Nanoconfinement and mass transport in metal–organic frameworks

Sharp, Conor H.; Bukowski, Brandon C.; Li, Hongyu; Johnson, Eric M.; Ilic, Stefan; Morris, Amanda J.; Gersappe, Dilip; Snurr, Randall Q.; Morris, John R.

doi:10.1039/d1cs00558h

Title: Nanoconfinement and mass transport in metal–organic frameworks

Journal Article · 25 August 2021 · Chemical Society Reviews

DOI: https://doi.org/10.1039/d1cs00558h · OSTI ID:1978770

^[1];

^[2]; Li, Hongyu ^[3]; Johnson, Eric M. ^[4]; Ilic, Stefan ^[4];

^[4]; Gersappe, Dilip ^[3];

^[2];

^[4]

U.S. Naval Research Laboratory, Washington, DC (United States); OSTI
Northwestern University, Evanston, IL (United States)
Stony Brook University, NY (United States)
Virginia Polytechnic Institute and State University (Virginia Tech), Blacksburg, VA (United States)

The ubiquity of metal–organic frameworks in recent scientific literature underscores their highly versatile nature. MOFs have been developed for use in a wide array of applications, including: sensors, catalysis, separations, drug delivery, and electrochemical processes. Often overlooked in the discussion of MOF-based materials is the mass transport of guest molecules within the pores and channels. Given the wide distribution of pore sizes, linker functionalization, and crystal sizes, molecular diffusion within MOFs can be highly dependent on the MOF-guest system. In this paper, we discuss the major factors that govern the mass transport of molecules through MOFs at both the intracrystalline and intercrystalline scale; provide an overview of the experimental and computational methods used to measure guest diffusivity within MOFs; and highlight the relevance of mass transfer in the applications of MOFs in electrochemical systems, separations, and heterogeneous catalysis.

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Research Organization:: University of Washington, Seattle, WA (United States)

Sponsoring Organization:: National Science Foundation (NSF); U.S. Army Research Office; USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012445

OSTI ID:: 1978770

Journal Information:: Chemical Society Reviews, Journal Name: Chemical Society Reviews Journal Issue: 20 Vol. 50; ISSN 0306-0012

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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