Polyanionic insertion hosts for aqueous rechargeable batteries

Sharma, Lalit; Manthiram, Arumugam

doi:10.1039/d1ta11080b

Title: Polyanionic insertion hosts for aqueous rechargeable batteries

Journal Article · 22 February 2022 · Journal of Materials Chemistry. A

DOI: https://doi.org/10.1039/d1ta11080b · OSTI ID:1978848

Sharma, Lalit ^[1];

^[1]

Univ. of Texas, Austin, TX (United States)

Safety concerns and costs of present-day lithium-ion batteries (LIBs) are prompting the development of alternate battery technologies with different types of electrolyte (e.g., solid-state, gel-polymer, aqueous, etc.); notably, systems based on aqueous electrolytes have emerged as a promising alternative, especially for grid storage applications. The last decade has witnessed a considerable spike in the research carried out on aqueous batteries. However, the narrow operating voltage window of aqueous electrolytes and the structural instability of materials in aqueous media demand proper selection of cathode materials to achieve desirable energy density. Polyanionic materials can be an ideal choice as they are structurally more stable and exhibit tunable redox potentials. This class of materials is considered as a storehouse in which many materials can be realized by substituting different polyanionic subunits. Here, this review highlights some of the recent advances made in the polyanionic class of cathode materials for rechargeable aqueous batteries (Li-, Na- and Zn-ion batteries). The challenges facing the field, possible remedies to overcome them and future perspectives are also presented.

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE

Grant/Contract Number:: SC0005397

OSTI ID:: 1978848

Alternate ID(s):: OSTI ID: 1848010

Journal Information:: Journal of Materials Chemistry. A, Vol. 10, Issue 12; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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