The evolution of composition and morphology during the initial growth of electrodeposited Ni-Fe films: Comparison between the potentiostatic mode and the pulse-reverse potential mode

Lin, Qiyuan; Zangari, Giovanni

doi:10.1016/j.electacta.2022.139978

Title: The evolution of composition and morphology during the initial growth of electrodeposited Ni-Fe films: Comparison between the potentiostatic mode and the pulse-reverse potential mode

Journal Article · 27 January 2022 · Electrochimica Acta

DOI: https://doi.org/10.1016/j.electacta.2022.139978 · OSTI ID:1977074

Lin, Qiyuan ^[1]; Zangari, Giovanni ^[2]

Univ. of Virginia, Charlottesville, VA (United States); OSTI
Univ. of Virginia, Charlottesville, VA (United States)

The anomalous codeposition of Ni-Fe tends to develop a composition gradient zone along the growth direction within the near-substrate region. Although it has been shown that such a composition gradient can be mitigated by the pulsed deposition method, a fundamental understanding of this behavior based on the anomalous codeposition mechanism has not been achieved yet. In this work, the evolution of the composition and the morphology during the (pulsed) electrodeposition of Ni-Fe films was reported. Further, a theory based on the Fe deposition mechanism originally described by Bockris, Drazic, and Despic was proposed and described in detail, which was used to rationalize not only the occurrence and the decline of the composition gradient, but also the opposite signs of the composition gradient observed under the potentiostatic mode and the pulse-reverse potential mode.

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Research Organization:: Univ. of Virginia, Charlottesville, VA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019191

OSTI ID:: 1977074

Journal Information:: Electrochimica Acta, Journal Name: Electrochimica Acta Journal Issue: C Vol. 409; ISSN 0013-4686

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Anomalous codeposition
Composition gradient
Electrochemistry
Electrodeposition
Ni-Fe
Thin films

Title: The evolution of composition and morphology during the initial growth of electrodeposited Ni-Fe films: Comparison between the potentiostatic mode and the pulse-reverse potential mode

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