Simultaneous Control of Pore-Space Partition and Charge Distribution in Multi-Modular Metal–Organic Frameworks

Hong, Anh N.; Kusumoputro, Emily; Wang, Yanxiang; Yang, Huajun; Chen, Yichong; Bu, Xianhui; Feng, Pingyun

doi:10.1002/anie.202116064

Title: Simultaneous Control of Pore-Space Partition and Charge Distribution in Multi-Modular Metal–Organic Frameworks

Journal Article · 30 January 2022 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.202116064 · OSTI ID:1976276

Hong, Anh N. ^[1]; Kusumoputro, Emily ^[1]; Wang, Yanxiang ^[1]; Yang, Huajun ^[2]; Chen, Yichong ^[1];

^[2];

^[1]

University of California, Riverside, CA (United States)
California State University (CalState), Long Beach, CA (United States)

Abstract We report here a strategy for making anionic pacs type porous materials by combining pore space partition with charge reallocation. The method uses the first negatively charged pore partition ligand (2,5,8‐tri‐(4‐pyridyl)‐1,3,4,6,7,9‐hexaazaphenalene, H‐tph) that simultaneously enables pore partition and charge reallocation. Over two dozen anionic pacs materials have been made to demonstrate their excellent chemical stability and a high degree of tunability. Notably, Ni ₃ ‐bdt‐tph (bdt=1,4‐benzeneditetrazolate) exhibits month‐long water stability, while CoV‐bdt‐tph sets a new benchmark for C ₂ H ₂ storage capacity under ambient conditions for ionic MOFs. In addition to tunable in‐framework modules, we show feasibility to tune the type and concentration of extra‐framework counter cations and their influence on both stability and capability to separate industrial C ₃ H ₈ /C ₃ H ₆ and C ₆ H ₆ /C ₆ H ₁₂ mixtures.

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Research Organization:: Univ. of California, Riverside, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0010596

OSTI ID:: 1976276

Alternate ID(s):: OSTI ID: 1844800; OSTI ID: 2205464

Journal Information:: Angewandte Chemie (International Edition), Vol. 61, Issue 13; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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CCDC 2124127: Experimental Crystal Structure Determination N., Hong, Anh; Emily, Kusumoputro,; Yanxiang, Wang, https://doi.org/10.5517/ccdc.csd.cc299b76 The current record is supplemented by this dataset	dataset	January 2022
CCDC 2124128: Experimental Crystal Structure Determination N., Hong, Anh; Emily, Kusumoputro,; Yanxiang, Wang, https://doi.org/10.5517/ccdc.csd.cc299b87 The current record is supplemented by this dataset	dataset	January 2022
CCDC 2124129: Experimental Crystal Structure Determination N., Hong, Anh; Emily, Kusumoputro,; Yanxiang, Wang, https://doi.org/10.5517/ccdc.csd.cc299b98 The current record is supplemented by this dataset	dataset	January 2022
CCDC 2124130: Experimental Crystal Structure Determination N., Hong, Anh; Emily, Kusumoputro,; Yanxiang, Wang, https://doi.org/10.5517/ccdc.csd.cc299bb9 The current record is supplemented by this dataset	dataset	January 2022