Preparation, characterization, and structural studies of new ruthenium(II) and ruthenium(III) complexes incorporating pyrazole ligands

Shi, Yifan; Arif, Atta M.; Ernst, Richard D.

doi:10.1016/j.poly.2021.115365

Title: Preparation, characterization, and structural studies of new ruthenium(II) and ruthenium(III) complexes incorporating pyrazole ligands

Journal Article · 11 July 2021 · Polyhedron

DOI: https://doi.org/10.1016/j.poly.2021.115365 · OSTI ID:1977587

Shi, Yifan ^[1]; Arif, Atta M. ^[2]; Ernst, Richard D. ^[2]

Univ. of Utah, Salt Lake City, UT (United States); OSTI
Univ. of Utah, Salt Lake City, UT (United States)

Multimetallic complexes containing disparate metals have been established to have practical utilities. We previously reported a strategy for preparing such species by using combinations of neutral pyrazole (Hpyz, C₃N₂H₄) and anionic pyrazolyl ligands (pyz, C₃N₂H₃^–), and herein are reported several new complexes that should be capable of incorporating a second metal center. Two of the complexes, [Ru(1,5-cod)(Hpyz)₃Cl][BPh₄] and Ru(1,5-cod)(Hpyz)₂(pyz)₂ (cod = cyclooctadiene), were prepared from [Ru(cod)Cl₂]₂, while [Ru(tmeda)(Hpyz)₂Cl₂][BF₄] (tmeda = tetramethylethylenediamine) was prepared from the neutral Ru(II) complex Ru(tmeda)(Hpyz)₂Cl₂ via one electron oxidation by the ferricinium ion. The first two complexes, one cationic and the other uncharged, involve Ru(II), while the tmeda complex involves Ru(III). Finally, all three species have been structurally characterized.

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Research Organization:: Univ. of Kentucky, Lexington, KY (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE); USDOE Office of Fossil Energy and Carbon Management (FECM)

Grant/Contract Number:: FC26-05NT42456

OSTI ID:: 1977587

Journal Information:: Polyhedron, Journal Name: Polyhedron Journal Issue: C Vol. 209; ISSN 0277-5387

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Bimetallic complexes
Chemistry
Crystallography
Polymetallic complexes
Pyrazole complexes
Pyrazolyl complexes
Ruthenium complexes

CCDC 2084225: Experimental Crystal Structure Determination Yifan, Shi,; M., Arif, Atta; D., Ernst, Richard https://doi.org/10.5517/ccdc.csd.cc27yt23 The current record is supplemented by this dataset	dataset	January 2021
CCDC 2084226: Experimental Crystal Structure Determination Yifan, Shi,; M., Arif, Atta; D., Ernst, Richard https://doi.org/10.5517/ccdc.csd.cc27yt34 The current record is supplemented by this dataset	dataset	January 2021
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Title: Preparation, characterization, and structural studies of new ruthenium(II) and ruthenium(III) complexes incorporating pyrazole ligands

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