry, Joseph J.; van de Lagemaat, Jao; Al-Jassim, Mowafak M. ACS Energy Letters, Vol. 2, Issue 11 https://doi.org/10.1021/acsenergylett.7b00964	journal	October 2017
Improved Environmental Stability and Solar Cell Efficiency of (MA,FA)PbI₃ Perovskite Using a Wide-Band-Gap 1D Thiazolium Lead Iodide Capping Layer Strategy Gao, Lili; Spanopoulos, Ioannis; Ke, Weijun ACS Energy Letters, Vol. 4, Issue 7 https://doi.org/10.1021/acsenergylett.9b00930	journal	June 2019
Perovskite Photocatalysis. Methyl Viologen Induces Unusually Long-Lived Charge Carrier Separation in CsPbBr ₃ Nanocrystals Kobosko, Steven M.; DuBose, Jeffrey T.; Kamat, Prashant V. ACS Energy Letters, Vol. 5, Issue 1 https://doi.org/10.1021/acsenergylett.9b02573	journal	December 2019
Membranes for Hydrogen Separation Ockwig, Nathan W.; Nenoff, Tina M. Chemical Reviews, Vol. 107, Issue 10, p. 4078-4110 https://doi.org/10.1021/cr0501792	journal	October 2007
Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G. Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038 https://doi.org/10.1021/ic401215x	journal	July 2013
White-Light Emission from Magic-Sized Cadmium Selenide Nanocrystals Bowers, Michael J.; McBride, James R.; Rosenthal, Sandra J. Journal of the American Chemical Society, Vol. 127, Issue 44 https://doi.org/10.1021/ja055470d	journal	November 2005
Organic Cation Alloying on Intralayer A and Interlayer A’ sites in 2D Hybrid Dion–Jacobson Lead Bromide Perovskites (A’)(A)Pb ₂ Br ₇ Mao, Lingling; Guo, Peijun; Kepenekian, Mikaël Journal of the American Chemical Society, Vol. 142, Issue 18 https://doi.org/10.1021/jacs.0c01625	journal	April 2020
Water-Stable 1D Hybrid Tin(II) Iodide Emits Broad Light with 36% Photoluminescence Quantum Efficiency Spanopoulos, Ioannis; Hadar, Ido; Ke, Weijun Journal of the American Chemical Society, Vol. 142, Issue 19 https://doi.org/10.1021/jacs.0c03004	journal	April 2020
Continuous Electrical Conductivity Variation in M ₃ (Hexaiminotriphenylene) ₂ (M = Co, Ni, Cu) MOF Alloys Chen, Tianyang; Dou, Jin-Hu; Yang, Luming Journal of the American Chemical Society, Vol. 142, Issue 28 https://doi.org/10.1021/jacs.0c04458	journal	June 2020
Solid-State NMR and NQR Spectroscopy of Lead-Halide Perovskite Materials Piveteau, Laura; Morad, Viktoriia; Kovalenko, Maksym V. Journal of the American Chemical Society, Vol. 142, Issue 46 https://doi.org/10.1021/jacs.0c07338	journal	September 2020
Tunable Broad Light Emission from 3D “Hollow” Bromide Perovskites through Defect Engineering Spanopoulos, Ioannis; Hadar, Ido; Ke, Weijun Journal of the American Chemical Society, Vol. 143, Issue 18 https://doi.org/10.1021/jacs.1c01727	journal	April 2021
Highly Stable Zr(IV)-Based Metal–Organic Frameworks for the Detection and Removal of Antibiotics and Organic Explosives in Water Wang, Bin; Lv, Xiu-Liang; Feng, Dawei Journal of the American Chemical Society, Vol. 138, Issue 19 https://doi.org/10.1021/jacs.6b01663	journal	May 2016
Unraveling the Chemical Nature of the 3D “Hollow” Hybrid Halide Perovskites Spanopoulos, Ioannis; Ke, Weijun; Stoumpos, Constantinos C. Journal of the American Chemical Society, Vol. 140, Issue 17 https://doi.org/10.1021/jacs.8b01034	journal	April 2018
Blue Emitting Single Crystalline Assembly of Metal Halide Clusters Zhou, Chenkun; Lin, Haoran; Worku, Michael Journal of the American Chemical Society, Vol. 140, Issue 41 https://doi.org/10.1021/jacs.8b07731	journal	September 2018
Two-Dimensional Hybrid Halide Perovskites: Principles and Promises Mao, Lingling; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G. Journal of the American Chemical Society, Vol. 141, Issue 3 https://doi.org/10.1021/jacs.8b10851	journal	November 2018
Uniaxial Expansion of the 2D Ruddlesden–Popper Perovskite Family for Improved Environmental Stability Spanopoulos, Ioannis; Hadar, Ido; Ke, Weijun Journal of the American Chemical Society, Vol. 141, Issue 13 https://doi.org/10.1021/jacs.9b01327	journal	March 2019
Ultrafast Carrier Dynamics in CdSe Nanocrystals Determined by Femtosecond Fluorescence Upconversion Spectroscopy Underwood, David F.; Kippeny, Tadd; Rosenthal, Sandra J. The Journal of Physical Chemistry B, Vol. 105, Issue 2 https://doi.org/10.1021/jp003088b	journal	January 2001
Understanding the physical properties of hybrid perovskites for photovoltaic applications Huang, Jinsong; Yuan, Yongbo; Shao, Yuchuan Nature Reviews Materials, Vol. 2, Issue 7 https://doi.org/10.1038/natrevmats.2017.42	journal	July 2017
All-solid-state dye-sensitized solar cells with high efficiency Chung, In; Lee, Byunghong; He, Jiaqing Nature, Vol. 485, Issue 7399, p. 486-489 https://doi.org/10.1038/nature11067	journal	May 2012
One-dimensional organic lead halide perovskites with efficient bluish white-light emission Yuan, Zhao; Zhou, Chenkun; Tian, Yu Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14051	journal	January 2017
Metal halide perovskites for energy applications Zhang, Wei; Eperon, Giles E.; Snaith, Henry J. Nature Energy, Vol. 1, Issue 6 https://doi.org/10.1038/nenergy.2016.48	journal	May 2016
Low-bandgap mixed tin–lead iodide perovskite absorbers with long carrier lifetimes for all-perovskite tandem solar cells Zhao, Dewei; Yu, Yue; Wang, Changlei Nature Energy, Vol. 2, Issue 4 https://doi.org/10.1038/nenergy.2017.18	journal	March 2017
The emergence of perovskite solar cells Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J. Nature Photonics, Vol. 8, Issue 7, p. 506-514 https://doi.org/10.1038/nphoton.2014.134	journal	July 2014
Perovskite photonic sources Sutherland, Brandon R.; Sargent, Edward H. Nature Photonics, Vol. 10, Issue 5 https://doi.org/10.1038/nphoton.2016.62	journal	April 2016
Halide lead perovskites for ionizing radiation detection Wei, Haotong; Huang, Jinsong Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08981-w	journal	March 2019
Lead halide perovskites for photocatalytic organic synthesis Zhu, Xiaolin; Lin, Yixiong; San Martin, Jovan Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10634-x	journal	June 2019
Suppression of phase transitions and glass phase signatures in mixed cation halide perovskites Simenas, Mantas; Balciunas, Sergejus; Wilson, Jacob N. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-18938-z	journal	October 2020
CsPbBr3 perovskite detectors with 1.4% energy resolution for high-energy γ-rays He, Yihui; Petryk, Matthew; Liu, Zhifu Nature Photonics, Vol. 15, Issue 1 https://doi.org/10.1038/s41566-020-00727-1	journal	December 2020
NMR spectroscopy probes microstructure, dynamics and doping of metal halide perovskites Kubicki, Dominik J.; Stranks, Samuel D.; Grey, Clare P. Nature Reviews Chemistry, Vol. 5, Issue 9 https://doi.org/10.1038/s41570-021-00309-x	journal	August 2021
Dimensional tailoring of hybrid perovskites for photovoltaics Grancini, Giulia; Nazeeruddin, Mohammad Khaja Nature Reviews Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s41578-018-0065-0	journal	November 2018
All-inorganic perovskite nanocrystal scintillators Chen, Qiushui; Wu, Jing; Ou, Xiangyu Nature, Vol. 561, Issue 7721 https://doi.org/10.1038/s41586-018-0451-1	journal	August 2018
Efficient and stable emission of warm-white light from lead-free halide double perovskites Luo, Jiajun; Wang, Xiaoming; Li, Shunran Nature, Vol. 563, Issue 7732 https://doi.org/10.1038/s41586-018-0691-0	journal	November 2018
Defects activated photoluminescence in two-dimensional semiconductors: interplay between bound, charged and free excitons Tongay, Sefaattin; Suh, Joonki; Ataca, Can Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02657	journal	September 2013
Tunable electrical conductivity in oriented thin films of tetrathiafulvalene-based covalent organic framework Cai, Song-Liang; Zhang, Yue-Biao; Pun, Andrew B. Chem. Sci., Vol. 5, Issue 12 https://doi.org/10.1039/C4SC02593H	journal	January 2014
A nanowire array with two types of bromoplumbate chains and high anisotropic conductance Sun, Cai; Du, Ming-Xiu; Xu, Jian-Gang Dalton Transactions, Vol. 47, Issue 4 https://doi.org/10.1039/C7DT03679E	journal	January 2018
Structural origins of broadband emission from layered Pb–Br hybrid perovskites Smith, Matthew D.; Jaffe, Adam; Dohner, Emma R. Chemical Science, Vol. 8, Issue 6 https://doi.org/10.1039/C7SC01590A	journal	January 2017
Extra thermo- and water-stable one-dimensional organic–inorganic hybrid perovskite [ N -methyldabconium]PbI ₃ showing switchable dielectric behaviour, conductivity and bright yellow-green emission Xue, Chen; Yao, Zhi-Yuan; Zhang, Jin Chemical Communications, Vol. 54, Issue 34 https://doi.org/10.1039/C8CC00786A	journal	January 2018
White-light emission in a chiral one-dimensional organic–inorganic hybrid perovskite Peng, Yu; Yao, Yunpeng; Li, Lina Journal of Materials Chemistry C, Vol. 6, Issue 22 https://doi.org/10.1039/C8TC01150H	journal	January 2018
Transition metal complex dye-sensitized 3D iodoplumbates: syntheses, structures and photoelectric properties Yue, Cheng-Yang; Yue, Yun-Di; Sun, Hai-Xiao Chemical Communications, Vol. 55, Issue 48 https://doi.org/10.1039/C9CC02301A	journal	January 2019
The effect of the magnitude and direction of the dipoles of organic cations on the electronic structure of hybrid halide perovskites Maheshwari, Sudeep; Patwardhan, Sameer; Schatz, George C. Physical Chemistry Chemical Physics, Vol. 21, Issue 30 https://doi.org/10.1039/C9CP02866H	journal	January 2019
Synthesis, optoelectronic properties and applications of halide perovskites Chouhan, Lata; Ghimire, Sushant; Subrahmanyam, Challapalli Chemical Society Reviews, Vol. 49, Issue 10 https://doi.org/10.1039/C9CS00848A	journal	January 2020
A novel water-resistant and thermally stable black lead halide perovskite, phenyl viologen lead iodide C₂₂H₁₈N₂(PbI₃)₂ Latini, Alessandro; Quaranta, Simone; Menchini, Francesca Dalton Transactions, Vol. 49, Issue 8 https://doi.org/10.1039/C9DT04148F	journal	January 2020
PEA₂SnBr₄: a water-stable lead-free two-dimensional perovskite and demonstration of its use as a co-catalyst in hydrogen photogeneration and organic-dye degradation Romani, Lidia; Bala, Anu; Kumar, Vijay Journal of Materials Chemistry C, Vol. 8, Issue 27 https://doi.org/10.1039/D0TC02525A	journal	January 2020
Interfaces in metal halide perovskites probed by solid-state NMR spectroscopy Dahlman, Clayton J.; Kubicki, Dominik J.; Reddy, G. N. Manjunatha Journal of Materials Chemistry A, Vol. 9, Issue 35 https://doi.org/10.1039/D1TA03572J	journal	January 2021
Chemical exchange of labile protons by deuterium enables selective detection of pharmaceuticals in solid formulations Welton, Claire; Raval, Parth; Trébosc, Julien Chemical Communications, Vol. 58, Issue 82 https://doi.org/10.1039/D2CC04585K	journal	January 2022
Phase transitions and optical properties of the trigonal perovskite (CH₃NH₃)₂TeCl₆ Liu, Yuhan; Cockcroft, Jeremy K.; Chen, Zizhen Journal of Materials Chemistry C, Vol. 10, Issue 33 https://doi.org/10.1039/D2TC02372E	journal	January 2022
Templating and structural engineering in organic–inorganic perovskites Mitzi, David B. Journal of the Chemical Society, Dalton Transactions, Issue 1 https://doi.org/10.1039/b007070j	journal	January 2001
Porous ZnO–ZnSe nanocomposites for visible light photocatalysis Cho, Seungho; Jang, Ji-Wook; Lee, Jae Sung Nanoscale, Vol. 4, Issue 6 https://doi.org/10.1039/c2nr11869f	journal	January 2012
Fabrication and photoluminescence properties of porous CdSe Tiginyanu, I. M.; Monaico, E.; Ursaki, V. V. Applied Physics Letters, Vol. 86, Issue 6 https://doi.org/10.1063/1.1864240	journal	February 2005
Luminescence properties of defects in GaN Reshchikov, Michael A.; Morkoç, Hadis Journal of Applied Physics, Vol. 97, Issue 6 https://doi.org/10.1063/1.1868059	journal	March 2005
Porous semiconductor compounds Monaico, Eduard; Tiginyanu, Ion; Ursaki, Veaceslav Semiconductor Science and Technology, Vol. 35, Issue 10 https://doi.org/10.1088/1361-6641/ab9477	journal	September 2020
Local Polar Fluctuations in Lead Halide Perovskite Crystals Yaffe, Omer; Guo, Yinsheng; Tan, Liang Z. Physical Review Letters, Vol. 118, Issue 13 https://doi.org/10.1103/PhysRevLett.118.136001	journal	March 2017
Hexagonal Mesoporous Germanium Armatas, Gerasimos S.; Kanatzidis, Mercouri G. Science, Vol. 313, Issue 5788, p. 817-820 https://doi.org/10.1126/science.1130101	journal	August 2006
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Lee, M. M.; Teuscher, J.; Miyasaka, T. Science, Vol. 338, Issue 6107, p. 643-647 https://doi.org/10.1126/science.1228604	journal	October 2012
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber Stranks, S. D.; Eperon, G. E.; Grancini, G. Science, Vol. 342, Issue 6156, p. 341-344 https://doi.org/10.1126/science.1243982	journal	October 2013
Electron-hole diffusion lengths > 175 μm in solution-grown CH ₃ NH ₃ PbI ₃ single crystals Dong, Qingfeng; Fang, Yanjun; Shao, Yuchuan Science, Vol. 347, Issue 6225 https://doi.org/10.1126/science.aaa5760	journal	January 2015
Formation of Tetrahedron-Like Pores during Anodic Etching of (100) Oriented n-GaAs Langa, S.; Carstensen, J.; Tiginyanu, I. M. Electrochemical and Solid-State Letters, Vol. 5, Issue 1 https://doi.org/10.1149/1.1423803	journal	January 2002
Porous and Nanoporous Semiconductors and Emerging Applications Föll, Helmut; Carstensen, Jürgen; Frey, Stefan Journal of Nanomaterials, Vol. 2006 https://doi.org/10.1155/JNM/2006/91635	journal	January 2006
Structural Phase Transition and Electrical Conductivity of the Perovskite CH ₃ NH ₃ Sn ₁ - _x Pb _x Br ₃ and CsSnBr ₃ Yamada, Koji; Kawaguchi, Hiroshi; Matsui, Takashi Bulletin of the Chemical Society of Japan, Vol. 63, Issue 9 https://doi.org/10.1246/bcsj.63.2521	journal	September 1990
Porous Mixed Ionic Electronic Conductor Interlayers for Solid-State Batteries Kim, So Yeon; Li, Ju Energy Material Advances, Vol. 2021 https://doi.org/10.34133/2021/1519569	journal	January 2021

Similar Records

Porous and Water Stable 2D Hybrid Metal Halide with Broad Light Emission and Selective H₂O Vapor Sorption

Journal Article · Thu Jan 19 00:00:00 UTC 2023 · Angewandte Chemie (International Edition) · OSTI ID:2423562

Azmy, Ali; Li, Shunran; Angeli, Giasemi K.; +9 more

Metal Halide Scaffolded Assemblies of Organic Molecules with Enhanced Emission and Room Temperature Phosphorescence

Journal Article · Mon Aug 23 00:00:00 UTC 2021 · Journal of Physical Chemistry Letters · OSTI ID:1818639

Chaaban, Maya; Ben-Akacha, Azza; Worku, Michael; +9 more

Controlled Demolition and Reconstruction of Imidazolate and Carboxylate Metal–Organic Frameworks by Acid Gas Exposure and Linker Treatment

Journal Article · Thu Oct 21 00:00:00 UTC 2021 · Industrial and Engineering Chemistry Research · OSTI ID:1831612

Ganesan, Arvind; Purdy, Stephen C.; Yu, Zhenzi; +4 more

Title: Porous and Water Stable 2D Hybrid Metal Halide with Broad Light Emission and Selective H 2 O Vapor Sorption

Citation Formats

References (132)

Similar Records

Related Subjects

Title: Porous and Water Stable 2D Hybrid Metal Halide with Broad Light Emission and Selective H ₂ O Vapor Sorption