Pressure-controlled magnetism in 2D molecular layers

Huang, Yulong; Pathak, Arjun K.; Tsai, Jeng-Yuan; Rumsey, Clayton; Ivill, Mathew; Kramer, Noah; Hu, Yong; Trebbin, Martin; Yan, Qimin; Ren, Shenqiang

doi:10.1038/s41467-023-38991-8

Title: Pressure-controlled magnetism in 2D molecular layers

Journal Article · 01 June 2023 · Nature Communications

DOI: https://doi.org/10.1038/s41467-023-38991-8 · OSTI ID:1983426

;

; Tsai, Jeng-Yuan;

; Ivill, Mathew; Kramer, Noah; Hu, Yong;

;

Abstract Long-range magnetic ordering of two-dimensional crystals can be sensitive to interlayer coupling, enabling the effective control of interlayer magnetism towards voltage switching, spin filtering and transistor applications. With the discovery of two-dimensional atomically thin magnets, a good platform provides us to manipulate interlayer magnetism for the control of magnetic orders. However, a less-known family of two-dimensional magnets possesses a bottom-up assembled molecular lattice and metal-to-ligand intermolecular contacts, which lead to a combination of large magnetic anisotropy and spin-delocalization. Here, we report the pressure-controlled interlayer magnetic coupling of molecular layered compounds via chromium-pyrazine coordination. Room-temperature long-range magnetic ordering exhibits pressure tuning with a coercivity coefficient up to 4 kOe/GPa, while pressure-controlled interlayer magnetism also presents a strong dependence on alkali metal stoichiometry and composition. Two-dimensional molecular interlayers provide a pathway towards pressure-controlled peculiar magnetism through charge redistribution and structural transformation.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0023433

OSTI ID:: 1983426

Alternate ID(s):: OSTI ID: 2422249

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 14; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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