Covalent Organic Framework as an Efficient Protection Layer for a Stable Lithium-Metal Anode

He, Jiarui; Bhargav, Amruth; Manthiram, Arumugam

doi:10.1002/anie.202116586

Title: Covalent Organic Framework as an Efficient Protection Layer for a Stable Lithium-Metal Anode

Journal Article · 21 February 2022 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.202116586 · OSTI ID:1976277

He, Jiarui ^[1]; Bhargav, Amruth ^[1];

^[1]

University of Texas, Austin, TX (United States)

Abstract Lithium (Li) metal shows great potential for achieving high‐energy‐density rechargeable batteries. However, the practical applications of Li‐metal batteries are still challenged by the formation of Li dendrites and unstable solid‐electrolyte interphase (SEI) on metallic Li. Herein, a thin covalent organic framework layer is in situ fabricated on Li (COF‐Li) to suppress Li dendrite growth and mitigate the side reaction on the Li anode. The COF has a periodic and uniform porosity, allowing for selectively sieving Li ions and guiding a uniform Li deposition. As a result, the COF‐Li exhibits a non‐dendrite morphology during repeated Li plating/stripping and demonstrates a remarkable cycle life over 13 200 h with an extremely low overpotential of only 16 mV at a high current density of 10 mA cm ⁻² and a high areal capacity of 10 mAh cm ⁻² .

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE

Grant/Contract Number:: SC0005397

OSTI ID:: 1976277

Alternate ID(s):: OSTI ID: 1847189

Journal Information:: Angewandte Chemie (International Edition), Vol. 61, Issue 18; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
lithium-metal batteries
artificial interphase
covalent organic framework
dendrite-free anode
electrochemistry

Title: Covalent Organic Framework as an Efficient Protection Layer for a Stable Lithium-Metal Anode

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References (34)

Figures / Tables (4)

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