Hard and semi-hard Fe-based magnetic materials

Mohapatra, Jeotikanta; Liu, Xubo; Joshi, Pramanand; Liu, J. Ping

doi:10.1016/j.jallcom.2023.170258

Title: Hard and semi-hard Fe-based magnetic materials

Journal Article · 24 April 2023 · Journal of Alloys and Compounds

DOI: https://doi.org/10.1016/j.jallcom.2023.170258 · OSTI ID:1972804

^[1]; Liu, Xubo ^[2];

^[1]; Liu, J. Ping ^[1]

Univ. of Texas, Arlington, TX (United States)
Ames Lab., Ames, IA (United States)

Iron (Fe) is the most important ferromagnetic element, not only for its high magnetic moment and high Curie temperature but for its abundance as well. Fe-based magnetic materials are therefore widely applied in technologies and industries, with most of the applications for soft magnetic materials, because of the low magnetocrystalline anisotropy (MCA) of Fe. However, it is possible to realize magnetic hardening in Fe-based materials as we have learned from the early carbon steel permanent magnets although their coercivity was modest. Recent efforts to search for rare-earth-free hard magnetic materials have shown more promising evidences for achieving high MCA in Fe-based materials. In this paper, we review the history and the recent developments of Fe-based hard and semi-hard magnetic materials with a focus on mechanisms of high MCA in Fe-based phases and the related crystal and electronic structures. Here, we have tabulated and discussed the structures and the magnetic properties of the Fe-based binary or ternary systems containing p-block and d-block elements, with many of them showing considerable MCA. Furthermore, it is important to know and to understand that the MCA in Fe-based magnetic materials can be tailored/enhanced through chemical and/or structural modifications that will lead to “artificially engineered” hard and semi-hard magnetic materials for advanced permanent magnets in the future.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Buildings and Industry. Advanced Materials & Manufacturing Technologies Office (AMMTO)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1972804

Report Number(s):: IS-J 11,050

Journal Information:: Journal of Alloys and Compounds, Vol. 955; ISSN 0925-8388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (147)

Advances in nanostructured permanent magnets research Poudyal, Narayan; Ping Liu, J. Journal of Physics D: Applied Physics, Vol. 46, Issue 4 https://doi.org/10.1088/0022-3727/46/4/043001	journal	December 2012
Bulk combinatorial analysis for searching new rare-earth free permanent magnets: Reactive crucible melting applied to the Fe-Sn binary system Fayyazi, Bahar; Skokov, Konstantin P.; Faske, Tom Acta Materialia, Vol. 141 https://doi.org/10.1016/j.actamat.2017.09.036	journal	December 2017
Semi-hard magnetic nanocomposites based on out-of-equilibrium Fe2+δNb and Fe2+δTa Laves phases Gabay, A. M.; Hadjipanayis, G. C. AIP Advances, Vol. 9, Issue 3 https://doi.org/10.1063/1.5079727	journal	March 2019
Superior Magnetic Performance in FePt L1 ₀ Nanomaterials Son, Kwanghyo; Ryu, Gihun; Jeong, Hyeon‐Ho Small, Vol. 15, Issue 34 https://doi.org/10.1002/smll.201902353	journal	July 2019
Magnetic Structure of Fe₃Ga Studied by Neutron Diffraction Kawamiya, Nobuo; Adachi, Kengo Transactions of the Japan Institute of Metals, Vol. 23, Issue 6 https://doi.org/10.2320/matertrans1960.23.296	journal	January 1982
Preparation of the Nanowire Form of ε-Fe ₂ O ₃ Single Crystal and a Study of the Formation Process Sakurai, Shunsuke; Tomita, Kotaro; Hashimoto, Kazuhito The Journal of Physical Chemistry C, Vol. 112, Issue 51 https://doi.org/10.1021/jp806336f	journal	December 2008
Band-filling effect on magnetic anisotropy using a Green's function method Ke, Liqin; van Schilfgaarde, Mark Physical Review B, Vol. 92, Issue 1 https://doi.org/10.1103/PhysRevB.92.014423	journal	July 2015
Properties of Fe2 P crystals prepared from a liquid copper medium Andersson, Y.; Rundqvist, S.; Beckman, O. Physica Status Solidi (a), Vol. 49, Issue 2 https://doi.org/10.1002/pssa.2210490260	journal	October 1978
Synthesis and characterisation of (Fe,Co)2–3B microcrystalline alloys Wallisch, Wolfgang; Fidler, Josef; Toson, Peter Journal of Alloys and Compounds, Vol. 644 https://doi.org/10.1016/j.jallcom.2015.04.179	journal	September 2015
The magnetic moments and their long-range ordering for Fe atoms in a wide variety of metallic environments Ayuela, A.; March, N. H. International Journal of Quantum Chemistry, Vol. 110, Issue 15 https://doi.org/10.1002/qua.22764	journal	August 2010
On-the-fly machine-learning for high-throughput experiments: search for rare-earth-free permanent magnets Kusne, Aaron Gilad; Gao, Tieren; Mehta, Apurva Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06367	journal	September 2014
αʺ-Fe16N2 phase epitaxially grown by sputter beam method Okamoto, Satoshi; Kitakami, Osamu; Shimada, Yutaka Journal of Applied Physics, Vol. 79, Issue 8 https://doi.org/10.1063/1.361301	journal	January 1996
Nanometer-size hard magnetic ferrite exhibiting high optical-transparency and nonlinear optical-magnetoelectric effect Ohkoshi, Shin-ichi; Namai, Asuka; Imoto, Kenta Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep14414	journal	October 2015
τ-MnAl with high coercivity and saturation magnetization Wei, J. Z.; Song, Z. G.; Yang, Y. B. AIP Advances, Vol. 4, Issue 12 https://doi.org/10.1063/1.4903773	journal	December 2014
Environment-friendly bulk Fe16N2 permanent magnet: Review and prospective Wang, Jian-Ping Journal of Magnetism and Magnetic Materials, Vol. 497 https://doi.org/10.1016/j.jmmm.2019.165962	journal	March 2020
The magnetic transition in ε-Fe₂O₃ nanoparticles: Magnetic properties and hyperfine interactions from Mössbauer spectroscopy Kohout, J.; Brázda, P.; Závěta, K. Journal of Applied Physics, Vol. 117, Issue 17 https://doi.org/10.1063/1.4907610	journal	May 2015
First-principles theory of surface magnetocrystalline anisotropy and the diatomic-pair model Wang, Ding-sheng; Wu, Ruqian; Freeman, A. J. Physical Review B, Vol. 47, Issue 22 https://doi.org/10.1103/PhysRevB.47.14932	journal	June 1993
Route towards finding large magnetic anisotropy in nanocomposites: Application to a W 1 − x Re x /Fe multilayer Bhandary, Sumanta; Grånäs, Oscar; Szunyogh, Laszlo Physical Review B, Vol. 84, Issue 9 https://doi.org/10.1103/PhysRevB.84.092401	journal	September 2011
Processing of alnico permanent magnets by advanced directional solidification methods Zou, Min; Johnson, Francis; Zhang, Wanming Journal of Magnetism and Magnetic Materials, Vol. 420 https://doi.org/10.1016/j.jmmm.2016.06.091	journal	December 2016
Crystal structures and magnetic properties of Fe1.93-Co P1-Si compounds Bao, L. L.; Yibole, H.; Xu, J. Y. Journal of Alloys and Compounds, Vol. 903 https://doi.org/10.1016/j.jallcom.2022.163770	journal	May 2022
High pressure X-ray diffraction study of all Fe–Sn intermetallic compounds and one Fe–Sn solid solution Giefers, Hubertus; Nicol, Malcolm Journal of Alloys and Compounds, Vol. 422, Issue 1-2 https://doi.org/10.1016/j.jallcom.2005.11.061	journal	September 2006
Magnetic properties of core–shell type nanoparticles Kita, Eiji; Shibata, K.; Yanagihara, H. Journal of Magnetism and Magnetic Materials, Vol. 310, Issue 2, p. 2411-2413 https://doi.org/10.1016/j.jmmm.2006.10.1009	journal	March 2007
Discovery and Implications of Hidden Atomic-Scale Structure in a Metallic Meteorite Kovács, András; Lewis, Laura H.; Palanisamy, Dhanalaksmi Nano Letters, Vol. 21, Issue 19 https://doi.org/10.1021/acs.nanolett.1c02573	journal	September 2021
Nanospheres of Silica with an ε-Fe ₂ O ₃ Single Crystal Nucleus Taboada, Elena; Gich, Martí; Roig, Anna ACS Nano, Vol. 3, Issue 11 https://doi.org/10.1021/nn901022s	journal	October 2009
Controlling the properties of high energy density permanent magnetic materials by different processing routes Gutfleisch, O. Journal of Physics D: Applied Physics, Vol. 33, Issue 17 https://doi.org/10.1088/0022-3727/33/17/201	journal	August 2000
Exchange-coupled nanocomposite magnets by nanoparticle self-assembly Zeng, Hao; Li, Jing; Liu, J. P. Nature, Vol. 420, Issue 6914, p. 395-398 https://doi.org/10.1038/nature01208	journal	November 2002
Giant magnetostriction in an ordered Fe3Pt single crystal exhibiting a martensitic transformation Kakeshita, Tomoyuki; Takeuchi, Tetsuya; Fukuda, Takashi Applied Physics Letters, Vol. 77, Issue 10 https://doi.org/10.1063/1.1290694	journal	September 2000
ε-Fe ₂ O ₃ : An Advanced Nanomaterial Exhibiting Giant Coercive Field, Millimeter-Wave Ferromagnetic Resonance, and Magnetoelectric Coupling Tuček, Jiří; Zbořil, Radek; Namai, Asuka Chemistry of Materials, Vol. 22, Issue 24 https://doi.org/10.1021/cm101967h	journal	December 2010
Accelerating the discovery of novel magnetic materials using machine learning–guided adaptive feedback Xia, Weiyi; Sakurai, Masahiro; Balasubramanian, Balamurugan Proceedings of the National Academy of Sciences, Vol. 119, Issue 47 https://doi.org/10.1073/pnas.2204485119	journal	November 2022
Magnetic Anisotropy of Localized State in Metals Yosida, Kei; Okiji, Ayao; Chikazumi, S\=oshin Progress of Theoretical Physics, Vol. 33, Issue 4 https://doi.org/10.1143/PTP.33.559	journal	April 1965
Magnetization studies of binary and ternary alloys based on Fe 3 Si Hines, W. A.; Menotti, A. H.; Budnick, J. I. Physical Review B, Vol. 13, Issue 9 https://doi.org/10.1103/PhysRevB.13.4060	journal	May 1976
Structural and magnetic properties of hexagonal Fe3Sn prepared by non-equilibrium techniques Echevarria-Bonet, C.; Iglesias, N.; Garitaonandia, J. S. Journal of Alloys and Compounds, Vol. 769 https://doi.org/10.1016/j.jallcom.2018.07.257	journal	November 2018
Iron carbide nanoplatelets: colloidal synthesis and characterization Abel, Frank M.; Pourmiri, Shirin; Basina, Georgia Nanoscale Advances, Vol. 1, Issue 11 https://doi.org/10.1039/C9NA00526A	journal	January 2019
Giant Magnetic Anisotropy in Tetragonal FeCo Alloys Burkert, Till; Nordström, Lars; Eriksson, Olle Physical Review Letters, Vol. 93, Issue 2 https://doi.org/10.1103/PhysRevLett.93.027203	journal	July 2004
Prospect and status of iron-based rare-earth-free permanent magnetic materials Li, Da; Li, Yong; Pan, Desheng Journal of Magnetism and Magnetic Materials, Vol. 469 https://doi.org/10.1016/j.jmmm.2018.09.032	journal	January 2019
Perpendicular magnetic anisotropy in bulk and thin-film CuMnAs for antiferromagnetic memory applications Zhuravlev, I. A.; Adhikari, A.; Belashchenko, K. D. Applied Physics Letters, Vol. 113, Issue 16 https://doi.org/10.1063/1.5048207	journal	October 2018
Carbon Nanocapsule-Mediated Formation of Ferromagnetic Fe₅Si₃ Nanoparticles Kolel-Veetil, Manoj K.; Qadri, Syed B.; Osofsky, Michael The Journal of Physical Chemistry C, Vol. 113, Issue 33 https://doi.org/10.1021/jp904188f	journal	July 2009
Intrinsic Magnetic Properties of a Highly Anisotropic Rare‐Earth‐Free Fe ₂ P‐Based Magnet He, Yangkun; Adler, Peter; Schneider, Sebastian Advanced Functional Materials, Vol. 32, Issue 4 https://doi.org/10.1002/adfm.202107513	journal	October 2021
Electronic structure and magnetic properties of L 1 0 binary alloys Edström, Alexander; Chico, Jonathan; Jakobsson, Adam Physical Review B, Vol. 90, Issue 1 https://doi.org/10.1103/PhysRevB.90.014402	journal	July 2014
Magnetocrystalline anisotropy study of Co-substituted M-type strontium hexaferrite single crystals Liu, Ruoshui; Wang, Lichen; Yu, Xiang Ceramics International, Vol. 49, Issue 2 https://doi.org/10.1016/j.ceramint.2022.09.153	journal	January 2023
Giant magnetic moment and other magnetic properties of epitaxially grown Fe₁₆N₂ single‐crystal films (invited) Sugita, Y.; Mitsuoka, K.; Komuro, M. Journal of Applied Physics, Vol. 70, Issue 10, p. 5977-5982 https://doi.org/10.1063/1.350067	journal	November 1991
Giant Coercive Field of Nanometer- Sized Iron Oxide Jin, J.; Ohkoshi, S.; Hashimoto, K. Advanced Materials, Vol. 16, Issue 1 https://doi.org/10.1002/adma.200305297	journal	January 2004
Hexagonal Iron-Oxide Compounds as Permanent-Magnet Materials Went, J. J.; Rathenau, G. W.; Gorter, E. W. Physical Review, Vol. 86, Issue 3 https://doi.org/10.1103/PhysRev.86.424.2	journal	May 1952
Large Coercive Field of 45 kOe in a Magnetic Film Based on Metal-Substituted ε-Iron Oxide Ohkoshi, Shin-ichi; Imoto, Kenta; Namai, Asuka Journal of the American Chemical Society, Vol. 139, Issue 38 https://doi.org/10.1021/jacs.7b07087	journal	September 2017
ThMn12-type structure and uniaxial magnetic anisotropy in ZrFe10Si2 and Zr1−Ce Fe10Si2 alloys Gabay, A. M.; Hadjipanayis, G. C. Journal of Alloys and Compounds, Vol. 657 https://doi.org/10.1016/j.jallcom.2015.10.073	journal	February 2016
Band structure theory of magnetism in 3d-4f compounds Richter, Manuel Journal of Physics D: Applied Physics, Vol. 31, Issue 9 https://doi.org/10.1088/0022-3727/31/9/002	journal	May 1998
Tight-binding approach to the orbital magnetic moment and magnetocrystalline anisotropy of transition-metal monolayers Bruno, Patrick Physical Review B, Vol. 39, Issue 1, p. 865-868 https://doi.org/10.1103/PhysRevB.39.865	journal	January 1989
First-principles calculation of the magnetocrystalline anisotropy energy of iron, cobalt, and nickel Daalderop, G. H. O.; Kelly, P. J.; Schuurmans, M. F. H. Physical Review B, Vol. 41, Issue 17 https://doi.org/10.1103/PhysRevB.41.11919	journal	June 1990
New Magnetic Material Having Ultrahigh Magnetic Moment Kim, T. K.; Takahashi, M. Applied Physics Letters, Vol. 20, Issue 12, p. 492-494 https://doi.org/10.1063/1.1654030	journal	June 1972
Database of novel magnetic materials for high-performance permanent magnet development Nieves, P.; Arapan, S.; Maudes-Raedo, J. Computational Materials Science, Vol. 168 https://doi.org/10.1016/j.commatsci.2019.06.007	journal	October 2019
Magnetism of α′-FeN alloys and α″-(Fe₁₆N₂) Fe nitrides Huang, M. Q.; Wallace, W. E.; Simizu, S. Journal of Magnetism and Magnetic Materials, Vol. 135, Issue 2, p. 226-230 https://doi.org/10.1016/0304-8853(94)90350-6	journal	July 1994
Extraordinary Magnetic Hardening in Nanowire Assemblies: the Geometry and Proximity Effects Mohapatra, Jeotikanta; Xing, Meiying; Elkins, Jacob Advanced Functional Materials, Vol. 31, Issue 13 https://doi.org/10.1002/adfm.202010157	journal	January 2021
Cooling of Permanent Magnet Alloys in a Constant Magnetic Field Oliver, D. A.; Shedden, J. W. Nature, Vol. 142, Issue 3587 https://doi.org/10.1038/142209a0	journal	July 1938
Simulation of alnico coercivity Ke, Liqin; Skomski, Ralph; Hoffmann, Todd D. Applied Physics Letters, Vol. 111, Issue 2 https://doi.org/10.1063/1.4992787	journal	July 2017
Anomalous structural transformation and magnetism of Fe–Ga alloys Matsushita, Masafumi; Matsushima, Yasushi; Ono, Fumihisa Physica B: Condensed Matter, Vol. 405, Issue 4 https://doi.org/10.1016/j.physb.2009.11.026	journal	February 2010
The paramagnetic properties of the monoborides of V, Cr, Mn, Fe, Co and Ni Lundquist, N.; Myers, H. P.; Westin, R. Philosophical Magazine, Vol. 7, Issue 79 https://doi.org/10.1080/14786436208209119	journal	July 1962
Magnetic and structural properties of ultrathin epitaxial Fe3Si films on GaAs(001) Herfort, J.; Schönherr, H. -P.; Jenichen, B. Journal of Applied Physics, Vol. 103, Issue 7 https://doi.org/10.1063/1.2831333	journal	April 2008
Size-Dependent Phase Map and Phase Transformation Kinetics for Nanometric Iron(III) Oxides (γ → ε → α Pathway) Lee, Seungyeol; Xu, Huifang The Journal of Physical Chemistry C, Vol. 120, Issue 24 https://doi.org/10.1021/acs.jpcc.6b05287	journal	June 2016
Structure and magnetic properties of Fe1.95-Ni P1-Si alloys Xu, J. Y.; Yibole, H. Solid State Communications, Vol. 319 https://doi.org/10.1016/j.ssc.2020.113996	journal	October 2020
Creating, probing and confirming tetragonality in bulk FeNi alloys Maât, N.; McDonald, I.; Barua, R. Acta Materialia, Vol. 196 https://doi.org/10.1016/j.actamat.2020.07.019	journal	September 2020
Magnetic Materials and Devices for the 21st Century: Stronger, Lighter, and More Energy Efficient Gutfleisch, Oliver; Willard, Matthew A.; Brück, Ekkes Advanced Materials, Vol. 23, Issue 7 https://doi.org/10.1002/adma.201002180	journal	December 2010
Phase Separation by Spinodal Decomposition in Isotropic Systems Cahn, John W. The Journal of Chemical Physics, Vol. 42, Issue 1 https://doi.org/10.1063/1.1695731	journal	January 1965
Hard magnetic ferrite with a gigantic coercivity and high frequency millimetre wave rotation Namai, Asuka; Yoshikiyo, Marie; Yamada, Kana Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms2038	journal	January 2012
State-tracking first-principles determination of magnetocrystalline anisotropy Wang, Ding-sheng; Wu, Ruqian; Freeman, A. J. Physical Review Letters, Vol. 70, Issue 6 https://doi.org/10.1103/PhysRevLett.70.869	journal	February 1993
Magnetic properties of α′-FeNx and α″-Fe16N2 nitrides Bezdička, Petr; Kláriková, Adriana; Paseka, Ivo Journal of Alloys and Compounds, Vol. 274, Issue 1-2 https://doi.org/10.1016/S0925-8388(98)00525-8	journal	June 1998
Magnetocrystalline anisotropy of (Fe1−xCox)3P Broddefalk, A.; Granberg, P.; Nordblad, P. Journal of Applied Physics, Vol. 83, Issue 11 https://doi.org/10.1063/1.367851	journal	June 1998
The history of permanent-magnet materials Livingston, J. D. JOM, Vol. 42, Issue 2 https://doi.org/10.1007/BF03220870	journal	February 1990
Magnetocrystalline anisotropy of Fe3B, Fe2B and Fe1.4Co0.6B as studied by Lorentz electron microscopy, singular point detection and magnetization measurements Coene, W.; Hakkens, F.; Coehoorn, R. Journal of Magnetism and Magnetic Materials, Vol. 96, Issue 1-3 https://doi.org/10.1016/0304-8853(91)90627-M	journal	June 1991
Machine learning for molecular and materials science Butler, Keith T.; Davies, Daniel W.; Cartwright, Hugh Nature, Vol. 559, Issue 7715 https://doi.org/10.1038/s41586-018-0337-2	journal	July 2018
Magnetocrystalline anisotropy of La- and Co-substituted M -type strontium ferrites: Role of Co 2 + and Fe 2 + Ueda, Hiroaki; Tanioku, Yasuaki; Michioka, Chishiro Physical Review B, Vol. 95, Issue 22 https://doi.org/10.1103/PhysRevB.95.224421	journal	June 2017
First-principles prediction of enhanced magnetic anisotropy in FeCo alloys Wu, Dangxin; Zhang, Qiming; Liu, J. Ping Applied Physics Letters, Vol. 92, Issue 5 https://doi.org/10.1063/1.2840721	journal	February 2008
Magnetocrystalline Anisotropy in (Fe _{1- x} Co _x ) ₂ B System Iga, Atsushi Japanese Journal of Applied Physics, Vol. 9, Issue 4 https://doi.org/10.1143/JJAP.9.415	journal	April 1970
Anisotropy of W in Fe and Co Kashyap, A.; Manchanda, P.; Sahota, P. K. IEEE Transactions on Magnetics, Vol. 47, Issue 10 https://doi.org/10.1109/TMAG.2011.2157317	journal	October 2011
Permanent magnets: Plugging the gap Coey, J. M. D. Scripta Materialia, Vol. 67, Issue 6 https://doi.org/10.1016/j.scriptamat.2012.04.036	journal	September 2012
Flux growth of magnetoplumbite-type strontium ferrite single crystals with La–Co co-substitution Shimoda, A.; Takao, K.; Uji, K. Journal of Solid State Chemistry, Vol. 239 https://doi.org/10.1016/j.jssc.2016.04.031	journal	July 2016
An Improved Permeameter for Testing Magnet Steel Babbitt, B. J. Journal of the Optical Society of America, Vol. 17, Issue 1 https://doi.org/10.1364/JOSA.17.000047	journal	July 1928
The Magnetic Properties of Iron Selenide Single Crystals Hirakawa, Kinshiro Journal of the Physical Society of Japan, Vol. 12, Issue 8 https://doi.org/10.1143/JPSJ.12.929	journal	August 1957
Iron magnetic moments and spin-density asphericity inFe3(AlxSi1−x) alloys Dobrzynski, L.; Petrillo, C.; Sacchetti, F. Physical Review B, Vol. 42, Issue 2 https://doi.org/10.1103/PhysRevB.42.1142	journal	July 1990
Magnetic properties of hexagonal and cubic Fe ₃ Ge Drijver, J. W.; Sinnema, S. G.; Woude, F. van der Journal of Physics F: Metal Physics, Vol. 6, Issue 11 https://doi.org/10.1088/0305-4608/6/11/015	journal	November 1976
Hard Magnetic Materials: A Perspective Coey, J. M. D. IEEE Transactions on Magnetics, Vol. 47, Issue 12 https://doi.org/10.1109/TMAG.2011.2166975	journal	December 2011
On the potential of hard ferrite ceramics for permanent magnet technology—a review on sintering strategies Granados-Miralles, Cecilia; Jenuš, Petra Journal of Physics D: Applied Physics, Vol. 54, Issue 30 https://doi.org/10.1088/1361-6463/abfad4	journal	May 2021
The occurrence and the crystal structure of α" -iron nitride; a new type of interstitial alloy formed during the tempering of nitrogen-martensite Jack, Kenneth Henderson Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 208, Issue 1093, p. 216-224 https://doi.org/10.1098/rspa.1951.0155	journal	August 1951
Direct Formation of Hard‐Magnetic Tetrataenite in Bulk Alloy Castings Ivanov, Yurii P.; Sarac, Baran; Ketov, Sergey V. Advanced Science, Vol. 10, Issue 1 https://doi.org/10.1002/advs.202204315	journal	October 2022
Origin of Brown's coercive paradox in perfect ferromagnetic crystals Hartmann, U. Physical Review B, Vol. 36, Issue 4 https://doi.org/10.1103/PhysRevB.36.2331	journal	August 1987
Magnetic anisotropy and coercivity of Fe₃Se₄ nanostructures Long, Gen; Zhang, Hongwang; Li, Da Applied Physics Letters, Vol. 99, Issue 20 https://doi.org/10.1063/1.3662388	journal	November 2011
Rare-earth-free magnetically hard ferrous materials Shao, Zefan; Ren, Shenqiang Nanoscale Advances, Vol. 2, Issue 10 https://doi.org/10.1039/D0NA00519C	journal	January 2020
New Determination of Magnetic Anisotropy Constants of Alnico Magnet Alloys Iwama, Y.; Takeuchi, M.; Iwata, M. Le Journal de Physique Colloques, Vol. 32, Issue C1 https://doi.org/10.1051/jphyscol:19711189	journal	February 1971
Semihard Iron-Based Permanent-Magnet Materials Yin, Li; Juneja, Rinkle; Lindsay, Lucas Physical Review Applied, Vol. 15, Issue 2 https://doi.org/10.1103/PhysRevApplied.15.024012	journal	February 2021
Coercivity limits in nanoscale ferromagnets Mohapatra, Jeotikanta; Fischbacher, J.; Gusenbauer, M. Physical Review B, Vol. 105, Issue 21 https://doi.org/10.1103/PhysRevB.105.214431	journal	June 2022
Perpendicular Magnetic Anisotropy Induced by Tetragonal Distortion of FeCo Alloy Films Grown on Pd(001) Winkelmann, Aimo; Przybylski, Marek; Luo, Feng Physical Review Letters, Vol. 96, Issue 25 https://doi.org/10.1103/PhysRevLett.96.257205	journal	June 2006
Magnetic Properties of Intermetallic Compounds in Manganese-Tin System: Mn_3.67Sn, Mn_1.77Sn, and MnSn₂ Yasukōchi, Kō; Kanematsu, Kazuo; Ohoyama, Tetuo Journal of the Physical Society of Japan, Vol. 16, Issue 6 https://doi.org/10.1143/JPSJ.16.1123	journal	June 1961
Initial permeabilities of sintered ferrites Rathenau, G. W.; Fast, J. F. Physica, Vol. 21, Issue 6-10 https://doi.org/10.1016/S0031-8914(55)93127-X	journal	January 1955
Tuning the magnetocrystalline anisotropy of Fe 3 Sn by alloying Vekilova, Olga Yu.; Fayyazi, Bahar; Skokov, Konstantin P. Physical Review B, Vol. 99, Issue 2 https://doi.org/10.1103/PhysRevB.99.024421	journal	January 2019
Magnetic properties of ( Fe 1 − x Co x ) 2 B alloys and the effect of doping by 5 d elements Edström, A.; Werwiński, M.; Iuşan, D. Physical Review B, Vol. 92, Issue 17 https://doi.org/10.1103/PhysRevB.92.174413	journal	November 2015
Structure and magnetism of new rare-earth-free intermetallic compounds: Fe _3+x Co _3−x Ti ₂ (0 ≤ x ≤ 3) Balasubramanian, Balamurugan; Das, Bhaskar; Nguyen, Manh Cuong APL Materials, Vol. 4, Issue 11 https://doi.org/10.1063/1.4968517	journal	November 2016
Mechanism of Uniaxial Magnetocrystalline Anisotropy in Transition Metal Alloys Kota, Yohei; Sakuma, Akimasa Journal of the Physical Society of Japan, Vol. 83, Issue 3 https://doi.org/10.7566/JPSJ.83.034715	journal	March 2014
Ferromagnetism in Hexagonal and Cubic Fe₂Hf Compounds Ikeda, Köki International Journal of Materials Research, Vol. 68, Issue 3 https://doi.org/10.1515/ijmr-1977-680305	journal	March 1977
Effective uniaxial anisotropy in easy-plane materials through nanostructuring Fischbacher, J.; Kovacs, A.; Oezelt, H. Applied Physics Letters, Vol. 111, Issue 19 https://doi.org/10.1063/1.4997816	journal	November 2017
Preparation, crystallization process and magnetic property of Fe(Co, Ni)ZrB alloy powders Hua, Zhong; Yu, Wanqiu; Sun, Yaming Journal of Alloys and Compounds, Vol. 505, Issue 2 https://doi.org/10.1016/j.jallcom.2010.06.138	journal	September 2010
(Fe,Co)2(P,Si) rare-earth free permanent magnets: From macroscopic single crystals to submicron-sized particles Yibole, H.; Lingling-Bao, B.; Xu, J. Y. Acta Materialia, Vol. 221 https://doi.org/10.1016/j.actamat.2021.117388	journal	December 2021
Ferromagnetism of Fe3Sn and Alloys Sales, Brian C.; Saparov, Bayrammurad; McGuire, Michael A. Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep07024	journal	November 2014
Fe ₃ Se ₄ Nanostructures with Giant Coercivity Synthesized by Solution Chemistry Zhang, Hongwang; Long, Gen; Li, Da Chemistry of Materials, Vol. 23, Issue 16 https://doi.org/10.1021/cm201610k	journal	July 2011
Reinvestigation of the intrinsic magnetic properties of ( Fe 1 - x Co x ) 2 B alloys and crystallization behavior of ribbons Lamichhane, Tej Nath; Palasyuk, Olena; Antropov, Vladimir P. Journal of Magnetism and Magnetic Materials, Vol. 513 https://doi.org/10.1016/j.jmmm.2020.167214	journal	November 2020
Magnetic anisotropies of La–Co substituted M-type Sr hexaferrites studied by ⁵⁷Fe Mössbauer spectroscopy with external magnetic fields Nagasawa, Nobumoto; Oura, Momoko; Ikeda, Shugo Journal of Applied Physics, Vol. 128, Issue 13 https://doi.org/10.1063/5.0019954	journal	October 2020
Crystal structure and magnetic properties of new Fe ₃ Co ₃ X ₂ ( X = Ti, Nb) intermetallic compounds Zhang, Jie; Nguyen, Manh Cuong; Balasubramanian, Balamurugan Journal of Physics D: Applied Physics, Vol. 49, Issue 17 https://doi.org/10.1088/0022-3727/49/17/175002	journal	March 2016
Structure, magnetism, and magnetostrictive properties of mechanically alloyed Fe81Ga19 Taheri, P.; Barua, R.; Hsu, J. Journal of Alloys and Compounds, Vol. 661 https://doi.org/10.1016/j.jallcom.2015.11.037	journal	March 2016
A Mössbauer and X-ray study of Fe2P1−xBx compounds (x < 0.15) Chandra, R.; Bjarman, S.; Ericsson, T. Journal of Solid State Chemistry, Vol. 34, Issue 3 https://doi.org/10.1016/0022-4596(80)90440-5	journal	October 1980
Room Temperature Ferromagnetism in Single-Crystalline Fe ₅ Si ₃ Nanowires Seo, Kwanyong; Lee, Sunghun; Jo, Younghun The Journal of Physical Chemistry C, Vol. 113, Issue 17 https://doi.org/10.1021/jp902010j	journal	April 2009
Stabilization of the tetragonal distortion of Fe x Co 1 − x alloys by C impurities: A potential new permanent magnet Delczeg-Czirjak, E. K.; Edström, A.; Werwiński, M. Physical Review B, Vol. 89, Issue 14 https://doi.org/10.1103/PhysRevB.89.144403	journal	April 2014
Combinatorial exploration of rare-earth-free permanent magnets: Magnetic and microstructural properties of Fe-Co-W thin films Gao, T. R.; Wu, Y. Q.; Fackler, S. Applied Physics Letters, Vol. 102, Issue 2 https://doi.org/10.1063/1.4775581	journal	January 2013
The synthesis and characterization of bulk α″-Fe16N2 Jack, K. H. Journal of Alloys and Compounds, Vol. 222, Issue 1-2 https://doi.org/10.1016/0925-8388(94)04901-7	journal	May 1995
Iron Carbide Nanostructures: An Emerging Material for Tumor Theranostics Wang, Jingjing; Hou, Yanglong Accounts of Materials Research, Vol. 3, Issue 1 https://doi.org/10.1021/accountsmr.0c00018	journal	November 2021
Experimental and computational analysis of binary Fe-Sn ferromagnetic compounds Fayyazi, Bahar; Skokov, Konstantin P.; Faske, Tom Acta Materialia, Vol. 180 https://doi.org/10.1016/j.actamat.2019.08.054	journal	November 2019
Room temperature magnetic anisotropy in Fe2P-type transition metal based alloys Guillou, F.; Haschuluu, O. Journal of Alloys and Compounds, Vol. 800, p. 403-411 https://doi.org/10.1016/j.jallcom.2019.05.327	journal	May 2019
L1₀ FeNi: a promising material for next generation permanent magnets Mandal, Shuvam; Debata, Mayadhar; Sengupta, Pradyut Critical Reviews in Solid State and Materials Sciences https://doi.org/10.1080/10408436.2022.2107484	journal	August 2022
Tuning magnetocrystalline anisotropy of α″-Fe 16 N 2 by interstitial impurity doping: A first principles study Khan, Imran; Hong, Jisang Journal of Magnetism and Magnetic Materials, Vol. 433 https://doi.org/10.1016/j.jmmm.2017.02.041	journal	July 2017
Second-Order Perturbation Formula for Magnetocrystalline Anisotropy Using Orbital Angular Momentum Matrix Kosugi, Taichi; Miyake, Takashi; Ishibashi, Shoji Journal of the Physical Society of Japan, Vol. 83, Issue 4 https://doi.org/10.7566/JPSJ.83.044707	journal	April 2014
Fe-Cr-Co ductile magnet with (BH)max?8 MGOe Kaneko, H.; Homma, M.; Okada, M. AIP Conference Proceedings Vol. 29 https://doi.org/10.1063/1.30486	conference	January 1976
Crossover in magnetic properties of FeSi Sluchanko, N. E.; Glushkov, V. V.; Demishev, S. V. Physical Review B, Vol. 65, Issue 6 https://doi.org/10.1103/PhysRevB.65.064404	journal	January 2002
The Magnetic Properties of FeSe _x with the NiAs Structure Hirone, Tokutaro; Chiba, Shu Journal of the Physical Society of Japan, Vol. 11, Issue 6 https://doi.org/10.1143/JPSJ.11.666	journal	June 1956
Particle size effects on magnetic properties of BaFe₁₂₋₂_xTi_xCo_xO₁₉fine particles Kubo, O.; Ido, T.; Yokoyama, H. Journal of Applied Physics, Vol. 57, Issue 8 https://doi.org/10.1063/1.334585	journal	April 1985
Exchange bias and Verwey transition in Fe₅C₂/Fe₃O₄ core/shell nanoparticles Xing, M.; Mohapatra, Jeotikanta; Elkins, J. Nanoscale, Vol. 13, Issue 37 https://doi.org/10.1039/D1NR04520B	journal	January 2021
Hard and semi-hard magnetic materials based on cobalt and cobalt alloys Mohapatra, Jeotikanta; Xing, Meiying; Elkins, Jacob Journal of Alloys and Compounds, Vol. 824 https://doi.org/10.1016/j.jallcom.2020.153874	journal	May 2020
Recent Developments in High‐Energy Alnico Alloys Cronk, Edward R. Journal of Applied Physics, Vol. 37, Issue 3 https://doi.org/10.1063/1.1708350	journal	March 1966
Magnetic properties of hard magnetic (Fe,Cr)₃Sn₂intermetallic compound Goll, D.; Loeffler, R.; Herbst, J. physica status solidi (RRL) - Rapid Research Letters, Vol. 9, Issue 10 https://doi.org/10.1002/pssr.201510243	journal	September 2015
Properties of magnetically semi-hard (FexCo1−x)3B compounds Pal, S. K.; Skokov, K. P.; Groeb, T. Journal of Alloys and Compounds, Vol. 696 https://doi.org/10.1016/j.jallcom.2016.11.226	journal	March 2017
Criterion for Uniform Micromagnetization Brown, William Fuller Physical Review, Vol. 105, Issue 5 https://doi.org/10.1103/PhysRev.105.1479	journal	March 1957
Cobalt magnet steel Brace, P. H. Electrical Engineering, Vol. 51, Issue 2 https://doi.org/10.1109/EE.1932.6429690	journal	February 1932
High-throughput and data-mining approach to predict new rare-earth free permanent magnets Vishina, Alena; Vekilova, Olga Yu.; Björkman, Torbjörn Physical Review B, Vol. 101, Issue 9 https://doi.org/10.1103/PhysRevB.101.094407	journal	March 2020
Analysis of optical and magnetooptical spectra of Fe5Si3 and Fe3Si magnetic silicides using spectral magnetoellipsometry Lyashchenko, S. A.; Popov, Z. I.; Varnakov, S. N. Journal of Experimental and Theoretical Physics, Vol. 120, Issue 5 https://doi.org/10.1134/S1063776115050155	journal	May 2015
Influence of Ligand States on the Relationship between Orbital Moment and Magnetocrystalline Anisotropy Andersson, C.; Sanyal, B.; Eriksson, O. Physical Review Letters, Vol. 99, Issue 17 https://doi.org/10.1103/PhysRevLett.99.177207	journal	October 2007
Anisotropic characteristics and improved magnetic performance of Ca–La–Co-substituted strontium hexaferrite nanomagnets Lee, Jimin; Lee, Eun Jae; Hwang, Tae-Yeon Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-72608-0	journal	September 2020
Magnetic anisotropy in low-dimensional ferromagnetic systems: Fe monolayers on Ag(001), Au(001), and Pd(001) substrates Li, Chun; Freeman, A. J.; Jansen, H. J. F. Physical Review B, Vol. 42, Issue 9 https://doi.org/10.1103/PhysRevB.42.5433	journal	September 1990
Magnetic and crystallographic properties of the system Fe2P1−xAsx Catalano, A.; Arnott, R. J.; Wold, A. Journal of Solid State Chemistry, Vol. 7, Issue 3 https://doi.org/10.1016/0022-4596(73)90132-1	journal	July 1973
Architecture and magnetism of alnico Zhou, Lin; Miller, M. K.; Lu, Ping Acta Materialia, Vol. 74 https://doi.org/10.1016/j.actamat.2014.04.044	journal	August 2014
Single crystal synthesis and magnetic properties of Co2+-substituted and non-substituted magnetoplumbite-type Na–La ferrite Waki, Takeshi; Takao, Kenta; Tabata, Yoshikazu Journal of Solid State Chemistry, Vol. 282 https://doi.org/10.1016/j.jssc.2019.121071	journal	February 2020
Magnetic moment of α″‐Fe₁₆N₂ films (invited) Takahashi, Migaku; Shoji, H.; Takahashi, H. Journal of Applied Physics, Vol. 76, Issue 10, p. 6642-6647 https://doi.org/10.1063/1.358431	journal	November 1994
Magnetic hardening and coercivity mechanisms in L1₀ ordered FePd ferromagnets Klemmer, T.; Hoydick, D.; Okumura, H. Scripta Metallurgica et Materialia, Vol. 33, Issue 10-11, p. 1793-1805 https://doi.org/10.1016/0956-716X(95)00413-P	journal	December 1995
Structural Study of Iron Selenides FeSe _x . I Ordered Arrangement of Defects of Fe Atoms Okazaki, Atsushi; Hirakawa, Kinshiro Journal of the Physical Society of Japan, Vol. 11, Issue 9 https://doi.org/10.1143/JPSJ.11.930	journal	September 1956
Magnetic properties of Fe ₃ Sn ₂ . II. Neutron diffraction study (and Mossbauer effect) Malaman, B.; Fruchart, D.; Caer, G. Le Journal of Physics F: Metal Physics, Vol. 8, Issue 11 https://doi.org/10.1088/0305-4608/8/11/022	journal	November 1978
Magnetization reversal and coercivity of Fe₃Se₄ nanowire arrays Li, D.; Li, S. J.; Zhou, Y. T. Journal of Applied Physics, Vol. 117, Issue 17 https://doi.org/10.1063/1.4908297	journal	May 2015
Magnetic Aging of Spinodal Alloys Cahn, John W. Journal of Applied Physics, Vol. 34, Issue 12 https://doi.org/10.1063/1.1729261	journal	December 1963
Magnetic Properties of ZrFe2 and TiFe2 within Their Homogeneity Range Brückner, W.; Perthel, R.; Kleinstück, K. Physica Status Solidi (b), Vol. 29, Issue 1 https://doi.org/10.1002/pssb.19680290124	journal	January 1968
Phase-Controlled Growth of Metastable Fe ₅ Si ₃ Nanowires by a Vapor Transport Method Varadwaj, Kumar S. K.; Seo, Kwanyong; In, Juneho Journal of the American Chemical Society, Vol. 129, Issue 27 https://doi.org/10.1021/ja071439v	journal	July 2007
Annealing effect on microstructure and magnetic properties of nanocrystalline Zr6Fe23 compound Fersi, R.; Dalia, A. P. Journal of Magnetism and Magnetic Materials, Vol. 560 https://doi.org/10.1016/j.jmmm.2022.169650	journal	October 2022
Crystallographic and Magnetic Properties of Solid Solutions of the Phosphides M ₂ P, M = Cr, Mn, Fe, Co, and Ni Fruchart, R.; Roger, A.; Senateur, J. P. Journal of Applied Physics, Vol. 40, Issue 3 https://doi.org/10.1063/1.1657617	journal	March 1969
On K. S. Magnet Steel Honda, Kôtarô; Saitô, Shôzô Physical Review, Vol. 16, Issue 6 https://doi.org/10.1103/PhysRev.16.495	journal	December 1920