Porous materials for hydrogen storage

Chen, Zhijie; Kirlikovali, Kent O.; Idrees, Karam B.; Wasson, Megan C.; Farha, Omar K.

doi:10.1016/j.chempr.2022.01.012

Title: Porous materials for hydrogen storage

Journal Article · 10 February 2022 · Chem

DOI: https://doi.org/10.1016/j.chempr.2022.01.012 · OSTI ID:1976957

^[1];

^[2]; Idrees, Karam B. ^[2]; Wasson, Megan C. ^[2]; Farha, Omar K. ^[2]

Northwestern University, Evanston, IL (United States); OSTI
Northwestern University, Evanston, IL (United States)

Hydrogen is a clean energy carrier and a promising candidate to realize carbon-neutral systems for a sustainable future because the combustion of hydrogen produces only water. The large-scale implementation of hydrogen, particularly in zero-emission hydrogen-powered fuel-cell automobiles, requires efficient hydrogen storage systems; however, the current on-board hydrogen storage technologies mainly rely on costly and potentially unsafe high-pressure compression strategies that reach pressures of up to 700 bar. Recently, solid-state porous materials, such as metal-organic frameworks, have emerged as sorbents that can conceivably store comparable amounts of hydrogen in a safer and more efficient manner relative to the current high-pressure storage technologies. Here this review summarizes the current progress on the development of state-of-the-art porous materials and their composites for hydrogen storage. We hope this work will inspire efforts toward creating next-generation hydrogen storage materials.

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Research Organization:: Northwestern University, Evanston, IL (United States)

Sponsoring Organization:: IIN Postdoctoral Fellowship; National Science Foundation (NSF); Northwestern University; USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0008816

OSTI ID:: 1976957

Journal Information:: Chem, Journal Name: Chem Journal Issue: 3 Vol. 8; ISSN 2451-9294

Publisher:: Cell PressCopyright Statement

Country of Publication:: United States

Language:: English

References (147)

Ordered Mesoporous Carbons Ryoo, R.; Joo, S. H.; Kruk, M. Advanced Materials, Vol. 13, Issue 9, p. 677-681 https://doi.org/10.1002/1521-4095(200105)13:9<677::AID-ADMA677>3.0.CO;2-C	journal	May 2001
Highly Stable Porous Polymer Networks with Exceptionally High Gas-Uptake Capacities Yuan, Daqiang; Lu, Weigang; Zhao, Dan Advanced Materials, Vol. 23, Issue 32 https://doi.org/10.1002/adma.201101759	journal	July 2011
Templated Nanocarbons for Energy Storage Nishihara, Hirotomo; Kyotani, Takashi Advanced Materials, Vol. 24, Issue 33, p. 4473-4498 https://doi.org/10.1002/adma.201201715	journal	July 2012
Optimization of the Pore Structures of MOFs for Record High Hydrogen Volumetric Working Capacity Zhang, Xin; Lin, Rui-Biao; Wang, Jing Advanced Materials https://doi.org/10.1002/adma.201907995	journal	March 2020
Nanoscaffold Mediates Hydrogen Release and the Reactivity of Ammonia Borane Gutowska, Anna; Li, Liyu; Shin, Yongsoon Angewandte Chemie International Edition, Vol. 44, Issue 23 https://doi.org/10.1002/anie.200462602	journal	June 2005
An In Situ High-Temperature Single-Crystal Investigation of a Dehydrated Metal-Organic Framework Compound and Field-Induced Magnetization of One-Dimensional Metal-Oxygen Chains Dietzel, Pascal D. C.; Morita, Yusuke; Blom, Richard Angewandte Chemie International Edition, Vol. 44, Issue 39, p. 6354-6358 https://doi.org/10.1002/anie.200501508	journal	October 2005
Assembly of Metal–Organic Frameworks (MOFs) Based on Indium-Trimer Building Blocks: A Porous MOF with soc Topology and High Hydrogen Storage Liu, Yunling; Eubank, Jarrod F.; Cairns, Amy J. Angewandte Chemie International Edition, Vol. 46, Issue 18 https://doi.org/10.1002/anie.200604306	journal	April 2007
Lithium-Doped 3D Covalent Organic Frameworks: High-Capacity Hydrogen Storage Materials Cao, Dapeng; Lan, Jianhui; Wang, Wenchuan Angewandte Chemie International Edition, Vol. 48, Issue 26 https://doi.org/10.1002/anie.200900960	journal	June 2009
Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area Ben, Teng; Ren, Hao; Ma, Shengqian Angewandte Chemie International Edition, Vol. 48, Issue 50, p. 9457-9460 https://doi.org/10.1002/anie.200904637	journal	November 2009
On Demand: The Singular rht Net, an Ideal Blueprint for the Construction of a Metal-Organic Framework (MOF) Platform Eubank, Jarrod F.; Nouar, Farid; Luebke, Ryan Angewandte Chemie International Edition, Vol. 51, Issue 40 https://doi.org/10.1002/anie.201201202	journal	September 2012
Scorpionate-Type Coordination in MFU-4 l Metal-Organic Frameworks: Small-Molecule Binding and Activation upon the Thermally Activated Formation of Open Metal Sites Denysenko, Dmytro; Grzywa, Maciej; Jelic, Jelena Angewandte Chemie International Edition, Vol. 53, Issue 23 https://doi.org/10.1002/anie.201310004	journal	May 2014
Electrosynthesis of Metal-Organic Frameworks: Challenges and Opportunities Al-Kutubi, Hanan; Gascon, Jorge; Sudhölter, Ernst J. R. ChemElectroChem, Vol. 2, Issue 4 https://doi.org/10.1002/celc.201402429	journal	February 2015
Elucidating Gating Effects for Hydrogen Sorption in MFU-4-Type Triazolate-Based Metal-Organic Frameworks Featuring Different Pore Sizes Denysenko, Dmytro; Grzywa, Maciej; Tonigold, Markus Chemistry - A European Journal, Vol. 17, Issue 6 https://doi.org/10.1002/chem.201001872	journal	January 2011
Nanoconfinement and Catalytic Dehydrogenation of Ammonia Borane by Magnesium‐Metal–Organic‐Framework‐74 Gadipelli, Srinivas; Ford, Jamie; Zhou, Wei Chemistry – A European Journal, Vol. 17, Issue 22 https://doi.org/10.1002/chem.201100090	journal	April 2011
Nanoporous Polymers for Hydrogen Storage Germain, Jonathan; Fréchet, Jean M. J.; Svec, Frantisek Small, Vol. 5, Issue 10 https://doi.org/10.1002/smll.200801762	journal	May 2009
A Unique Double‐Layered Carbon Nanobowl‐Confined Lithium Borohydride for Highly Reversible Hydrogen Storage Wu, Ruyan; Zhang, Xin; Liu, Yongfeng Small, Vol. 16, Issue 32 https://doi.org/10.1002/smll.202001963	journal	July 2020
Outlook and challenges for hydrogen storage in nanoporous materials Broom, D. P.; Webb, C. J.; Hurst, K. E. Applied Physics A, Vol. 122, Issue 3 https://doi.org/10.1007/s00339-016-9651-4	journal	February 2016
Adsorption for efficient low carbon hydrogen production: part 1—adsorption equilibrium and breakthrough studies for H2/CO2/CH4 on zeolite 13X Streb, Anne; Mazzotti, Marco Adsorption, Vol. 27, Issue 4 https://doi.org/10.1007/s10450-021-00306-y	journal	March 2021
Mechanical characterisation of polymer of intrinsic microporosity PIM-1 for hydrogen storage applications Polak-Kraśna, Katarzyna; Dawson, Robert; Holyfield, Leighton T. Journal of Materials Science, Vol. 52, Issue 7 https://doi.org/10.1007/s10853-016-0647-4	journal	December 2016
Water-based routes for synthesis of metal-organic frameworks: A review Duan, Chongxiong; Yu, Yi; Xiao, Jing Science China Materials, Vol. 63, Issue 5 https://doi.org/10.1007/s40843-019-1264-x	journal	March 2020
Hydrogen adsorption in zeolites A, X, Y and RHO Langmi, H. W.; Walton, A.; Al-Mamouri, M. M. Journal of Alloys and Compounds, Vol. 356-357 https://doi.org/10.1016/S0925-8388(03)00368-2	journal	August 2003
A cubic ordered, mesoporous carbide-derived carbon for gas and energy storage applications Oschatz, Martin; Kockrick, Emanuel; Rose, Marcus Carbon, Vol. 48, Issue 14 https://doi.org/10.1016/j.carbon.2010.06.058	journal	November 2010
Post-synthesis modifications of SBA-15 carbon replicas: Improving hydrogen storage by increasing microporous volume Armandi, M.; Bonelli, B.; Karaindrou, E. I. Catalysis Today, Vol. 138, Issue 3-4 https://doi.org/10.1016/j.cattod.2008.05.002	journal	November 2008
Precursor suitability and pilot scale production of super activated carbon for greenhouse gas adsorption and fuel gas storage Sawant, Sandesh Y.; Munusamy, K.; Somani, Rajesh S. Chemical Engineering Journal, Vol. 315 https://doi.org/10.1016/j.cej.2017.01.037	journal	May 2017
TiO2 decorated porous carbonaceous network structures offer confinement, catalysis and thermal conductivity for effective hydrogen storage of LiBH4 Xian, Kaicheng; Nie, Bo; Li, Zigen Chemical Engineering Journal, Vol. 407 https://doi.org/10.1016/j.cej.2020.127156	journal	March 2021
A nanoconfined-LiBH4 system using a unique multifunctional porous scaffold of carbon wrapped ultrafine Fe3O4 skeleton for reversible hydrogen storage with high capacity Wang, Shun; Gao, Mingxia; Yao, Zhihao Chemical Engineering Journal, Vol. 428 https://doi.org/10.1016/j.cej.2021.131056	journal	January 2022
Porous Metal-Organic Frameworks: Promising Materials for Methane Storage Li, Bin; Wen, Hui-Min; Zhou, Wei Chem, Vol. 1, Issue 4 https://doi.org/10.1016/j.chempr.2016.09.009	journal	October 2016
CO2 activation of ordered porous carbon CMK-1 for hydrogen storage Xia, K.; Gao, Q.; Song, S. International Journal of Hydrogen Energy, Vol. 33, Issue 1 https://doi.org/10.1016/j.ijhydene.2007.08.019	journal	January 2008
Improving hydrogen storage properties of covalent organic frameworks by substitutional doping Li, Fen; Zhao, Jijun; Johansson, Börje International Journal of Hydrogen Energy, Vol. 35, Issue 1 https://doi.org/10.1016/j.ijhydene.2009.10.061	journal	January 2010
Improved hydrogen desorption properties of ammonia borane by Ni-modified metal-organic frameworks Si, Xiao-liang; Sun, Li-xian; Xu, Fen International Journal of Hydrogen Energy, Vol. 36, Issue 11 https://doi.org/10.1016/j.ijhydene.2011.02.102	journal	June 2011
Review of hydrogen storage techniques for on board vehicle applications Durbin, D. J.; Malardier-Jugroot, C. International Journal of Hydrogen Energy, Vol. 38, Issue 34 https://doi.org/10.1016/j.ijhydene.2013.07.058	journal	November 2013
Low-temperature hydrogen desorption from Mg(BH4)2 catalysed by ultrafine Ni nanoparticles in a mesoporous carbon matrix Wahab, Mohammad A.; Young, David J.; Karim, Azharul International Journal of Hydrogen Energy, Vol. 41, Issue 45 https://doi.org/10.1016/j.ijhydene.2016.09.098	journal	December 2016
Assessment of the long-term stability of the polymer of intrinsic microporosity PIM-1 for hydrogen storage applications Rochat, Sébastien; Polak-Kraśna, Katarzyna; Tian, Mi International Journal of Hydrogen Energy, Vol. 44, Issue 1 https://doi.org/10.1016/j.ijhydene.2018.02.175	journal	January 2019
Nanoconfinement of borohydrides in hollow carbon spheres: Melt infiltration versus solvent impregnation for enhanced hydrogen storage Lai, Qiwen; Yang, Yuwei; Aguey-Zinsou, Kondo-Francois International Journal of Hydrogen Energy, Vol. 44, Issue 41 https://doi.org/10.1016/j.ijhydene.2019.07.041	journal	August 2019
Anchoring and space-confinement effects to synthesize ultrasmall Pd nanoparticles for efficient ammonia borane hydrolysis Mao, Mingyue; Chen, Qian; Wu, Jie International Journal of Hydrogen Energy, Vol. 45, Issue 51 https://doi.org/10.1016/j.ijhydene.2020.07.097	journal	October 2020
Enhanced hydrogen storage properties of high-loading nanoconfined LiBH4–Mg(BH4)2 composites with porous hollow carbon nanospheres Zheng, Jiaguang; Yao, Zhendong; Xiao, Xuezhang International Journal of Hydrogen Energy, Vol. 46, Issue 1 https://doi.org/10.1016/j.ijhydene.2020.09.177	journal	January 2021
Materials for hydrogen-based energy storage – past, recent progress and future outlook Hirscher, Michael; Yartys, Volodymyr A.; Baricco, Marcello Journal of Alloys and Compounds, Vol. 827 https://doi.org/10.1016/j.jallcom.2019.153548	journal	June 2020
Hydrogen storage by carbon materials Ströbel, R.; Garche, J.; Moseley, P. T. Journal of Power Sources, Vol. 159, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.03.047	journal	September 2006
The influence of textural properties on the adsorption of hydrogen on ordered nanostructured carbons Gadiou, Roger; Saadallah, Seif-Eddine; Piquero, Thierry Microporous and Mesoporous Materials, Vol. 79, Issue 1-3 https://doi.org/10.1016/j.micromeso.2004.10.034	journal	April 2005
Optimal isosteric heat of adsorption for hydrogen storage and delivery using metal–organic frameworks Bae, Youn-Sang; Snurr, Randall Q. Microporous and Mesoporous Materials, Vol. 132, Issue 1-2 https://doi.org/10.1016/j.micromeso.2010.02.023	journal	July 2010
Triptycene based microporous polymers (TMPs): Efficient small gas (H2 and CO2) storage and high CO2/N2 selectivity Bera, Ranajit; Mondal, Snehasish; Das, Neeladri Microporous and Mesoporous Materials, Vol. 257 https://doi.org/10.1016/j.micromeso.2017.08.045	journal	February 2018
Hydrogen storage: The major technological barrier to the development of hydrogen fuel cell cars Ross, D. K. Vacuum, Vol. 80, Issue 10 https://doi.org/10.1016/j.vacuum.2006.03.030	journal	August 2006
Future Porous Materials Kitagawa, Susumu Accounts of Chemical Research, Vol. 50, Issue 3 https://doi.org/10.1021/acs.accounts.6b00500	journal	March 2017
Gaining Insights on the H ₂ –Sorbent Interactions: Robust soc-MOF Platform as a Case Study Cairns, Amy J.; Eckert, Juergen; Wojtas, Lukasz Chemistry of Materials, Vol. 28, Issue 20 https://doi.org/10.1021/acs.chemmater.6b02817	journal	October 2016
Anomalous H ₂ Desorption Rate of NaAlH ₄ Confined in Nitrogen-Doped Nanoporous Carbon Frameworks Carr, Christopher L.; Jayawardana, Waruni; Zou, Hongyang Chemistry of Materials, Vol. 30, Issue 9 https://doi.org/10.1021/acs.chemmater.8b00305	journal	April 2018
Record High Hydrogen Storage Capacity in the Metal–Organic Framework Ni ₂ ( m -dobdc) at Near-Ambient Temperatures Kapelewski, Matthew T.; Runčevski, Tomče; Tarver, Jacob D. Chemistry of Materials, Vol. 30, Issue 22 https://doi.org/10.1021/acs.chemmater.8b03276	journal	October 2018
Nanostructured Metal Hydrides for Hydrogen Storage Schneemann, Andreas; White, James L.; Kang, ShinYoung Chemical Reviews, Vol. 118, Issue 22 https://doi.org/10.1021/acs.chemrev.8b00313	journal	October 2018
Hydrogen Release from Ammonia Borane Nanoconfined in Metal–Organic Frameworks with MIL-53 Topology Peil, Stefan; Wisser, Dorothea; Stähle, Melanie The Journal of Physical Chemistry C, Vol. 125, Issue 18 https://doi.org/10.1021/acs.jpcc.0c11417	journal	May 2021
Surface-Functionalized Nanoporous Carbons for Kinetically Stabilized Complex Hydrides through Lewis Acid–Lewis Base Chemistry Carr, C. L.; Majzoub, E. H. The Journal of Physical Chemistry C, Vol. 120, Issue 21 https://doi.org/10.1021/acs.jpcc.6b03374	journal	May 2016
Al ₂ O ₃ Atomic Layer Deposition on Nanostructured γ-Mg(BH ₄ ) ₂ for H ₂ Storage Leick, Noemi; Strange, Nicholas A.; Schneemann, Andreas ACS Applied Energy Materials, Vol. 4, Issue 2 https://doi.org/10.1021/acsaem.0c02314	journal	January 2021
Selenium-Infused Ordered Mesoporous Carbon for Room-Temperature All-Solid-State Lithium–Selenium Batteries with Ultrastable Cyclability Zhang, Qiang; Cai, Liangting; Liu, Gaozhan ACS Applied Materials & Interfaces, Vol. 12, Issue 14 https://doi.org/10.1021/acsami.0c01996	journal	March 2020
Understanding Volumetric and Gravimetric Hydrogen Adsorption Trade-off in Metal–Organic Frameworks Gómez-Gualdrón, Diego A.; Wang, Timothy C.; García-Holley, Paula ACS Applied Materials & Interfaces, Vol. 9, Issue 39 https://doi.org/10.1021/acsami.7b01190	journal	April 2017
Nanoconfinement of Complex Borohydrides for Hydrogen Storage Lai, Qiwen; Pratthana, Chulaluck; Yang, Yuwei ACS Applied Nano Materials, Vol. 4, Issue 2 https://doi.org/10.1021/acsanm.0c03059	journal	January 2021
Benchmark Study of Hydrogen Storage in Metal–Organic Frameworks under Temperature and Pressure Swing Conditions García-Holley, Paula; Schweitzer, Benjamin; Islamoglu, Timur ACS Energy Letters, Vol. 3, Issue 3 https://doi.org/10.1021/acsenergylett.8b00154	journal	February 2018
Nanoconfinement of Molecular Magnesium Borohydride Captured in a Bipyridine-Functionalized Metal–Organic Framework Schneemann, Andreas; Wan, Liwen F.; Lipton, Andrew S. ACS Nano, Vol. 14, Issue 8 https://doi.org/10.1021/acsnano.0c03764	journal	July 2020
Reversing the Irreversible: Thermodynamic Stabilization of LiAlH ₄ Nanoconfined Within a Nitrogen-Doped Carbon Host Cho, YongJun; Li, Sichi; Snider, Jonathan L. ACS Nano, Vol. 15, Issue 6 https://doi.org/10.1021/acsnano.1c02079	journal	May 2021
Hierarchical Porous g-C₃N₄ Coupled Ultrafine RuNi Alloys as Extremely Active Catalysts for the Hydrolytic Dehydrogenation of Ammonia Borane Li, Yong-Ting; Zhang, Xiao-Li; Peng, Zhi-Kun ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 22 https://doi.org/10.1021/acssuschemeng.0c03009	journal	May 2020
Encapsulation of Ammonia Borane in Pd/Halloysite Nanotubes for Efficient Thermal Dehydrogenation Feng, Yanan; Zhou, Xiaopeng; Yang, Jing-he ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 5 https://doi.org/10.1021/acssuschemeng.9b04480	journal	January 2020
Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks Eddaoudi, Mohamed; Moler, David B.; Li, Hailian Accounts of Chemical Research, Vol. 34, Issue 4, p. 319-330 https://doi.org/10.1021/ar000034b	journal	April 2001
Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of Frameworks Ockwig, Nathan W.; Delgado-Friedrichs, Olaf; O'Keeffe, Michael Accounts of Chemical Research, Vol. 38, Issue 3, p. 176-182 https://doi.org/10.1021/ar020022l	journal	March 2005
Microporous Heptazine Functionalized (3,24)-Connected rht -Metal–Organic Framework: Synthesis, Structure, and Gas Sorption Analysis Luebke, Ryan; Weseliński, Łukasz J.; Belmabkhout, Youssef Crystal Growth & Design, Vol. 14, Issue 2 https://doi.org/10.1021/cg401802s	journal	January 2014
Systematic Pore-Size Effects of Nanoconfinement of LiBH ₄ : Elimination of Diborane Release and Tunable Behavior for Hydrogen Storage Applications Liu, Xiangfeng; Peaslee, David; Jost, Christopher Z. Chemistry of Materials, Vol. 23, Issue 5 https://doi.org/10.1021/cm103546g	journal	March 2011
Formation of New Type of Porous Carbon by Carbonization in Zeolite Nanochannels Kyotani, Takashi; Nagai, Takayuki; Inoue, Sanjuro Chemistry of Materials, Vol. 9, Issue 2 https://doi.org/10.1021/cm960430h	journal	February 1997
Effect of Micropore Topology on the Structure and Properties of Zeolite Polymer Replicas Johnson, Stacy A.; Brigham, Elaine S.; Ollivier, Patricia J. Chemistry of Materials, Vol. 9, Issue 11 https://doi.org/10.1021/cm9703278	journal	November 1997
Structural and Textural Properties of Pyrolytic Carbon Formed within a Microporous Zeolite Template Rodriguez-Mirasol, J.; Cordero, T.; Radovic, L. R. Chemistry of Materials, Vol. 10, Issue 2 https://doi.org/10.1021/cm970552p	journal	January 1998
Hydrogen Storage in Metal–Organic Frameworks Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri Chemical Reviews, Vol. 112, Issue 2, p. 782-835 https://doi.org/10.1021/cr200274s	journal	September 2011
Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units Rosi, Nathaniel L.; Kim, Jaheon; Eddaoudi, Mohamed Journal of the American Chemical Society, Vol. 127, Issue 5, p. 1504-1518 https://doi.org/10.1021/ja045123o	journal	February 2005
Enhanced Hydrogen Storage Capacity of High Surface Area Zeolite-like Carbon Materials Yang, Zhuxian; Xia, Yongde; Mokaya, Robert Journal of the American Chemical Society, Vol. 129, Issue 6 https://doi.org/10.1021/ja067149g	journal	February 2007
Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination Feng, Dawei; Chung, Wan-Chun; Wei, Zhangwen Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja408084j	journal	October 2013
M₂(m-dobdc) (M = Mg, Mn, Fe, Co, Ni) Metal–Organic Frameworks Exhibiting Increased Charge Density and Enhanced H₂ Binding at the Open Metal Sites Kapelewski, Matthew T.; Geier, Stephen J.; Hudson, Matthew R. Journal of the American Chemical Society, Vol. 136, Issue 34, p. 12119-12129 https://doi.org/10.1021/ja506230r	journal	August 2014
Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks Nouar, Farid; Eubank, Jarrod F.; Bousquet, Till Journal of the American Chemical Society, Vol. 130, Issue 6 https://doi.org/10.1021/ja710123s	journal	February 2008
Surface Interactions and Quantum Kinetic Molecular Sieving for H ₂ and D ₂ Adsorption on a Mixed Metal−Organic Framework Material Chen, Banglin; Zhao, Xuebo; Putkham, Apipong Journal of the American Chemical Society, Vol. 130, Issue 20 https://doi.org/10.1021/ja710144k	journal	May 2008
Metal-Organic Framework as a Template for Porous Carbon Synthesis Liu, Bo; Shioyama, Hiroshi; Akita, Tomoki Journal of the American Chemical Society, Vol. 130, Issue 16 https://doi.org/10.1021/ja7106146	journal	April 2008
Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials Han, Sang Soo; Furukawa, Hiroyasu; Yaghi, Omar M. Journal of the American Chemical Society, Vol. 130, Issue 35, p. 11580-11581 https://doi.org/10.1021/ja803247y	journal	September 2008
Enhanced H₂ Adsorption in Isostructural Metal−Organic Frameworks with Open Metal Sites: Strong Dependence of the Binding Strength on Metal Ions Zhou, Wei; Wu, Hui; Yildirim, Taner Journal of the American Chemical Society, Vol. 130, Issue 46, p. 15268-15269 https://doi.org/10.1021/ja807023q	journal	November 2008
Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications Furukawa, Hiroyasu; Yaghi, Omar M. Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8875-8883 https://doi.org/10.1021/ja9015765	journal	July 2009
Metal−Organic Frameworks As Templates for Nanoscale NaAlH₄ Bhakta, Raghunandan K.; Herberg, Julie L.; Jacobs, Benjamin Journal of the American Chemical Society, Vol. 131, Issue 37, p. 13198-13199 https://doi.org/10.1021/ja904431x	journal	September 2009
Ammonia Borane Confined by a Metal−Organic Framework for Chemical Hydrogen Storage: Enhancing Kinetics and Eliminating Ammonia Li, Zhongyue; Zhu, Guangshan; Lu, Gaoqing Journal of the American Chemical Society, Vol. 132, Issue 5 https://doi.org/10.1021/ja9103217	journal	January 2010
Ambient-Temperature Hydrogen Storage via Vanadium(II)-Dihydrogen Complexation in a Metal–Organic Framework Jaramillo, David E.; Jiang, Henry Z. H.; Evans, Hayden A. Journal of the American Chemical Society, Vol. 143, Issue 16 https://doi.org/10.1021/jacs.1c01883	journal	April 2021
Observation of an Intermediate to H ₂ Binding in a Metal–Organic Framework Barnett, Brandon R.; Evans, Hayden A.; Su, Gregory M. Journal of the American Chemical Society, Vol. 143, Issue 36 https://doi.org/10.1021/jacs.1c07223	journal	August 2021
Fine-Tuning a Robust Metal–Organic Framework toward Enhanced Clean Energy Gas Storage Chen, Zhijie; Mian, Mohammad Rasel; Lee, Seung-Joon Journal of the American Chemical Society, Vol. 143, Issue 45 https://doi.org/10.1021/jacs.1c08749	journal	November 2021
Application of Consistency Criteria To Calculate BET Areas of Micro- And Mesoporous Metal–Organic Frameworks Gómez-Gualdrón, Diego A.; Moghadam, Peyman Z.; Hupp, Joseph T. Journal of the American Chemical Society, Vol. 138, Issue 1 https://doi.org/10.1021/jacs.5b10266	journal	December 2015
Reticular Access to Highly Porous acs -MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption Chen, Zhijie; Li, Penghao; Zhang, Xuan Journal of the American Chemical Society, Vol. 141, Issue 7 https://doi.org/10.1021/jacs.8b13710	journal	February 2019
New Insights into the Interaction of Hydrogen Atoms with Boron-Substituted Carbon Zhu, Z. H.; Lu, G. Q.; Hatori, H. The Journal of Physical Chemistry B, Vol. 110, Issue 3 https://doi.org/10.1021/jp0516590	journal	December 2005
Controlling the Decomposition Pathway of LiBH ₄ via Confinement in Highly Ordered Nanoporous Carbon Liu, Xiangfeng; Peaslee, David; Jost, C. Z. The Journal of Physical Chemistry C, Vol. 114, Issue 33 https://doi.org/10.1021/jp1055045	journal	July 2010
High-Throughput Screening of Porous Crystalline Materials for Hydrogen Storage Capacity near Room Temperature Colón, Yamil J.; Fairen-Jimenez, David; Wilmer, Christopher E. The Journal of Physical Chemistry C, Vol. 118, Issue 10 https://doi.org/10.1021/jp4122326	journal	March 2014
Enhanced Hydrogen Storage Kinetics of LiBH₄ in Nanoporous Carbon Scaffolds Gross, Adam F.; Vajo, John J.; Van Atta, Sky L. The Journal of Physical Chemistry C, Vol. 112, Issue 14, p. 5651-5657 https://doi.org/10.1021/jp711066t	journal	March 2008
Hydrogen Storage in 3D Covalent Organic Frameworks. A Multiscale Theoretical Investigation Klontzas, Emmanouel; Tylianakis, Emmanuel; Froudakis, George E. The Journal of Physical Chemistry C, Vol. 112, Issue 24 https://doi.org/10.1021/jp711326g	journal	May 2008
LiBH ₄ /SBA-15 Nanocomposites Prepared by Melt Infiltration under Hydrogen Pressure: Synthesis and Hydrogen Sorption Properties Ngene, Peter; Adelhelm, Philipp; Beale, Andrew M. The Journal of Physical Chemistry C, Vol. 114, Issue 13 https://doi.org/10.1021/jp9065949	journal	March 2010
Hydrogen Storage in Lithium-Functionalized 3-D Covalent-Organic Framework Materials Klontzas, Emmanouel; Tylianakis, Emmanuel; Froudakis, George E. The Journal of Physical Chemistry C, Vol. 113, Issue 50 https://doi.org/10.1021/jp907241y	journal	November 2009
Synthesis of Highly Ordered Carbon Molecular Sieves via Template-Mediated Structural Transformation Ryoo, Ryong; Joo, Sang Hoon; Jun, Shinae The Journal of Physical Chemistry B, Vol. 103, Issue 37 https://doi.org/10.1021/jp991673a	journal	September 1999
Optimum Conditions for Adsorptive Storage Bhatia, Suresh K.; Myers, Alan L. Langmuir, Vol. 22, Issue 4 https://doi.org/10.1021/la0523816	journal	February 2006
Computer Simulation of the Adsorption of Light Gases in Covalent Organic Frameworks Garberoglio, G. Langmuir, Vol. 23, Issue 24 https://doi.org/10.1021/la701736m	journal	October 2007
Reversible Hydrogen Storage by NaAlH ₄ Confined within a Titanium-Functionalized MOF-74(Mg) Nanoreactor Stavila, Vitalie; Bhakta, Raghunandan K.; Alam, Todd M. ACS Nano, Vol. 6, Issue 11 https://doi.org/10.1021/nn304514c	journal	October 2012
Order of Stability of Metal Complexes Irving, H.; Williams, R. J. P. Nature, Vol. 162, Issue 4123 https://doi.org/10.1038/162746a0	journal	November 1948
Hydrogen carriers He, Teng; Pachfule, Pradip; Wu, Hui Nature Reviews Materials, Vol. 1, Issue 12 https://doi.org/10.1038/natrevmats.2016.59	journal	October 2016
Reticular synthesis and the design of new materials Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W. Nature, Vol. 423, Issue 6941, p. 705-714 https://doi.org/10.1038/nature01650	journal	June 2003
Opportunities and challenges for a sustainable energy future Chu, Steven; Majumdar, Arun Nature, Vol. 488, Issue 7411, p. 294-303 https://doi.org/10.1038/nature11475	journal	August 2012
Large-scale screening of hypothetical metal–organic frameworks Wilmer, Christopher E.; Leaf, Michael; Lee, Chang Yeon Nature Chemistry, Vol. 4, Issue 2, p. 83-89 https://doi.org/10.1038/nchem.1192	journal	November 2011
De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim Nature Chemistry, Vol. 2, Issue 11, p. 944-948 https://doi.org/10.1038/nchem.834	journal	September 2010
Oxygen-rich microporous carbons with exceptional hydrogen storage capacity Blankenship II, Troy Scott; Balahmar, Norah; Mokaya, Robert Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01633-x	journal	November 2017
Exceptional hydrogen storage achieved by screening nearly half a million metal-organic frameworks Ahmed, Alauddin; Seth, Saona; Purewal, Justin Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09365-w	journal	April 2019
Ruthenium nanoparticles confined in SBA-15 as highly efficient catalyst for hydrolytic dehydrogenation of ammonia borane and hydrazine borane Yao, Qilu; Lu, Zhang-Hui; Yang, Kangkang Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep15186	journal	October 2015
A triptycene-based polymer of intrinsic microposity that displays enhanced surface area and hydrogen adsorption Ghanem, Bader S.; Msayib, Kadhum J.; McKeown, Neil B. Chem. Commun., Issue 1 https://doi.org/10.1039/B614214A	journal	January 2007
Taxonomy of periodic nets and the design of materials Delgado-Friedrichs, Olaf; O’Keeffe, Michael; Yaghi, Omar M. Phys. Chem. Chem. Phys., Vol. 9, Issue 9, p. 1035-1043 https://doi.org/10.1039/B615006C	journal	January 2007
Conjugated microporous poly(phenylene butadiynylene)s Jiang, Jia-Xing; Su, Fabing; Niu, Hongjun Chem. Commun., Issue 4 https://doi.org/10.1039/B715563H	journal	January 2008
Covalent organic frameworks (COFs): from design to applications Ding, San-Yuan; Wang, Wei Chem. Soc. Rev., Vol. 42, Issue 2 https://doi.org/10.1039/C2CS35072F	journal	January 2013
Stabilization of NaZn(BH₄)₃via nanoconfinement in SBA-15 towards enhanced hydrogen release Xia, Guanglin; Li, Li; Guo, Zaiping J. Mater. Chem. A, Vol. 1, Issue 2 https://doi.org/10.1039/C2TA00195K	journal	January 2013
Design and synthesis of novel carbazole–spacer–carbazole type conjugated microporous networks for gas storage and separation Qiao, Shanlin; Du, Zhengkun; Yang, Renqiang J. Mater. Chem. A, Vol. 2, Issue 6 https://doi.org/10.1039/C3TA14017B	journal	January 2014
High-throughput computational screening of metal–organic frameworks Colón, Yamil J.; Snurr, Randall Q. Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00070F	journal	January 2014
Sustainable carbon materials Titirici, Maria-Magdalena; White, Robin J.; Brun, Nicolas Chemical Society Reviews, Vol. 44, Issue 1, p. 250-290 https://doi.org/10.1039/C4CS00232F	journal	January 2015
A metal–organic framework as a chemical guide to control hydrogen desorption pathways of ammonia borane Jeong, Hyung Mo; Shin, Weon Ho; Park, Jung Hyo Nanoscale, Vol. 6, Issue 12 https://doi.org/10.1039/C4NR01296H	journal	January 2014
Improved dehydrogenation performance of LiBH₄ by confinement into porous TiO₂ micro-tubes Liu, Huiqiao; Jiao, Lifang; Zhao, Yanping J. Mater. Chem. A, Vol. 2, Issue 24 https://doi.org/10.1039/C4TA01327A	journal	January 2014
Evaluating topologically diverse metal–organic frameworks for cryo-adsorbed hydrogen storage Gómez-Gualdrón, Diego A.; Colón, Yamil J.; Zhang, Xu Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE02104B	journal	January 2016
Balancing gravimetric and volumetric hydrogen density in MOFs Ahmed, Alauddin; Liu, Yiyang; Purewal, Justin Energy & Environmental Science, Vol. 10, Issue 11 https://doi.org/10.1039/C7EE02477K	journal	January 2017
Graphene entanglement in a mesoporous resorcinol–formaldehyde matrix applied to the nanoconfinement of LiBH ₄ for hydrogen storage Gasnier, A.; Gennari, F. C. RSC Advances, Vol. 7, Issue 45 https://doi.org/10.1039/C7RA02288C	journal	January 2017
An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage Allendorf, Mark D.; Hulvey, Zeric; Gennett, Thomas Energy & Environmental Science, Vol. 11, Issue 10 https://doi.org/10.1039/C8EE01085D	journal	January 2018
Energy-based descriptors to rapidly predict hydrogen storage in metal–organic frameworks Bucior, Benjamin J.; Bobbitt, N. Scott; Islamoglu, Timur Molecular Systems Design & Engineering, Vol. 4, Issue 1 https://doi.org/10.1039/C8ME00050F	journal	January 2019
Salt template-assisted in situ construction of Ru nanoclusters and porous carbon: excellent catalysts toward hydrogen evolution, ammonia-borane hydrolysis, and 4-nitrophenol reduction Ding, Rong; Chen, Qian; Luo, Qian Green Chemistry, Vol. 22, Issue 3 https://doi.org/10.1039/C9GC03986D	journal	January 2020
Technoeconomic analysis of metal–organic frameworks for bulk hydrogen transportation Anastasopoulou, Aikaterini; Furukawa, Hiroyasu; Barnett, Brandon R. Energy & Environmental Science, Vol. 14, Issue 3 https://doi.org/10.1039/D0EE02448A	journal	January 2021
In situ catalyzed and nanoconfined magnesium hydride nanocrystals in a Ni-MOF scaffold for hydrogen storage Ma, Zhewen; Zhang, Qiuyu; Panda, Subrata Sustainable Energy & Fuels, Vol. 4, Issue 9 https://doi.org/10.1039/D0SE00818D	journal	January 2020
Synthesis of a new mesoporous carbon and its application to electrochemical double-layer capacitors Lee, Jinwoo; Yoon, Songhun; Hyeon, Taeghwan Chemical Communications, Issue 21 https://doi.org/10.1039/a906872d	journal	January 1999
Preparation of a high surface area microporous carbon having the structural regularity of Y zeolite Ma, Zhixin; Kyotani, Takashi; Tomita, Akira Chemical Communications, Issue 23 https://doi.org/10.1039/b006295m	journal	January 2000
Independent verification of the saturation hydrogen uptake in MOF-177 and establishment of a benchmark for hydrogen adsorption in metal–organic frameworks Furukawa, Hiroyasu; Miller, Michael A.; Yaghi, Omar M. Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3197-3204 https://doi.org/10.1039/b703608f	journal	January 2007
Hydrogen storage in metal–organic frameworks Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R. Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314 https://doi.org/10.1039/b802256a	journal	January 2009
New sorbents for hydrogen storage by hydrogen spillover – a review Wang, Lifeng; Yang, Ralph T. Energy & Environmental Science, Vol. 1, Issue 2 https://doi.org/10.1039/b807957a	journal	January 2008
Microporous polyphenylenes with tunable pore size for hydrogen storage Yuan, Shengwen; Dorney, Brian; White, Desiree Chemical Communications, Vol. 46, Issue 25 https://doi.org/10.1039/c0cc00235f	journal	January 2010
Altered thermodynamic and kinetic properties of MgH2 infiltrated in microporous scaffold Zhao-Karger, Zhirong; Hu, Jianjiang; Roth, Arne Chemical Communications, Vol. 46, Issue 44 https://doi.org/10.1039/c0cc03072d	journal	January 2010
Multi-scale theoretical investigation of hydrogen storage in covalent organic frameworks Tylianakis, Emmanuel; Klontzas, Emmanouel; Froudakis, George E. Nanoscale, Vol. 3, Issue 3 https://doi.org/10.1039/c0nr00505c	journal	January 2011
The current status of hydrogen storage in metal–organic frameworks—updated Sculley, Julian; Yuan, Daqiang; Zhou, Hong-Cai Energy & Environmental Science, Vol. 4, Issue 8 https://doi.org/10.1039/c1ee01240a	journal	January 2011
Tetraphenylethylene-based fluorescent porous organic polymers: preparation, gas sorption properties and photoluminescence properties Chen, Qi; Wang, Jin-Xiang; Yang, Fen Journal of Materials Chemistry, Vol. 21, Issue 35, p. 13554-13560 https://doi.org/10.1039/c1jm11787d	journal	January 2011
Conjugated microporous polymers: design, synthesis and application Xu, Yanhong; Jin, Shangbin; Xu, Hong Chemical Society Reviews, Vol. 42, Issue 20 https://doi.org/10.1039/c3cs60160a	journal	January 2013
Nanoconfined ammonia borane in a flexible metal–organic framework Fe–MIL-53: clean hydrogen release with fast kinetics Srinivas, Gadipelli; Travis, Will; Ford, Jamie Journal of Materials Chemistry A, Vol. 1, Issue 13 https://doi.org/10.1039/c3ta00037k	journal	January 2013
From ionic-liquid@metal–organic framework composites to heteroatom-decorated large-surface area carbons: superior CO2 and H2 uptake Aijaz, Arshad; Akita, Tomoki; Yang, Hui Chemical Communications, Vol. 50, Issue 49 https://doi.org/10.1039/c4cc02459a	journal	January 2014
Hydrogen adsorption in mesoporous carbons Pang, Jiebin; Hampsey, J. Eric; Wu, Zhiwang Applied Physics Letters, Vol. 85, Issue 21 https://doi.org/10.1063/1.1827338	journal	November 2004
Adsorption of H ₂ , CO ₂ , CH ₄ , CO, N ₂ and H ₂ O in Activated Carbon and Zeolite for Hydrogen Production Lopes, Filipe V. S.; Grande, Carlos A.; Ribeiro, Ana M. Separation Science and Technology, Vol. 44, Issue 5 https://doi.org/10.1080/01496390902729130	journal	March 2009
Hydrogen Storage in Microporous Metal-Organic Frameworks Rosi, Nathaniel L.; Eckert, Juergen; Eddaoudi, Mohamed Science, Vol. 300, Issue 5622, p. 1127-1129 https://doi.org/10.1126/science.1083440	journal	May 2003
Cleaning the Air and Improving Health with Hydrogen Fuel-Cell Vehicles Jacobson, M. Z. Science, Vol. 308, Issue 5730 https://doi.org/10.1126/science.1109157	journal	June 2005
Porous, Crystalline, Covalent Organic Frameworks Côté, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W. Science, Vol. 310, Issue 5751, p. 1166-1170 https://doi.org/10.1126/science.1120411	journal	November 2005
Designed Synthesis of 3D Covalent Organic Frameworks El-Kaderi, Hani M.; Hunt, Joseph R.; Mendoza-Cortes, Jose L. Science, Vol. 316, Issue 5822, p. 268-272 https://doi.org/10.1126/science.1139915	journal	April 2007
Ultrahigh Porosity in Metal-Organic Frameworks Furukawa, H.; Ko, N.; Go, Y. B. Science, Vol. 329, Issue 5990, p. 424-428 https://doi.org/10.1126/science.1192160	journal	July 2010
The Outlook for Population Growth Lee, R. Science, Vol. 333, Issue 6042 https://doi.org/10.1126/science.1208859	journal	July 2011
The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene Cui, X.; Chen, K.; Xing, H. Science, Vol. 353, Issue 6295 https://doi.org/10.1126/science.aaf2458	journal	May 2016
A metal-organic framework-based splitter for separating propylene from propane Cadiau, A.; Adil, K.; Bhatt, P. M. Science, Vol. 353, Issue 6295 https://doi.org/10.1126/science.aaf6323	journal	July 2016
Balancing volumetric and gravimetric uptake in highly porous materials for clean energy Chen, Zhijie; Li, Penghao; Anderson, Ryther Science, Vol. 368, Issue 6488 https://doi.org/10.1126/science.aaz8881	journal	April 2020
Highly Porous Organic Polymers for Hydrogen Fuel Storage Cousins, Kimberley; Zhang, Renwu Polymers, Vol. 11, Issue 4 https://doi.org/10.3390/polym11040690	journal	April 2019

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