Structural diversity among multinary pnictide oxides: a minireview focused on semiconducting and superconducting heteroanionic materials

Baranets, Sviatoslav; Darone, Gregory M.; Bobev, Svilen

doi:10.1515/zkri-2021-2079

Title: Structural diversity among multinary pnictide oxides: a minireview focused on semiconducting and superconducting heteroanionic materials

Journal Article · 08 February 2022 · Zeitschrift fuer Kristallographie. Crystalline Materials

DOI: https://doi.org/10.1515/zkri-2021-2079 · OSTI ID:1981003

Baranets, Sviatoslav ^[1]; Darone, Gregory M. ^[2]; Bobev, Svilen ^[1]

University of Delaware, Newark, DE (United States)
The Charter School of Wilmington , Wilmington , DE (United States)

Incorporating different anions with varied ionic sizes and charges is a rapidly growing approach to bring out unusual physical properties among various classes of solid-state materials, pnictides and chalcogenides in particular. This minireview is focused on hetero-anionic materials based on the pnictogens, which have been demonstrated to offer an impressive diversity of crystal chemistry and electronic structures. In addition, many pnictide oxides or oxypnictides, over the course of the last decade, have been shown to exhibit a broad spectrum of superconducting, magnetic, and semiconducting properties. However, the structural diversity of the mixed-anion materials is far greater than the several known structure types, or their variants, of the well-known layered superconductive materials. Therefore, with this treatise, we aim to provide a comprehensive overview of the crystal chemistry of pnictide oxides by recounting almost 40 different structures of such ternary and multinary compounds. In addition to the structural aspects, we also highlight some of the challenges associated with the synthesis, and briefly summarize reported, to date, physical properties of this remarkable class of solids.

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Research Organization:: University of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: SC0008885

OSTI ID:: 1981003

Journal Information:: Zeitschrift fuer Kristallographie. Crystalline Materials, Journal Name: Zeitschrift fuer Kristallographie. Crystalline Materials Journal Issue: 1-3 Vol. 237; ISSN 2194-4946

Publisher:: de GruyterCopyright Statement

Country of Publication:: United States

Language:: English

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A Possible New Parent Compound Sr₄Al₂O₆Fe₂As₂ with High-T_C Superconductivity Zhang, Yun-Li; Zhang, Ji-Hua; Tao, Xiang-Ming Journal of the Physical Society of Japan, Vol. 81, Issue 2 https://doi.org/10.1143/JPSJ.81.024713	journal	February 2012
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Titanium Pnictide Oxide Superconductors Yajima, Takeshi Condensed Matter, Vol. 2, Issue 1 https://doi.org/10.3390/condmat2010004	journal	January 2017
On the New Oxyarsenides Eu5Zn2As5O and Eu5Cd2As5O Darone, Gregory M.; Baranets, Sviatoslav A.; Bobev, Svilen Crystals, Vol. 10, Issue 6 https://doi.org/10.3390/cryst10060475	journal	June 2020
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Synthesis and Physical Properties of the New Oxybismuthides BaTi ₂ Bi ₂ O and (SrF) ₂ Ti ₂ Bi ₂ O with a d ¹ Square Net Yajima, Takeshi; Nakano, Kousuke; Takeiri, Fumitaka Journal of the Physical Society of Japan, Vol. 82, Issue 1 https://doi.org/10.7566/JPSJ.82.013703	journal	January 2013
Synthesis of New Layered Oxypnictides Sr ₂ CrO ₂ (FeAs) ₂ Eguchi, Naoya; Ishikawa, Fumihiro; Kodama, Michihiro Journal of the Physical Society of Japan, Vol. 82, Issue 4 https://doi.org/10.7566/JPSJ.82.045002	journal	April 2013
Study on Magnetism and Electronic Structure of New Layered Compound Sr₃Sc₂O₅Co₂As₂ with Body-Centered Crystal Structure Ohta, Hiroto; Suzuki, Atsushi; Katori, Hiroko Aruga Journal of the Physical Society of Japan, Vol. 88, Issue 5 https://doi.org/10.7566/JPSJ.88.054714	journal	May 2019

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