Reversible electrochemical conversion from selenium to cuprous selenide

Sandstrom, Sean K.; Jiang, Heng; Lucero, Marcos; Xu, Yunkai; Gallagher, Trenton C.; Cao, Mengyuan; Feng, Zhenxing; Ji, Xiulei

doi:10.1039/d1cc03983k

Title: Reversible electrochemical conversion from selenium to cuprous selenide

Journal Article · 17 September 2021 · ChemComm

DOI: https://doi.org/10.1039/d1cc03983k · OSTI ID:1982185

Sandstrom, Sean K. ^[1]; Jiang, Heng ^[1];

^[1]; Xu, Yunkai ^[1];

^[1]; Cao, Mengyuan ^[1];

^[1];

^[1]

Oregon State University, Corvallis, OR (United States)

Using elemental selenium as an electrode, the redox-active Cu²⁺/Cu⁺ ion is reversibly hosted via the sequential conversion reactions of Se → CuSe → Cu₃Se₂ → Cu₂Se. Here, the four-electron redox process from Se to Cu₂Se produces a high initial specific capacity of 1233 mA h g^–1 based on the mass of selenium alone or 472 mA h g^–1 based on the mass of Cu₂Se, the fully discharged product.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: SLAC National Accelerator Laboratory, Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1982185

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 82 Vol. 57; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (32)

Sodium-Ion Batteries Slater, Michael D.; Kim, Donghan; Lee, Eungje Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958 https://doi.org/10.1002/adfm.201200691	journal	May 2012
Mixed‐Valence Copper Selenide as an Anode for Ultralong Lifespan Rocking‐Chair Zn‐Ion Batteries: An Insight into its Intercalation/Extraction Kinetics and Charge Storage Mechanism Yang, Yang; Xiao, Jinfei; Cai, Jinyan Advanced Functional Materials, Vol. 31, Issue 3 https://doi.org/10.1002/adfm.202005092	journal	October 2020
Energetic Zinc Ion Chemistry: The Rechargeable Zinc Ion Battery Xu, Chengjun; Li, Baohua; Du, Hongda Angewandte Chemie, Vol. 124, Issue 4 https://doi.org/10.1002/ange.201106307	journal	December 2011
A Four‐Electron Sulfur Electrode Hosting a Cu ²⁺ /Cu ⁺ Redox Charge Carrier Wu, Xianyong; Markir, Aaron; Ma, Lu Angewandte Chemie, Vol. 131, Issue 36 https://doi.org/10.1002/ange.201905875	journal	July 2019
A Dual Plating Battery with the Iodine/[ZnI _x (OH ₂ ) _{4− x} ] ^{2− x} Cathode Hong, Jessica J.; Zhu, Liangdong; Chen, Cheng Angewandte Chemie, Vol. 131, Issue 44 https://doi.org/10.1002/ange.201909324	journal	September 2019
An Aqueous Dual‐Ion Battery Cathode of Mn ₃ O ₄ via Reversible Insertion of Nitrate Jiang, Heng; Wei, Zhixuan; Ma, Lu Angewandte Chemie International Edition, Vol. 58, Issue 16 https://doi.org/10.1002/anie.201814646	journal	April 2019
A review of halide charge carriers for rocking‐chair and dual‐ion batteries Sandstrom, Sean K.; Chen, Xin; Ji, Xiulei Carbon Energy, Vol. 3, Issue 4 https://doi.org/10.1002/cey2.110	journal	May 2021
In situ characterizations of solid–solid interfaces in solid‐state batteries using synchrotron X‐ray techniques Lucero, Marcos; Qiu, Shen; Feng, Zhenxing Carbon Energy https://doi.org/10.1002/cey2.131	journal	July 2021
The Renaissance of Proton Batteries Xu, Yunkai; Wu, Xianyong; Ji, Xiulei Small Structures, Vol. 2, Issue 5 https://doi.org/10.1002/sstr.202000113	journal	February 2021
Recent Progress on Engineering Highly Efficient Porous Semiconductor Photocatalysts Derived from Metal–Organic Frameworks Zhan, Wenwen; Sun, Liming; Han, Xiguang Nano-Micro Letters, Vol. 11, Issue 1 https://doi.org/10.1007/s40820-018-0235-z	journal	January 2019
Pitfalls in X-ray absorption spectroscopy analysis and interpretation: A practical guide for general users Wang, Maoyu; Feng, Zhenxing Current Opinion in Electrochemistry, Vol. 30 https://doi.org/10.1016/j.coelec.2021.100803	journal	December 2021
Tuning crystal phase and morphology of copper selenide nanostructures and their visible-light photocatalytic applications to degrade organic pollutants Nouri, Morteza; Yousefi, Ramin; Zare-Dehnavi, Nasser Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 586 https://doi.org/10.1016/j.colsurfa.2019.124196	journal	February 2020
Scientific Challenges for the Implementation of Zn-Ion Batteries Blanc, Lauren E.; Kundu, Dipan; Nazar, Linda F. Joule, Vol. 4, Issue 4 https://doi.org/10.1016/j.joule.2020.03.002	journal	April 2020
Potassium secondary cell based on Prussian blue cathode Eftekhari, Ali Journal of Power Sources, Vol. 126, Issue 1-2, p. 221-228 https://doi.org/10.1016/j.jpowsour.2003.08.007	journal	February 2004
Chloride ion battery: A new member in the rechargeable battery family Zhao, Xiangyu; Ren, Shuhua; Bruns, Michael Journal of Power Sources, Vol. 245 https://doi.org/10.1016/j.jpowsour.2013.07.001	journal	January 2014
Recent developments and future perspectives of anionic batteries Karkera, Guruprakash; Reddy, M. Anji; Fichtner, Maximilian Journal of Power Sources, Vol. 481 https://doi.org/10.1016/j.jpowsour.2020.228877	journal	January 2021
Ultra-high thermoelectric performance in graphene incorporated Cu2Se: Role of mismatching phonon modes Li, Meng; Cortie, David L.; Liu, Jixing Nano Energy, Vol. 53 https://doi.org/10.1016/j.nanoen.2018.09.041	journal	November 2018
Rechargeable Ca-Ion Batteries: A New Energy Storage System Lipson, Albert L.; Pan, Baofei; Lapidus, Saul H. Chemistry of Materials, Vol. 27, Issue 24 https://doi.org/10.1021/acs.chemmater.5b04027	journal	December 2015
An Energetic CuS–Cu Battery System Based on CuS Nanosheet Arrays Wang, Yichun; Chao, Dongliang; Wang, Zhenzhu ACS Nano, Vol. 15, Issue 3 https://doi.org/10.1021/acsnano.1c00075	journal	March 2021
A New Class of Lithium and Sodium Rechargeable Batteries Based on Selenium and Selenium–Sulfur as a Positive Electrode Abouimrane, Ali; Dambournet, Damien; Chapman, Karena W. Journal of the American Chemical Society, Vol. 134, Issue 10 https://doi.org/10.1021/ja211766q	journal	February 2012
(De)Lithiation Mechanism of Li/SeS _x ( x = 0–7) Batteries Determined by in Situ Synchrotron X-ray Diffraction and X-ray Absorption Spectroscopy Cui, Yanjie; Abouimrane, Ali; Lu, Jun Journal of the American Chemical Society, Vol. 135, Issue 21 https://doi.org/10.1021/ja402597g	journal	May 2013
An ultrafast rechargeable aluminium-ion battery Lin, Meng-Chang; Gong, Ming; Lu, Bingan Nature, Vol. 520, Issue 7547 https://doi.org/10.1038/nature14340	journal	April 2015
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F. Nature Materials, Vol. 8, Issue 6, p. 500-506 https://doi.org/10.1038/nmat2460	journal	May 2009
Towards a calcium-based rechargeable battery Ponrouch, A.; Frontera, C.; Bardé, F. Nature Materials, Vol. 15, Issue 2 https://doi.org/10.1038/nmat4462	journal	October 2015
High-power Mg batteries enabled by heterogeneous enolization redox chemistry and weakly coordinating electrolytes Dong, Hui; Tutusaus, Oscar; Liang, Yanliang Nature Energy, Vol. 5, Issue 12 https://doi.org/10.1038/s41560-020-00734-0	journal	November 2020
Aqueous Li-ion battery enabled by halogen conversion–intercalation chemistry in graphite Yang, Chongyin; Chen, Ji; Ji, Xiao Nature, Vol. 569, Issue 7755 https://doi.org/10.1038/s41586-019-1175-6	journal	May 2019
Li–Se battery: absence of lithium polyselenides in carbonate based electrolyte Cui, Yanjie; Abouimrane, Ali; Sun, Cheng-Jun Chem. Commun., Vol. 50, Issue 42 https://doi.org/10.1039/C4CC00934G	journal	January 2014
The rise of lithium–selenium batteries Eftekhari, Ali Sustainable Energy & Fuels, Vol. 1, Issue 1 https://doi.org/10.1039/C6SE00094K	journal	January 2017
Rechargeable metal batteries based on selenium cathodes: progress, challenges and perspectives Gu, Xingxing; Tang, Tianyu; Liu, Xiaoteng Journal of Materials Chemistry A, Vol. 7, Issue 19 https://doi.org/10.1039/C8TA12537F	journal	January 2019
The rechargeable aluminum-ion battery Jayaprakash, N.; Das, S. K.; Archer, L. A. Chemical Communications, Vol. 47, Issue 47 https://doi.org/10.1039/c1cc15779e	journal	January 2011
Batteries based on fluoride shuttle Anji Reddy, M.; Fichtner, M. Journal of Materials Chemistry, Vol. 21, Issue 43, p. 17059-17062 https://doi.org/10.1039/c1jm13535j	journal	October 2011
Charge carriers in rechargeable batteries: Na ions vs. Li ions Hong, Sung You; Kim, Youngjin; Park, Yuwon Energy & Environmental Science, Vol. 6, Issue 7 https://doi.org/10.1039/c3ee40811f	journal	January 2013

Similar Records

Investigation of Rechargeable Calcium Metal-Selenium Batteries Enabled by Borate-Based Electrolytes

Journal Article · 2023 · Chemistry of Materials · OSTI ID:1989122

Kim, Sanghyeon; Hahn, Nathan T.; Fister, Timothy T.; +7 more

Selenium Impregnated Monolithic Carbons as Free-Standing Cathodes for High Volumetric Energy Lithium and Sodium Metal Batteries

Journal Article · 2017 · Advanced Energy Materials · OSTI ID:1505434

Ding, Jia; Zhou, Hui; Zhang, Hanlei; +2 more

Long Cycle Life, Low Self-Discharge Sodium-Selenium Batteries with High Selenium Loading and Suppressed Polyselenide Shuttling

Journal Article · 2017 · Advanced Energy Materials · OSTI ID:1596645

Wang, Hui; Jiang, Yang; Manthiram, Arumugam

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Chemistry

Title: Reversible electrochemical conversion from selenium to cuprous selenide

Citation Formats

References (32)

Similar Records

Related Subjects