Ion correlation and negative lithium transference in polyelectrolyte solutions

Bergstrom, Helen K.; Fong, Kara D.; Halat, David M.; Karouta, Carl A.; Celik, Hasan C.; Reimer, Jeffrey A.; McCloskey, Bryan D.

doi:10.1039/D3SC01224G

Title: Ion correlation and negative lithium transference in polyelectrolyte solutions

Journal Article · 20 June 2023 · Chemical Science

DOI: https://doi.org/10.1039/D3SC01224G · OSTI ID:1975418

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Department of Chemical & Biomolecular Engineering, University of California, Berkeley, CA 94720, USA, Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA
Department of Chemical & Biomolecular Engineering, University of California, Berkeley, CA 94720, USA, Materials Sciences Division, Joint Center for Energy Storage Research, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA
College of Chemistry NMR Facility, University of California, Berkeley, CA, 94720, USA

We demonstrate that contrary to previous reports, transference number decreases with increasing degree of polymerization in non-aqueous lithium-bearing polyelectrolyte solutions that have been proposed as next-generation battery electrolytes.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1975418

Alternate ID(s):: OSTI ID: 2282484

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 24 Vol. 14; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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