A Low-Voltage Layered Na2TiGeO5 Anode for Lithium-Ion Battery

Liu, Zhiwei; He, Di; Wang, Boya; Wu, Tianhao; Zhao, Shu; Li, Xunlu; He, Shiman; Liang, Yuan; Zhou, Yongning; Sun, Shuhui; Yu, Haijun

doi:10.1002/smll.202107608

Title: A Low-Voltage Layered Na₂TiGeO₅ Anode for Lithium-Ion Battery

Journal Article · 19 February 2022 · Small

DOI: https://doi.org/10.1002/smll.202107608 · OSTI ID:1981441

Liu, Zhiwei ^[1]; He, Di ^[2]; Wang, Boya ^[2]; Wu, Tianhao ^[2]; Zhao, Shu ^[2]; Li, Xunlu ^[3]; He, Shiman ^[2]; Liang, Yuan ^[2]; Zhou, Yongning ^[3]; Sun, Shuhui ^[4];

^[2]

Beijing University of Technology (China); Univ. of Science and Technology, Beijing (China)
Beijing University of Technology (China)
Fudan Univ., Shanghai (China)
National Institute of Scientific Research (INRS) (Canada)

Titanium-based anode materials have achieved much progress with the wide studies in lithium-ion batteries. However, these known materials usually possess high discharge voltage platforms and limited energy densities. In this work, a titanium-based oxide of Na₂TiGeO₅ with layered structure, two-dimensional lamellar frame and exposed highly active (001) facet, exhibiting good electrochemical performance in terms of high capacity (410 mAh g^–1 with a current density of 50 mA g^–1), excellent rate capability and cycling stability with no obvious capacity attenuation after 4000 cycles, is reported. The appropriate discharge voltage plateau at around 0.2 V endows the Na₂TiGeO₅ anode material high security compared with graphite and high energy density compared with spinel Li₄Ti₅O₁₂. Combining the electrochemical tests and the density functional theory calculations, the Li⁺ storage mechanism of Na₂TiGeO₅ is elucidated and the conversion reaction process is revealed. More importantly, this study provides a way to develop low-voltage and high-capacity titanium-based anode materials for efficient energy storage.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: SC0012704

OSTI ID:: 1981441

Journal Information:: Small, Journal Name: Small Journal Issue: 14 Vol. 18; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Title: A Low-Voltage Layered Na2TiGeO5 Anode for Lithium-Ion Battery

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References (51)

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Title: A Low-Voltage Layered Na₂TiGeO₅ Anode for Lithium-Ion Battery