Hybrid Monomer Design Synergizing Property Trade‐offs in Developing Polymers for Circularity and Performance

Shi, Changxia; Reilly, Liam T.; Chen, Eugene Y. ‐X.

doi:10.1002/anie.202301850

Title: Hybrid Monomer Design Synergizing Property Trade‐offs in Developing Polymers for Circularity and Performance

Journal Article · 09 May 2023 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.202301850 · OSTI ID:1973308

Shi, Changxia ^[1]; Reilly, Liam T. ^[1];

^[1]

Department of Chemistry Colorado State University Fort Collins CO 80523-1872 USA

Abstract Current search for more sustainable plastics seeks to redesign polymers possessing both chemical recyclability to monomer for a circular plastics economy and desirable performance that can rival or even exceed today's non‐recyclable or hard‐to‐recycle petroleum‐based incumbents. However, within a traditional monomer framework it is challenging to optimize, concurrently , contrasting polymerizability/depolymerizability and recyclability/performance properties. Here, we highlight the emerging hybrid monomer design strategy to develop intrinsically circular polymers with tunable performance properties, aiming to unify desired, but otherwise conflicting, properties in a single monomer. Conceptually, this design hybridizes parent monomer pairs of contrasting, mismatching, or matching properties into offspring monomers that not only unify the above‐described conflicting properties but also radically alter the resultant polymer properties far beyond the limits of what either parent homopolymers or their copolymers can achieve.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1973308

Alternate ID(s):: OSTI ID: 2424250; OSTI ID: 1973309

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 31 Vol. 62; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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