Oxygen-Vacancy Abundant Nanoporous Ni/NiMnO3/MnO2@NiMn Electrodes with Ultrahigh Capacitance and Energy Density for Supercapacitors
Abstract
High-performance energy storage devices (HPEDs) play a critical role in the realization of clean energy and thus enable the overarching pursuit of nonpolluting, green technologies. Supercapacitors are one class of such lucrative HPEDs; however, a serious limiting factor of supercapacitor technology is its sub-par energy density. Here, this report presents hitherto unchartered pathway of physical deformation, chemical dealloying, and microstructure engineering to produce ultrahigh-capacitance, energy-dense NiMn alloy electrodes. The activated electrode delivered an ultrahigh specific-capacitance of 2700 F/cm3 at 0.5 A/cm3. The symmetric device showcased an excellent energy density of 96.94 Wh/L and a remarkable cycle life of 95% retention after 10,000 cycles. Transmission electron microscopy and atom probe tomography studies revealed the evolution of a unique hierarchical microstructure comprising fine Ni/NiMnO3 nanoligaments within MnO2-rich nanoflakes. Theoretical analysis using density functional theory showed semimetallic nature of the nanoscaled oxygen-vacancy-rich NiMnO3 structure, highlighting enhanced carrier concentration and electronic conductivity of the active region. Furthermore, the geometrical model of NiMnO3 crystals revealed relatively large voids, likely providing channels for the ion intercalation/de-intercalation. The current processing approach is highly adaptable and can be applied to a wide range of material systems for designing highly efficient electrodes for energy-storage devices.
- Authors:
-
[3];
[4];
[5];
[5];
[6];
[1]
- Shiv Nadar University (India)
- University of Petroleum and Energy Studies (India)
- Colorado State Univ., Fort Collins, CO (United States)
- Univ. of North Texas, Denton, TX (United States)
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); North Carolina State University, Raleigh, NC (United States)
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Laboratory Directed Research and Development (LDRD) Program
- OSTI Identifier:
- 1975262
- Report Number(s):
- PNNL-SA-181415
Journal ID: ISSN 1944-8244
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 15; Journal Issue: 4; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; oxygen vacancies; physical deformation; atom probe tomography; density functional theory; hierarchical microstructures; defects in solids; electrical properties; electrodes; ions; transition metals
Citation Formats
Thomas, Arpit, Kumar, Ambrish, Perumal, Gopinath, Sharma, Ram Kumar, Manivasagam, Vignesh, Popat, Ketul C., Ayyagari, Aditya, Yu, Anqi, Tripathi, Shalini, Buck, Edgar C., Gwalani, Bharat, Bhogra, Meha, and Arora, Harpreet Singh. Oxygen-Vacancy Abundant Nanoporous Ni/NiMnO3/MnO2@NiMn Electrodes with Ultrahigh Capacitance and Energy Density for Supercapacitors. United States: N. p., 2023.
Web. doi:10.1021/acsami.2c16818.
Thomas, Arpit, Kumar, Ambrish, Perumal, Gopinath, Sharma, Ram Kumar, Manivasagam, Vignesh, Popat, Ketul C., Ayyagari, Aditya, Yu, Anqi, Tripathi, Shalini, Buck, Edgar C., Gwalani, Bharat, Bhogra, Meha, & Arora, Harpreet Singh. Oxygen-Vacancy Abundant Nanoporous Ni/NiMnO3/MnO2@NiMn Electrodes with Ultrahigh Capacitance and Energy Density for Supercapacitors. United States. https://doi.org/10.1021/acsami.2c16818
Thomas, Arpit, Kumar, Ambrish, Perumal, Gopinath, Sharma, Ram Kumar, Manivasagam, Vignesh, Popat, Ketul C., Ayyagari, Aditya, Yu, Anqi, Tripathi, Shalini, Buck, Edgar C., Gwalani, Bharat, Bhogra, Meha, and Arora, Harpreet Singh. Fri .
"Oxygen-Vacancy Abundant Nanoporous Ni/NiMnO3/MnO2@NiMn Electrodes with Ultrahigh Capacitance and Energy Density for Supercapacitors". United States. https://doi.org/10.1021/acsami.2c16818. https://www.osti.gov/servlets/purl/1975262.
@article{osti_1975262,
title = {Oxygen-Vacancy Abundant Nanoporous Ni/NiMnO3/MnO2@NiMn Electrodes with Ultrahigh Capacitance and Energy Density for Supercapacitors},
author = {Thomas, Arpit and Kumar, Ambrish and Perumal, Gopinath and Sharma, Ram Kumar and Manivasagam, Vignesh and Popat, Ketul C. and Ayyagari, Aditya and Yu, Anqi and Tripathi, Shalini and Buck, Edgar C. and Gwalani, Bharat and Bhogra, Meha and Arora, Harpreet Singh},
abstractNote = {High-performance energy storage devices (HPEDs) play a critical role in the realization of clean energy and thus enable the overarching pursuit of nonpolluting, green technologies. Supercapacitors are one class of such lucrative HPEDs; however, a serious limiting factor of supercapacitor technology is its sub-par energy density. Here, this report presents hitherto unchartered pathway of physical deformation, chemical dealloying, and microstructure engineering to produce ultrahigh-capacitance, energy-dense NiMn alloy electrodes. The activated electrode delivered an ultrahigh specific-capacitance of 2700 F/cm3 at 0.5 A/cm3. The symmetric device showcased an excellent energy density of 96.94 Wh/L and a remarkable cycle life of 95% retention after 10,000 cycles. Transmission electron microscopy and atom probe tomography studies revealed the evolution of a unique hierarchical microstructure comprising fine Ni/NiMnO3 nanoligaments within MnO2-rich nanoflakes. Theoretical analysis using density functional theory showed semimetallic nature of the nanoscaled oxygen-vacancy-rich NiMnO3 structure, highlighting enhanced carrier concentration and electronic conductivity of the active region. Furthermore, the geometrical model of NiMnO3 crystals revealed relatively large voids, likely providing channels for the ion intercalation/de-intercalation. The current processing approach is highly adaptable and can be applied to a wide range of material systems for designing highly efficient electrodes for energy-storage devices.},
doi = {10.1021/acsami.2c16818},
journal = {ACS Applied Materials and Interfaces},
number = 4,
volume = 15,
place = {United States},
year = {Fri Jan 20 00:00:00 EST 2023},
month = {Fri Jan 20 00:00:00 EST 2023}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
High Volumetric Energy Density Hybrid Supercapacitors Based on Reduced Graphene Oxide Scrolls
journal, June 2017
- Rani, Janardhanan R.; Thangavel, Ranjith; Oh, Se-I
- ACS Applied Materials & Interfaces, Vol. 9, Issue 27
Crystal Structure and Ferrimagnetism in NiMn and CoMn
journal, August 1958
- Cloud, W. H.
- Physical Review, Vol. 111, Issue 4
Hierarchical Fabric Decorated with Carbon Nanowire/Metal Oxide Nanocomposites for 1.6 V Wearable Aqueous Supercapacitors
journal, February 2018
- Fu, Wenbin; Zhao, Enbo; Ren, Xiaolei
- Advanced Energy Materials, Vol. 8, Issue 18
Birnessite nanotubes for electrochemical supercapacitor electrodes
journal, January 2011
- Roberts, Alexander J.; Slade, Robert C. T.
- Energy & Environmental Science, Vol. 4, Issue 8
High-Performance Ultrathin Flexible Solid-State Supercapacitors Based on Solution Processable Mo 1.33 C MXene and PEDOT:PSS
journal, November 2017
- Qin, Leiqiang; Tao, Quanzheng; El Ghazaly, Ahmed
- Advanced Functional Materials, Vol. 28, Issue 2
Engineering of MnO2-based nanocomposites for high-performance supercapacitors
journal, October 2015
- Wang, Jian-Gan; Kang, Feiyu; Wei, Bingqing
- Progress in Materials Science, Vol. 74
High-Energy All-Solid-State Symmetric Supercapacitor Based on Ni 3 S 2 Mesoporous Nanosheet-Decorated Three-Dimensional Reduced Graphene Oxide
journal, March 2017
- Zhang, Cheng; Huang, Ye; Tang, Shaolong
- ACS Energy Letters, Vol. 2, Issue 4
Supercapacitors of Nanocrystalline Metal–Organic Frameworks
journal, June 2014
- Choi, Kyung Min; Jeong, Hyung Mo; Park, Jung Hyo
- ACS Nano, Vol. 8, Issue 7
MnO2/Carbon Composites for Supercapacitor: Synthesis and Electrochemical Performance
journal, February 2020
- Wu, Dan; Xie, Xiubo; Zhang, Yuping
- Frontiers in Materials, Vol. 7
Recent advances in engineered metal oxide nanostructures for supercapacitor applications: experimental and theoretical aspects
journal, January 2021
- Kandasamy, Manikandan; Sahoo, Surjit; Nayak, Saroj Kumar
- Journal of Materials Chemistry A, Vol. 9, Issue 33
Engineering three-dimensional hybrid supercapacitors and microsupercapacitors for high-performance integrated energy storage
journal, March 2015
- El-Kady, Maher F.; Ihns, Melanie; Li, Mengping
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 14
Epitaxial grown self-supporting NiSe/Ni3S2/Ni12P5 vertical nanofiber arrays on Ni foam for high performance supercapacitor: Matched exposed facets and re-distribution of electron density
journal, January 2019
- Tao, Keyu; Gong, Yun; Lin, Jianhua
- Nano Energy, Vol. 55
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials
journal, September 2009
- Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola
- Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502
Electric field assisted chemical vapour deposition – a new method for the preparation of highly porous supercapacitor electrodes
journal, January 2014
- Warwick, Michael E. A.; Roberts, Alexander J.; Slade, Robert C. T.
- J. Mater. Chem. A, Vol. 2, Issue 17
High performance CuO@brass supercapacitor electrodes through surface activation
journal, January 2021
- Kumar, Ambrish; Thomas, Arpit; Garg, Mayank
- Journal of Materials Chemistry A, Vol. 9, Issue 14
Ultrathin and Porous Ni3
S2
/CoNi2
S4
3D-Network Structure for Superhigh Energy Density Asymmetric Supercapacitors
journal, July 2017
- He, Weidong; Wang, Chenggang; Li, Huiqiao
- Advanced Energy Materials, Vol. 7, Issue 21
Sulfidation of NiMn-Layered Double Hydroxides/Graphene Oxide Composites toward Supercapacitor Electrodes with Enhanced Performance
journal, December 2015
- Chen, Jingwei; Wang, Xu; Wang, Jiangxin
- Advanced Energy Materials, Vol. 6, Issue 5
Cyclic stability of supercapacitors: materials, energy storage mechanism, test methods, and device
journal, January 2021
- Wu, Qianghong; He, Tianqi; Zhang, Yikai
- Journal of Materials Chemistry A, Vol. 9, Issue 43
High energy density and enhanced stability of asymmetric supercapacitors with mesoporous MnO2@CNT and nanodot MoO3@CNT free-standing films
journal, May 2018
- Lee, Tae Hoon; Pham, Duy Tho; Sahoo, Ramkrishna
- Energy Storage Materials, Vol. 12
Synthesis and Characterization of MnO[sub 2]-Based Mixed Oxides as Supercapacitors
journal, January 2003
- Kim, Hansung; Popov, Branko N.
- Journal of The Electrochemical Society, Vol. 150, Issue 3
Wearable energy-dense and power-dense supercapacitor yarns enabled by scalable graphene–metallic textile composite electrodes
journal, June 2015
- Liu, Libin; Yu, You; Yan, Casey
- Nature Communications, Vol. 6, Issue 1
MnNiO 3 revisited with modern theoretical and experimental methods
journal, November 2017
- Dzubak, Allison L.; Mitra, Chandrima; Chance, Michael
- The Journal of Chemical Physics, Vol. 147, Issue 17
Self-Grown Oxy-Hydroxide@ Nanoporous Metal Electrode for High-Performance Supercapacitors
journal, October 2013
- Kang, JianLi; Hirata, Akihiko; Qiu, H. -J.
- Advanced Materials, Vol. 26, Issue 2
Greatly facilitated oxygen vacancy formation in ceria nanocrystallites
journal, January 2010
- Migani, Annapaola; Vayssilov, Georgi N.; Bromley, Stefan T.
- Chemical Communications, Vol. 46, Issue 32
Efficient and bending durable flexible perovskite solar cells via interface modification using a combination of thin MoS2 nanosheets and molecules binding to the perovskite
journal, May 2022
- Karimipour, Masoud; Khazraei, Sepideh; Kim, Byeong Jo
- Nano Energy, Vol. 95
Probing oxygen vacancy-induced mixed-valence states of nickel in LaNiO3 and their influence on electrocatalytic and magnetic properties
journal, September 2022
- Anjeline, C. Jesica; Marate, Bhaskara G.; Velu, D.
- Materials Chemistry and Physics, Vol. 288
Facile synthesis of MnO2-Cu composite electrode for high performance supercapacitor
journal, October 2021
- Kumar, A.; Thomas, A.; Gupta, A.
- Journal of Energy Storage, Vol. 42
Flexible free-standing Ni–Mn oxide antenna decorated CNT/nanofiber membrane for high-volumetric capacitance supercapacitors
journal, January 2021
- Fernando, Niranjala; Chinnappan, Amutha; Aziz, Atif
- Nanoscale, Vol. 13, Issue 45
Selectively dealloyed Ti/TiO 2 network nanostructures for supercapacitor application
journal, October 2014
- Chen, Po-Chun; Hsieh, Sheng-Jen; Zou, Jun
- Materials Letters, Vol. 133
Structural Directed Growth of Ultrathin Parallel Birnessite on β-MnO 2 for High-Performance Asymmetric Supercapacitors
journal, January 2018
- Zhu, Shijin; Li, Li; Liu, Jiabin
- ACS Nano, Vol. 12, Issue 2
Fabrication of hierarchical hollow Mn doped Ni(OH)2 nanostructures with enhanced catalytic activity towards electrochemical oxidation of methanol
journal, January 2019
- Dong, Bing; Li, Wei; Huang, Xiaoxiao
- Nano Energy, Vol. 55
MnO2 nanograsses on porous carbon cloth for flexible solid-state asymmetric supercapacitors with high energy density
journal, July 2017
- Wang, Haiyan; Xu, Chunmei; Chen, Yiqing
- Energy Storage Materials, Vol. 8
3D Freeze-Casting of Cellular Graphene Films for Ultrahigh-Power-Density Supercapacitors
journal, May 2016
- Shao, Yuanlong; El-Kady, Maher F.; Lin, Cheng-Wei
- Advanced Materials, Vol. 28, Issue 31
Oxygen vacancies enhancing capacitive properties of MnO2 nanorods for wearable asymmetric supercapacitors
journal, September 2014
- Zhai, Teng; Xie, Shilei; Yu, Minghao
- Nano Energy, Vol. 8
Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni
journal, January 2011
- Biesinger, Mark C.; Payne, Brad P.; Grosvenor, Andrew P.
- Applied Surface Science, Vol. 257, Issue 7, p. 2717-2730
Fe2O3 Nanoparticles Anchored on the Ti3C2Tx MXene Paper for Flexible Supercapacitors with Ultrahigh Volumetric Capacitance
journal, September 2020
- Ma, Yonglu; Sheng, Hongwei; Dou, Wei
- ACS Applied Materials & Interfaces, Vol. 12, Issue 37
Ni-Doped Cobalt–Cobalt Nitride Heterostructure Arrays for High-Power Supercapacitors
journal, September 2018
- Liu, Ximeng; Zang, Wenjie; Guan, Cao
- ACS Energy Letters, Vol. 3, Issue 10
Engineering Bimetallic NiFe‐Based Hydroxides/Selenides Heterostructure Nanosheet Arrays for Highly‐Efficient Oxygen Evolution Reaction
journal, January 2021
- Liu, Caichi; Han, Yu; Yao, Libing
- Small, Vol. 17, Issue 7
Nano-Sized Structurally Disordered Metal Oxide Composite Aerogels as High-Power Anodes in Hybrid Supercapacitors
journal, February 2018
- Huang, Haijian; Wang, Xing; Tervoort, Elena
- ACS Nano, Vol. 12, Issue 3
Dislocation-Mediated Conductivity in Oxides: Progress, Challenges, and Opportunities
journal, May 2021
- Armstrong, Micah D.; Lan, Kai-Wei; Guo, Yiwen
- ACS Nano, Vol. 15, Issue 6
On chip MnO2-based 3D micro-supercapacitors with ultra-high areal energy density
journal, June 2021
- Bounor, Botayna; Asbani, Bouchra; Douard, Camille
- Energy Storage Materials, Vol. 38
Towards ultrahigh volumetric capacitance: graphene derived highly dense but porous carbons for supercapacitors
journal, October 2013
- Tao, Ying; Xie, Xiaoying; Lv, Wei
- Scientific Reports, Vol. 3, Issue 1
Boosting gravimetric and volumetric energy density via engineering macroporous MXene films for supercapacitors
journal, September 2020
- Yao, Mengyao; Chen, Yaoyan; Wang, Zhe
- Chemical Engineering Journal, Vol. 395
Molecular-Level Heterostructures Assembled from Titanium Carbide MXene and Ni–Co–Al Layered Double-Hydroxide Nanosheets for All-Solid-State Flexible Asymmetric High-Energy Supercapacitors
journal, December 2017
- Zhao, Ruizheng; Wang, Mengqiao; Zhao, Danyang
- ACS Energy Letters, Vol. 3, Issue 1
True Performance Metrics in Electrochemical Energy Storage
journal, November 2011
- Gogotsi, Y.; Simon, P.
- Science, Vol. 334, Issue 6058
Hierarchical NiMn Layered Double Hydroxide/Carbon Nanotubes Architecture with Superb Energy Density for Flexible Supercapacitors
journal, January 2014
- Zhao, Jingwen; Chen, Jiale; Xu, Simin
- Advanced Functional Materials, Vol. 24, Issue 20
Metal–Organic Framework-Derived Nanoporous Metal Oxides toward Supercapacitor Applications: Progress and Prospects
journal, May 2017
- Salunkhe, Rahul R.; Kaneti, Yusuf V.; Yamauchi, Yusuke
- ACS Nano, Vol. 11, Issue 6
A Fast Proton‐Induced Pseudocapacitive Supercapacitor with High Energy and Power Density
journal, October 2021
- Xu, Tiezhu; Li, Zhiwei; Wang, Di
- Advanced Functional Materials, Vol. 32, Issue 5
Metal/Metal-Oxide Interfaces: How Metal Contacts Affect the Work Function and Band Structure of MoO 3
journal, August 2012
- Greiner, Mark T.; Chai, Lily; Helander, Michael G.
- Advanced Functional Materials, Vol. 23, Issue 2
First-principles study of electronic structure and photocatalytic properties of MnNiO 3 as an alkaline oxygen-evolution photocatalyst
journal, January 2015
- Yu, Jie; Yan, Qimin; Chen, Wei
- Chemical Communications, Vol. 51, Issue 14
Advanced Oxygen‐Vacancy Ce‐Doped MoO
3
Ultrathin Nanoflakes Anode Materials Used as Asymmetric Supercapacitors with Ultrahigh Energy Density
journal, March 2022
- Xu, Liming; Zhou, Weiqiang; Chao, Shixing
- Advanced Energy Materials, Vol. 12, Issue 16
Self-consistent Hubbard parameters from density-functional perturbation theory in the ultrasoft and projector-augmented wave formulations
journal, January 2021
- Timrov, Iurii; Marzari, Nicola; Cococcioni, Matteo
- Physical Review B, Vol. 103, Issue 4
A High-Energy Density Asymmetric Supercapacitor Based on Fe 2 O 3 Nanoneedle Arrays and NiCo 2 O 4 /Ni(OH) 2 Hybrid Nanosheet Arrays Grown on SiC Nanowire Networks as Free-Standing Advanced Electrodes
journal, January 2018
- Zhao, Jian; Li, Zhenjiang; Yuan, Xiangcheng
- Advanced Energy Materials, Vol. 8, Issue 12
Flexible NiO micro-rods/nanoporous Ni/metallic glass electrode with sandwich structure for high performance supercapacitors
journal, February 2019
- Zheng, Donghui; Zhao, Feng; Li, Yongyan
- Electrochimica Acta, Vol. 297
A high energy density aqueous hybrid supercapacitor with widened potential window through multi approaches
journal, May 2019
- Zhang, Si-Wen; Yin, Bo-Si; Liu, Xi-Xia
- Nano Energy, Vol. 59
On chip, all solid-state and flexible micro-supercapacitors with high performance based on MnOx/Au multilayers
journal, January 2013
- Si, Wenping; Yan, Chenglin; Chen, Yao
- Energy & Environmental Science, Vol. 6, Issue 11
Extraordinary Supercapacitor Performance of a Multicomponent and Mixed-Valence Oxyhydroxide
journal, May 2015
- Kang, Jianli; Hirata, Akihiko; Chen, Luyang
- Angewandte Chemie, Vol. 127, Issue 28
Soft self-consistent pseudopotentials in a generalized eigenvalue formalism
journal, April 1990
- Vanderbilt, David
- Physical Review B, Vol. 41, Issue 11, p. 7892-7895
Understanding the charge storage mechanism of supercapacitors: in situ/operando spectroscopic approaches and theoretical investigations
journal, January 2021
- Patra, Abhinandan; K., Namsheer; Jose, Jeena Rose
- Journal of Materials Chemistry A, Vol. 9, Issue 46
Construction of Hierarchical α-MnO 2 Nanowires@Ultrathin δ-MnO 2 Nanosheets Core–Shell Nanostructure with Excellent Cycling Stability for High-Power Asymmetric Supercapacitor Electrodes
journal, April 2016
- Ma, Zhipeng; Shao, Guangjie; Fan, Yuqian
- ACS Applied Materials & Interfaces, Vol. 8, Issue 14
Scalable fabrication of MnO 2 nanostructure deposited on free-standing Ni nanocone arrays for ultrathin, flexible, high-performance micro-supercapacitor
journal, January 2014
- Su, Zijin; Yang, Cheng; Xie, Binghe
- Energy Environ. Sci., Vol. 7, Issue 8
High-pressure torsion to induce oxygen vacancies in nanocrystals of magnesium oxide: Enhanced light absorbance, photocatalysis and significance in geology
journal, June 2020
- Fujita, Ikuro; Edalati, Kaveh; Wang, Qing
- Materialia, Vol. 11
Framework Doping of Ni Enhances Pseudocapacitive Na-Ion Storage of (Ni)MnO 2 Layered Birnessite
journal, October 2019
- Shan, Xiaoqiang; Guo, Fenghua; Page, Katharine
- Chemistry of Materials, Vol. 31, Issue 21
Regenerable Cu-intercalated MnO2 layered cathode for highly cyclable energy dense batteries
journal, March 2017
- Yadav, Gautam G.; Gallaway, Joshua W.; Turney, Damon E.
- Nature Communications, Vol. 8, Issue 1
Carrier localization in perovskite nickelates from oxygen vacancies
journal, October 2019
- Kotiuga, Michele; Zhang, Zhen; Li, Jiarui
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 44
Controlled Hydrolysis of Metal–Organic Frameworks: Hierarchical Ni/Co-Layered Double Hydroxide Microspheres for High-Performance Supercapacitors
journal, May 2019
- Xiao, Zhenyu; Mei, Yingjie; Yuan, Shuai
- ACS Nano, Vol. 13, Issue 6
Fabrication of Oxygen‐Vacancy Abundant NiMn‐Layered Double Hydroxides for Ultrahigh Capacity Supercapacitors
journal, January 2020
- Tang, Yanqun; Shen, Haoming; Cheng, Jinqian
- Advanced Functional Materials, Vol. 30, Issue 11
Attractive Forces At Interfaces
journal, December 1964
- Fowkes, Frederick M.
- Industrial & Engineering Chemistry, Vol. 56, Issue 12, p. 40-52
Approaches to design a surface with tunable wettability: a review on surface properties
journal, September 2020
- Jothi Prakash, C. G.; Prasanth, R.
- Journal of Materials Science, Vol. 56, Issue 1