A Metal-Organic Framework (MOF)-Based Multifunctional Cargo Vehicle for Reactive-Gas Delivery and Catalysis

Kittikhunnatham, Preecha; Leith, Gabrielle A.; Mathur, Abhijai; Naglic, Jennifer K.; Martin, Corey R.; Park, Kyoung Chul; McCullough, Katherine; Jayaweera, H. Chathumal; Corkill, Ryan E.; Lauterbach, Jochen; Karakalos, Stavros G.; Smith, Mark D.; Garashchuk, Sophya; Chen, Donna A.; Shustova, Natalia B.

doi:10.1002/anie.202113909

Title: A Metal-Organic Framework (MOF)-Based Multifunctional Cargo Vehicle for Reactive-Gas Delivery and Catalysis

Journal Article · 29 November 2021 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.202113909 · OSTI ID:1976272

Kittikhunnatham, Preecha ^[1]; Leith, Gabrielle A. ^[1]; Mathur, Abhijai ^[1]; Naglic, Jennifer K. ^[1]; Martin, Corey R. ^[1]; Park, Kyoung Chul ^[1]; McCullough, Katherine ^[1]; Jayaweera, H. Chathumal ^[1]; Corkill, Ryan E. ^[1]; Lauterbach, Jochen ^[1]; Karakalos, Stavros G. ^[1]; Smith, Mark D. ^[1]; Garashchuk, Sophya ^[1];

^[1];

^[1]

University of South Carolina, Columbia, SC (United States)

Abstract The efficient delivery of reactive and toxic gaseous reagents to organic reactions was studied using metal‐organic frameworks (MOFs). The simultaneous cargo vehicle and catalytic capabilities of several MOFs were probed for the first time using the examples of aromatization, aminocarbonylation, and carbonylative Suzuki–Miyaura coupling reactions. These reactions highlight that MOFs can serve a dual role as a gas cargo vehicle and a catalyst, leading to product formation with yields similar to reactions employing pure gases. Furthermore, the MOFs can be recycled without sacrificing product yield, while simultaneously maintaining crystallinity. The reported findings were supported crystallographically and spectroscopically (e.g., diffuse reflectance infrared Fourier transform spectroscopy), foreshadowing a pathway for the development of multifunctional MOF‐based reagent‐catalyst cargo vessels for reactive gas reagents as an attractive alternative to the use of toxic pure gases or gas generators.

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Research Organization:: Univ. of South Carolina, Columbia, SC (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Dreyfus Foundation; Hans Fischer fellowship; National Science Foundation (NSF); University of South Carolina; USDOE

Grant/Contract Number:: SC0019360; CHE-1955768; OIA-1655740; GEAR-CRP 20-GC03

OSTI ID:: 1976272

Alternate ID(s):: OSTI ID: 1842854

Journal Information:: Angewandte Chemie (International Edition), Vol. 61, Issue 12; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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