Fluoro–nitrogen Cations

Vij, Ashwani; Wilson, William W.; Haiges, Ralf; Edwards, Kyle C.; Dixon, David A.; Christe, Karl O.

doi:10.1002/anie.202116565

Title: Fluoro–nitrogen Cations

Journal Article · Mon Dec 13 00:00:00 UTC 2021 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.202116565 · OSTI ID:1981387

Vij, Ashwani ^[1]; Wilson, William W. ^[1]; Haiges, Ralf ^[1]; Edwards, Kyle C. ^[2]; Dixon, David A. ^[2];

^[1]

Univ. of Southern California, Los Angeles, CA (United States)
Univ. of Alabama, Tuscaloosa, AL (United States)

The crystal structures of [NH₃F]⁺[CF₃SO₃]^–, [NH₂F₂]⁺[SbF₆]^–, and [N₂F₃]⁺[Sb₃F₁₆]^– have been determined, representing the first structural characterizations of these simple fluoro-nitrogen cations. The influences of the hybridization of the central nitrogen atom and of the number of fluorine substituents on the N–F bond lengths are evaluated for the series N₂F⁺, N₂F₃⁺, NF₂O⁺, NH₃F⁺, NH₂F₂⁺, and NF₄⁺. Here it is shown that the N–F bond length decreases from 1.40 Å to 1.26 Å with increasing fluorine substitution and increasing s-character of the nitrogen atom, and that unusual N–F bond lengths reported in the previous literature are caused by disorder problems.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Catalysis Program

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1981387

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 8 Vol. 61; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Chemistry
fluoro-nitrogen
fluoroammonium
fluorodiazonium
fluoronitronium
trifluoro-diazenium

CSD 2127631: Experimental Crystal Structure Determination Ashwani, Vij,; W., Wilson, William; Ralf, Haiges, https://doi.org/10.25505/fiz.icsd.cc29dz8z The current record is supplemented by this dataset	dataset	January 2022
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Title: Fluoro–nitrogen Cations

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