Search for the interatomic Auger effect in Nitrous Oxide

Mailhiot, M.; Hikosaka, Y.; Jänkälä, K.; Kivimäki, A.; Küstner-Wetekam, C.; Palaudoux, J.; Pelimanni, E.; Penent, F.; Zindel, C.; Patanen, M.; Lablanquie, P.; Huttula, M.; Hans, A.

doi:10.1016/j.elspec.2023.147333

Title: Search for the interatomic Auger effect in Nitrous Oxide

Journal Article · 18 May 2023 · Journal of Electron Spectroscopy and Related Phenomena

DOI: https://doi.org/10.1016/j.elspec.2023.147333 · OSTI ID:1974487

^[1]; Hikosaka, Y. ^[2]; Jänkälä, K. ^[1]; Kivimäki, A. ^[3]; Küstner-Wetekam, C. ^[4]; Palaudoux, J. ^[5]; Pelimanni, E. ^[6]; Penent, F. ^[5]; Zindel, C. ^[4]; Patanen, M. ^[1]; Lablanquie, P. ^[5]; Huttula, M. ^[1]; Hans, A. ^[7]

University of Oulu (Finland)
University of Toyama (Japan)
University of Oulu (Finland); Lund Univ. (Sweden). MAX IV Laboratory
Univ. Kassel (Germany)
Sorbonne Univ., Paris (France)
University of Oulu (Finland); Argonne National Laboratory (ANL), Argonne, IL (United States)
University of Oulu (Finland); Univ. Kassel (Germany)

The interatomic Auger effect following O 1s ionization in NO has been experimentally investigated using multi-electron coincidence spectroscopy. The expected transition energies have been established by comparison to the measured N 1s-1v-1 core-valence double ionization energies. We describe a procedure to eliminate the background of two competing processes contributing spectroscopic signatures to the same energy range, namely double Auger decay of the O 1s vacancy and direct single-photon double ionization into the N 1s-1v-1 states. While the interatomic Auger transitions could not be successfully isolated, we provide an upper boundary of the transition probability of 0.07% with respect to the dominant single Auger decay after O 1s ionization.

View Journal Article

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Swedish Research Council (SRC); Swedish Governmental Agency for Innovation Systems; Formas

Grant/Contract Number:: AC02-06CH11357; 2018-07152; 2018- 04969; 2019-02496; DEAC02-06CH11357

OSTI ID:: 1974487

Alternate ID(s):: OSTI ID: 2423778

Journal Information:: Journal of Electron Spectroscopy and Related Phenomena, Vol. 265; ISSN 0368-2048

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (35)

Performance and characterization of the FinEstBeAMS beamline at the MAX IV Laboratory Chernenko, Kirill; Kivimäki, Antti; Pärna, Rainer Journal of Synchrotron Radiation, Vol. 28, Issue 5 https://doi.org/10.1107/S1600577521006032	journal	July 2021
Experimental evidence of interatomic resonant Auger electron emission from fixed-in-space NO molecules Yamazaki, Masakazu; Adachi, Jun-ichi; Teramoto, Takahiro Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 40, Issue 13 https://doi.org/10.1088/0953-4075/40/13/F02	journal	June 2007
Multiatom resonant photoemission Kay, A. W.; Garcia de Abajo, F. J.; Yang, S. -H. Physical Review B, Vol. 63, Issue 11 https://doi.org/10.1103/PhysRevB.63.115119	journal	March 2001
Single, double, and triple Auger decays from 1s shake-up states of the oxygen molecule Kaneyasu, T.; Odagiri, T.; Nakagawa, M. The Journal of Chemical Physics, Vol. 147, Issue 10 https://doi.org/10.1063/1.4996572	journal	September 2017
�ber den Zusammenhang zwischen ?- und ?-Strahlen Meitner, Lise Zeitschrift f�r Physik, Vol. 9, Issue 1 https://doi.org/10.1007/BF01326963	journal	December 1922
Interpretation of the Auger electron spectra of nitrous oxide Larkins, F. P. The Journal of Chemical Physics, Vol. 86, Issue 6 https://doi.org/10.1063/1.451982	journal	March 1987
Interatomic transitions and relaxation effects in Auger spectra of several gas adsorbates on transition metals Salmerón,, M.; Baró, A. M.; Rojo, J. M. Physical Review B, Vol. 13, Issue 10 https://doi.org/10.1103/PhysRevB.13.4348	journal	May 1976
Calculated photoionization cross sections and relative experimental photoionization intensities for a selection of small molecules Rabalais, J. Wayne; Debies, Thomas P.; Berkosky, Jeffrey L. The Journal of Chemical Physics, Vol. 61, Issue 2 https://doi.org/10.1063/1.1681926	journal	July 1974
Interatomic and Intermolecular Coulombic Decay Jahnke, Till; Hergenhahn, Uwe; Winter, Bernd Chemical Reviews, Vol. 120, Issue 20 https://doi.org/10.1021/acs.chemrev.0c00106	journal	October 2020
Ultrafast Molecular Three-Electron Auger Decay Feifel, Raimund; Eland, John H. D.; Squibb, Richard J. Physical Review Letters, Vol. 116, Issue 7 https://doi.org/10.1103/PhysRevLett.116.073001	journal	February 2016
Multi-Atom Resonant Photoemission: A Method for Determining Near-Neighbor Atomic Identities and Bonding Kay, A.; Arenholz, E.; Mun, S. Science, Vol. 281, Issue 5377 https://doi.org/10.1126/science.281.5377.679	journal	July 1998
Site-selected Auger electron spectroscopy of N2O Bolognesi, Paola; Coreno, Marcello; Avaldi, Lorenzo The Journal of Chemical Physics, Vol. 125, Issue 5 https://doi.org/10.1063/1.2213254	journal	August 2006
Multielectron spectroscopy: Auger decays of the krypton3dhole Palaudoux, J.; Lablanquie, P.; Andric, L. Physical Review A, Vol. 82, Issue 4 https://doi.org/10.1103/PhysRevA.82.043419	journal	October 2010
Auger emission and colour centres in lithium fluoride Lord, D. G.; Gallon, T. E. Surface Science, Vol. 36, Issue 2 https://doi.org/10.1016/0039-6028(73)90406-8	journal	May 1973
Interatomic Auger decay in CO molecule Ogurtsov, G. N.; Mikoushkin, V. M.; Semenov, S. K. Journal of Electron Spectroscopy and Related Phenomena, Vol. 161, Issue 1-3 https://doi.org/10.1016/j.elspec.2007.02.020	journal	October 2007
Low Energy Auger Emission from Lithium Fluoride Gallon, T. E.; Matthew, J. A. D. physica status solidi (b), Vol. 41, Issue 1 https://doi.org/10.1002/pssb.19700410138	journal	January 1970
Symmetry and vibrationally resolved absorption spectra near the O K edge of N2O: Experiment and theory Tanaka, T.; Ueda, K.; Feifel, R. Chemical Physics Letters, Vol. 435, Issue 4-6 https://doi.org/10.1016/j.cplett.2006.12.071	journal	February 2007
Magnetic bottle electron spectrometer using permanent magnets Tsuboi, Toshio; Xu, Emily Y.; Bae, Young K. Review of Scientific Instruments, Vol. 59, Issue 8 https://doi.org/10.1063/1.1139722	journal	August 1988
Interatomic Auger transitions: A survey Citrin, P. H. Journal of Electron Spectroscopy and Related Phenomena, Vol. 5, Issue 1 https://doi.org/10.1016/0368-2048(74)85019-X	journal	January 1974
Triple Photoionization of Lithium Wehlitz, R.; Huang, M. -T.; DePaola, B. D. Physical Review Letters, Vol. 81, Issue 9 https://doi.org/10.1103/PhysRevLett.81.1813	journal	August 1998
Multielectron spectroscopy: Auger decays of the argon 2p hole Lablanquie, P.; Andric, L.; Palaudoux, J. Journal of Electron Spectroscopy and Related Phenomena, Vol. 156-158 https://doi.org/10.1016/j.elspec.2006.11.062	journal	May 2007
X-ray excited photoelectron spectra of free molecules containing oxygen Nordfors, D.; Nilsson, A.; M»rtensson, N. Journal of Electron Spectroscopy and Related Phenomena, Vol. 56, Issue 2 https://doi.org/10.1016/0368-2048(91)80009-J	journal	May 1991
Complete Two-Electron Spectra in Double Photoionization: The Rare Gases Ar, Kr, and Xe Eland, J. H. D.; Vieuxmaire, O.; Kinugawa, T. Physical Review Letters, Vol. 90, Issue 5 https://doi.org/10.1103/PhysRevLett.90.053003	journal	February 2003
Far-Zone Resonant Energy Transfer in X-ray Photoemission as a Structure Determination Tool Céolin, Denis; Rueff, Jean-Pascal; Zimin, Andrey The Journal of Physical Chemistry Letters, Vol. 8, Issue 12 https://doi.org/10.1021/acs.jpclett.7b00835	journal	June 2017
Multiatom Resonant Photoemission: Theory and Systematics García de Abajo, F. J.; Fadley, C. S.; Van Hove, M. A. Physical Review Letters, Vol. 82, Issue 20 https://doi.org/10.1103/PhysRevLett.82.4126	journal	May 1999
New results on core excited N₂O obtained by electron–ion coincidence spectroscopy^a) Ferrand‐Tanaka, Laurence; Simon, Marc; Thissen, Roland Review of Scientific Instruments, Vol. 67, Issue 2 https://doi.org/10.1063/1.1146595	journal	February 1996
Sur l'effet photoélectrique composé Auger, Pierre Journal de Physique et le Radium, Vol. 6, Issue 6 https://doi.org/10.1051/jphysrad:0192500606020500	journal	January 1925
Interatomic resonant Auger effect in N₂O Deinert, Sascha; Schrodt, Alexander; Hartmann, Gregor Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 53, Issue 22 https://doi.org/10.1088/1361-6455/abbd2f	journal	October 2020
Nearest-Neighbor-Atom Core-Hole Transfer in Isolated Molecules Guillemin, R.; Hemmers, O.; Rolles, D. Physical Review Letters, Vol. 92, Issue 22 https://doi.org/10.1103/PhysRevLett.92.223002	journal	June 2004
FinEstBeaMS – A wide-range Finnish-Estonian Beamline for Materials Science at the 1.5 GeV storage ring at the MAX IV Laboratory Pärna, R.; Sankari, R.; Kukk, E. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 859 https://doi.org/10.1016/j.nima.2017.04.002	journal	July 2017
High resolution auger electron spectrum of MgO(100) Bassett, P. J.; Gallon, T. E.; Prutton, M. Surface Science, Vol. 33, Issue 1 https://doi.org/10.1016/0039-6028(72)90114-8	journal	October 1972
Multielectron coincidence spectroscopy for core-valence doubly ionized states of CO Hikosaka, Y.; Kaneyasu, T.; Shigemasa, E. The Journal of Chemical Physics, Vol. 127, Issue 4 https://doi.org/10.1063/1.2750341	journal	July 2007
Direct observation of three-electron collective decay in a resonant Auger process Eland, J. H. D.; Squibb, R. J.; Mucke, M. New Journal of Physics, Vol. 17, Issue 12 https://doi.org/10.1088/1367-2630/17/12/122001	journal	December 2015
Interatomic resonant Auger effects in core-level photoemission from NO and CS ₂ molecules Yamazaki, M.; Adachi, J.; Teramoto, T. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 46, Issue 11 https://doi.org/10.1088/0953-4075/46/11/115101	journal	May 2013
Many-electron dynamics of atomic processes studied by photon-induced fluorescence spectroscopy Sukhorukov, V. L.; Petrov, I. D.; Lagutin, B. M. Physics Reports, Vol. 786 https://doi.org/10.1016/j.physrep.2018.10.004	journal	January 2019

Similar Records

Influence of Selective Carbon 1s Excitation on Auger–Meitner Decay in the ESCA Molecule

Journal Article · 2024 · Journal of Physical Chemistry Letters · OSTI ID:2336816

Fouda, Adam E. A.; Lindblom, V.; Southworth, S. H.; +5 more

Forming Bonds While Breaking Old Ones: Isomer-Dependent Formation of H₃O⁺ from Aminobenzoic Acid During X-ray-Induced Fragmentation

Journal Article · 2023 · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory · OSTI ID:1923723

Abid, Abdul Rahman; Veteläinen, Onni; Boudjemia, Nacer; +6 more

Negative-Ion Formation upon Soft X-ray Photoexcitation of 2-Propanol

Journal Article · 2025 · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory · OSTI ID:2524602

Kivimäki, Antti; Pelimanni, Eetu; Chernenko, Kirill; +2 more

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS
Spectroscopy
Interatomic auger effect
Core-valence double-ionization
Double auger decay

Title: Search for the interatomic Auger effect in Nitrous Oxide

Citation Formats

References (35)

Similar Records

Related Subjects