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Title: Chlorination of Pu and U Metal Using GaCl 3

Journal Article · · Inorganic Chemistry
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [2];  [3]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States
  2. Pit Technologies, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States
  3. Materials and Physics Applications Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States
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Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC52-06NA25396
OSTI ID:
1974820
Alternate ID(s):
OSTI ID: 1975651
Journal Information:
Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 22 Vol. 62; ISSN 0020-1669
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (31)

Coordination and Redox Isomerization in the Reduction of a Uranium(III) Monoarene Complex journal July 2014
A delocalized arene-bridged diuranium single-molecule magnet journal April 2011
[AnI 3 (THF) 4 ] (An = Np, Pu) Preparation Bypassing An 0 Metal Precursors: Access to Np 3+ /Pu 3+ Nonaqueous and Organometallic Complexes journal December 2021
Synthesis and characterization of NpCl 4 (DME) 2 and PuCl 4 (DME) 2 neutral transuranic An( iv ) starting materials journal January 2014
Syntheses, structures, and solid-state carbon-13 NMR of two .eta.6-arene uranium(IV) complexes, [U(C6Me6)Cl2(.mu.-Cl)3UCl2(C6Me6)]AlCl4 and (C6Me6)UCl2(.mu.-Cl)3UCl2(.mu.-Cl)3UCl2(C6Me6) journal February 1986
Preparation and structure of [U2(C6Me6)2Cl7]+, the first uranium(IV) complex with a neutral arene in .eta.6-coordination journal May 1985
The preparation of anhydrous plutonium trichloride journal November 1960
Bonding Changes in Plutonium(III) and Americium(III) Borates journal August 2011
Synthesis and structural characterization of a molecular plutonium(iv) compound constructed from dimeric building blocks journal January 2007
Solutions of Gallium Trichloride in Ethers: A 71Ga NMR Study and the X-Ray Structure of GaCl3 · Monoglyme journal July 1990
On the covalency of U(III)–Cl, U(IV)–Cl bonding in a LiCl–KCl eutectic melt at 450°C: Spectroscopic evidences from their 5f–6d and 5f–5f electronic transitions journal September 2015
Non-aqueous neptunium and plutonium redox behaviour in THF – access to a rare Np( iii ) synthetic precursor journal January 2018
2.2.2-Cryptand complexes of neptunium( iii ) and plutonium( iii ) journal January 2022
Plutonium(IV) quantification in acidic process solutions using partial least-squares regression applied to UV–Vis spectrophotometry journal February 2022
Preparation of the First Electrolytic Plutonium and of Uranium from Fused Chlorides journal November 1982
A new Pu( iii ) coordination geometry in (C 5 H 5 NBr) 2 [PuCl 3 (H 2 O) 5 ]·2Cl·2H 2 O as obtained via supramolecular assembly in aqueous, high chloride media journal January 2017
Low-Valent Uranium Iodides: Straightforward Solution Syntheses of UI 3 and UI 4 Etherates journal October 2008
A Convenient Entry into Trivalent Actinide Chemistry: Synthesis and Characterization of AnI3(THF)4 and An[N(SiMe3)2]3 (An = U, Np, Pu) journal May 1994
Uranium(IV) Nucleophilic Carbene Complexes journal June 2011
A Pseudotetrahedral Uranium(V) Complex journal June 2018
Convenient Syntheses of Trivalent Uranium Halide Starting Materials without Uranium Metal journal May 2021
Structure, Spectroscopy, and Theoretical Analysis of Zero- and Three-Dimensional Lithium Plutonium Fluorides: Li 4 PuF 8 and LiPuF 5 journal October 2019
Thorium(IV) and Uranium(IV) Halide Complexes Supported by Bulky β-Diketiminate Ligands journal January 2013
Lewis base adducts of uranium triiodide: a new class of synthetically useful precursors for trivalent uranium chemistry journal May 1989
The Structure and Synthesis of Plutonium(III) Chlorides from Aqueous Solution journal October 2006
UI 4 (1,4-dioxane) 2 , [UCl 4 (1,4-dioxane)] 2 , and UI 3 (1,4-dioxane) 1.5 : Stable and Versatile Starting Materials for Low- and High-Valent Uranium Chemistry journal April 2011
Well-defined molecular uranium( iii ) chloride complexes journal January 2014
Werner-Type Complexes of Uranium(III) and (IV) journal January 2020
Low-Valent Molecular Plutonium Halide Complexes journal September 2008
β-Diketiminate Derivatives of Alkali Metals and Uranium journal September 2013
Plutonium trichloride: Preparation by reaction with phosgene or carbon tetrachloride, and bomb reduction to metal report December 1953

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