Synthesis, characterization, and high-pressure studies of a 3D berkelium(III) carboxylate framework material

Sperling, Joseph M.; Beck, Nicholas; Scheibe, Benjamin; Bai, Zhuanling; Brannon, Jacob; Gomez-Martinez, Daniela; Grödler, Dennis; Johnson, Jason A.; Lin, Xinsong; Rotermund, Brian M.; Albrecht-Schönzart, Thomas E.

doi:10.1039/d1cc06958f

Title: Synthesis, characterization, and high-pressure studies of a 3D berkelium(III) carboxylate framework material

Journal Article · 12 January 2022 · ChemComm

DOI: https://doi.org/10.1039/d1cc06958f · OSTI ID:1978752

^[1];

^[2];

^[1]; Lin, Xinsong ^[1];

^[1]; Albrecht-Schönzart, Thomas E. ^[1]

Florida State University, Tallahassee, FL (United States)
University of Cologne (Germany)

Here, a berkelium(III) mellitate, Bk₂[C₆(CO₂)₆](H₂O)₈·2H₂O, was synthesized and rapidly crystallized by reacting mellitic acid, C₆(CO₂H)₆, and BkBr₃·nH₂O in an aqueous medium. Single crystal X-ray diffraction shows that the compound crystallizes as a three-dimensional framework isostructural with Pu(III), Am(III), and Cm(III) mellitates. UV-vis-NIR spectroscopic studies as a function of pressure were performed using a diamond anvil cell and show that the 5f → 5f transitions of Bk³⁺ display enhanced hypsochromic shifting when compared to other An(III) mellitates.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Florida State University, Tallahassee, FL (United States); University of Cologne (Germany)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0010677

OSTI ID:: 1978752

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 13 Vol. 58; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (35)

[An(H2O)9](CF3SO3)3 (An=U-Cm, Cf): Exploring Their Stability, Structural Chemistry, and Magnetic Behavior by Experiment and Theory Apostolidis, Christos; Schimmelpfennig, Bernd; Magnani, Nicola Angewandte Chemie International Edition, Vol. 49, Issue 36 https://doi.org/10.1002/anie.201001077	journal	June 2010
Polyhedral Structures with an Odd Number of Vertices: Nine-Coordinate Metal Compounds Ruiz-Martínez, Antonio; Casanova, David; Alvarez, Santiago Chemistry - A European Journal, Vol. 14, Issue 4 https://doi.org/10.1002/chem.200701137	journal	January 2008
The absorption spectra of Bk3+ and Bk4+ in solution Gutmacher, R. G.; Hulet, E. K.; Lougheed, R. Journal of Inorganic and Nuclear Chemistry, Vol. 29, Issue 9 https://doi.org/10.1016/0022-1902(67)80289-6	journal	September 1967
Crystal structures and lattice parameters of the compounds of berkelium—IV berkelium trifluoride Peterson, J. R.; Cunningham, B. B. Journal of Inorganic and Nuclear Chemistry, Vol. 30, Issue 7 https://doi.org/10.1016/0022-1902(68)80353-7	journal	August 1968
Electron-transfer and f → d absorption bands of some lanthanide and actinide complexes and the standard (III–IV) oxidation potentials for each member of the lanthanide and actinide series Nugent, L. J.; Baybarz, R. D.; Burnett, J. L. Journal of Inorganic and Nuclear Chemistry, Vol. 33, Issue 8 https://doi.org/10.1016/0022-1902(71)80226-9	journal	August 1971
The formal potential of the Bk(IV)-Bk(III) couple in several media Stokely, J. R.; Baybarz, R. D.; Peterson, J. R. Journal of Inorganic and Nuclear Chemistry, Vol. 34, Issue 1 https://doi.org/10.1016/0022-1902(72)80411-1	journal	January 1972
Actinide targets for the synthesis of super-heavy elements Roberto, J. B.; Alexander, C. W.; Boll, R. A. Nuclear Physics A, Vol. 944 https://doi.org/10.1016/j.nuclphysa.2015.06.009	journal	December 2015
Trivalent f-Element Squarates, Squarate-Oxalates, and Cationic Materials, and the Determination of the Nine-Coordinate Ionic Radius of Cf(III) Brenner, Natasha; Sperling, Joseph M.; Poe, Todd N. Inorganic Chemistry, Vol. 59, Issue 13 https://doi.org/10.1021/acs.inorgchem.0c01254	journal	June 2020
Pressure-Induced Spectroscopic Changes in a Californium 1D Material Are Twice as Large as Found in the Holmium Analog Sperling, Joseph M.; Warzecha, Evan; Windorff, Cory J. Inorganic Chemistry, Vol. 59, Issue 15 https://doi.org/10.1021/acs.inorgchem.0c01290	journal	July 2020
A Single Small-Scale Plutonium Redox Reaction System Yields Three Crystallographically-Characterizable Organoplutonium Complexes Windorff, Cory J.; Sperling, Joseph M.; Albrecht-Schönzart, Thomas E. Inorganic Chemistry, Vol. 59, Issue 18 https://doi.org/10.1021/acs.inorgchem.0c01671	journal	September 2020
Exploring the Oxidation States of Neptunium with Schiff Base Coordination Complexes Klamm, Bonnie E.; Windorff, Cory J.; Celis-Barros, Cristian Inorganic Chemistry, Vol. 59, Issue 24 https://doi.org/10.1021/acs.inorgchem.0c02455	journal	November 2020
Pronounced Pressure Dependence of Electronic Transitions for Americium Compared to Isomorphous Neodymium and Samarium Mellitates Sperling, Joseph M.; Warzecha, Evan; Klamm, Bonnie E. Inorganic Chemistry, Vol. 60, Issue 1 https://doi.org/10.1021/acs.inorgchem.0c03293	journal	December 2020
Structural and Spectroscopic Investigation of Two Plutonium Mellitates Sperling, Joseph M.; Gaiser, Alyssa N.; Windorff, Cory J. Inorganic Chemistry, Vol. 59, Issue 5 https://doi.org/10.1021/acs.inorgchem.9b03432	journal	February 2020
Inkjet Printing of Lanthanide–Organic Frameworks for Anti-Counterfeiting Applications da Luz, Leonis L.; Milani, Raquel; Felix, Jorlandio F. ACS Applied Materials & Interfaces, Vol. 7, Issue 49 https://doi.org/10.1021/acsami.5b06301	journal	December 2015
Relativity and the periodic system of elements Pyykko, Pekka; Desclaux, Jean Paul Accounts of Chemical Research, Vol. 12, Issue 8 https://doi.org/10.1021/ar50140a002	journal	August 1979
Absorption spectrophotometric and x-ray diffraction studies of the trichlorides of berkelium-249 and californium-249 Peterson, J. R.; Young, J. P.; Ensor, D. D. Inorganic Chemistry, Vol. 25, Issue 21 https://doi.org/10.1021/ic00241a015	journal	October 1986
Syntheses, Structures, and Spectroscopic Properties of Plutonium and Americium Phosphites and the Redetermination of the Ionic Radii of Pu(III) and Am(III) Cross, Justin N.; Villa, Eric M.; Wang, Shuao Inorganic Chemistry, Vol. 51, Issue 15 https://doi.org/10.1021/ic300958z	journal	July 2012
Microchemical preparation of tricyclopentadienyl compounds of berkelium, californium, and some lanthanide elements Laubereau, Peter G.; Burns, John H. Inorganic Chemistry, Vol. 9, Issue 5 https://doi.org/10.1021/ic50087a018	journal	May 1970
Chemical consequences of radioactive decay. 1. Study of californium-249 ingrowth into crystalline berkelium-249 tribromide: a new crystalline phase of californium tribromide Young, J. P.; Haire, R. G.; Peterson, J. R. Inorganic Chemistry, Vol. 19, Issue 8 https://doi.org/10.1021/ic50210a003	journal	August 1980
Lanthanide and Actinide Contractions: Relativistic and Shell Structure Effects Seth, Michael; Dolg, Michael; Fulde, Peter Journal of the American Chemical Society, Vol. 117, Issue 24 https://doi.org/10.1021/ja00129a026	journal	June 1995
Reactions of the Uranium Carbides with Nitric Acid ¹ Ferris, Leslie M.; Bradley, Mildred J. Journal of the American Chemical Society, Vol. 87, Issue 8 https://doi.org/10.1021/ja01086a016	journal	April 1965
Electronic Structure and Properties of Berkelium Iodates Silver, Mark A.; Cary, Samantha K.; Garza, Alejandro J. Journal of the American Chemical Society, Vol. 139, Issue 38 https://doi.org/10.1021/jacs.7b05569	journal	September 2017
Synthesis and Characterization of Tris-chelate Complexes for Understanding f -Orbital Bonding in Later Actinides Galley, Shane S.; Pattenaude, Scott A.; Gaggioli, Carlo Alberto Journal of the American Chemical Society, Vol. 141, Issue 6 https://doi.org/10.1021/jacs.8b10251	journal	January 2019
Acid Leaching of Uranium and Thorium Carbides Pauson, P. L.; McLEAN, J.; Clelland, W. J. Nature, Vol. 197, Issue 4873 https://doi.org/10.1038/1971200a0	journal	March 1963
Experimental detection of α-particles from the radioactive decay of natural bismuth de Marcillac, Pierre; Coron, Noël; Dambier, Gérard Nature, Vol. 422, Issue 6934 https://doi.org/10.1038/nature01541	journal	April 2003
Creation of an unexpected plane of enhanced covalency in cerium(III) and berkelium(III) terpyridyl complexes Gaiser, Alyssa N.; Celis-Barros, Cristian; White, Frankie D. Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-27576-y	journal	December 2021
Compression of curium pyrrolidine-dithiocarbamate enhances covalency Sperling, Joseph M.; Warzecha, Evan J.; Celis-Barros, Cristian Nature, Vol. 583, Issue 7816 https://doi.org/10.1038/s41586-020-2479-2	journal	July 2020
Schiff-base coordination complexes with plutonium( iv ) and cerium( iv ) Klamm, Bonnie E.; Windorff, Cory J.; Marsh, Matthew L. Chemical Communications, Vol. 54, Issue 62 https://doi.org/10.1039/C8CC03571G	journal	January 2018
A series of dithiocarbamates for americium, curium, and californium Cary, Samantha K.; Su, Jing; Galley, Shane S. Dalton Transactions, Vol. 47, Issue 41 https://doi.org/10.1039/C8DT02658K	journal	January 2018
Absorption spectrum of CfCl ₃ Carnall, William T.; Fried, Sherman; Wagner, Frank The Journal of Chemical Physics, Vol. 58, Issue 5 https://doi.org/10.1063/1.1679455	journal	March 1973
Electronic energy level and intensity correlations in the spectra of the trivalent actinide aquo ions. III. Bk ³ ⁺ Carnall, W. T.; Beitz, J. V.; Crosswhite, H. The Journal of Chemical Physics, Vol. 80, Issue 6 https://doi.org/10.1063/1.446980	journal	March 1984
A systematic analysis of the spectra of trivalent actinide chlorides in D _{3 h} site symmetry Carnall, William T. The Journal of Chemical Physics, Vol. 96, Issue 12 https://doi.org/10.1063/1.462278	journal	June 1992
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Assessment of a Heterogeneous PWR Assembly for Plutonium and Minor Actinide Recycle Taiwo, T. A.; Kim, T. K.; Stillman, J. A. Nuclear Technology, Vol. 155, Issue 1 https://doi.org/10.13182/NT06-A3744	journal	July 2006
Spent Nuclear Fuel Bruno, J.; Ewing, R. C. Elements, Vol. 2, Issue 6 https://doi.org/10.2113/gselements.2.6.343	journal	December 2006

Similar Records

Effects of the Inverse Trans-Influence in a Berkelium(III) Phosphine Oxide Complex

Journal Article · 2025 · Inorganic Chemistry · OSTI ID:3005019

Huffman, Zachary K.; Wineinger, Hannah B.; Brannon, Jacob P.; +8 more

Two Neptunium(III) Mellitate Coordination Polymers: Completing the Series Np–Cf of Trans-Uranic An(III) Mellitates

Journal Article · 2022 · Inorganic Chemistry · OSTI ID:3017269

Beck, Nicholas B.; Bai, Zhuanling; Brannon, Jacob P.; +7 more

Energy levels of neutral and singly ionized berkelium, /sup 249/Bk I and II

Journal Article · 1987 · J. Opt. Soc. Am. B: Opt. Phys.; (United States) · OSTI ID:6237526

Worden, E F; Conway, J G; Blaise, J

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Chemistry

Title: Synthesis, characterization, and high-pressure studies of a 3D berkelium(III) carboxylate framework material

Citation Formats

References (35)

Linked Research (1)

Similar Records

Related Subjects