A Heteromeric Carboxylic Acid Based Single-Crystalline Crosslinked Organic Framework

Liang, Rongran; Samanta, Jayanta; Shao, Baihao; Zhang, Mingshi; Staples, Richard J.; Chen, Albert D.; Tang, Miao; Wu, Yuyang; Aprahamian, Ivan; Ke, Chenfeng

doi:10.1002/anie.202109987

Title: A Heteromeric Carboxylic Acid Based Single-Crystalline Crosslinked Organic Framework

Journal Article · 09 August 2021 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.202109987 · OSTI ID:1981381

Liang, Rongran ^[1]; Samanta, Jayanta ^[1]; Shao, Baihao ^[1]; Zhang, Mingshi ^[1]; Staples, Richard J. ^[2]; Chen, Albert D. ^[1]; Tang, Miao ^[1]; Wu, Yuyang ^[3];

^[1];

^[1]

Dartmouth College, Hanover, NH (United States)
Michigan State University, East Lansing, MI (United States)
Northwestern University, Evanston, IL (United States)

The development of large pore single-crystalline covalently linked organic frameworks is critical in revealing the detailed structure-property relationship with substrates. One emergent approach is to photo-crosslink hydrogen-bonded molecular crystals. Introducing complementary hydrogen-bonded carboxylic acid building blocks is promising to construct large pore networks, but these molecules often form interpenetrated networks or non-porous solids. In this report we introduced heteromeric carboxylic acid dimers to construct a non-interpenetrated molecular crystal. Crosslinking this crystal precursor with dithiols afforded a large pore single-crystalline hydrogen-bonded crosslinked organic framework H_COF-101. X-ray diffraction analysis revealed H_COF-101 as an interlayer connected hexagonal network, which possesses flexible linkages and large porous channels to host a hydrazone photoswitch. Multicycle Z/E-isomerization of the hydrazone took place reversibly within H_COF-101, showcasing the potential use of H_COF-101 for optical information storage.

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Research Organization:: Dartmouth College, Hanover, NH (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Sponsoring Organization:: American Chemical Society Petroleum Research Fund; Beckman Young Investigator Program; National Science Foundation (NSF); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231; AC02-06CH11357

OSTI ID:: 1981381

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 43 Vol. 60; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
heteromeric carboxylic acid dimer
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Title: A Heteromeric Carboxylic Acid Based Single-Crystalline Crosslinked Organic Framework

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