Automated reaction kinetics and network exploration (Arkane): A statistical mechanics, thermodynamics, transition state theory, and master equation software

Dana, Alon Grinberg; Johnson, Matthew S.; Allen, Joshua W.; Sharma, Sandeep; Raman, Sumathy; Liu, Mengjie; Gao, Connie W.; Grambow, Colin A.; Goldman, Mark J.; Ranasinghe, Duminda S.; Gillis, Ryan J.; Payne, A. Mark; Li, Yi‐Pei; Dong, Xiaorui; Spiekermann, Kevin A.; Wu, Haoyang; Dames, Enoch E.; Buras, Zachary J.; Vandewiele, Nick M.; Yee, Nathan W.; Merchant, Shamel S.; Buesser, Beat; Class, Caleb A.; Goldsmith, Franklin; West, Richard H.; Green, William H.

doi:10.1002/kin.21637

Title: Automated reaction kinetics and network exploration (Arkane): A statistical mechanics, thermodynamics, transition state theory, and master equation software

Journal Article · 02 April 2023 · International Journal of Chemical Kinetics

DOI: https://doi.org/10.1002/kin.21637 · OSTI ID:1968115

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^[2]; Dames, Enoch E. ^[2];

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Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Technion-Israel Institute of Technology, Haifa (Israel)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Univ. of Colorado, Boulder, CO (United States)
National Taiwan Univ., Taipei (Taiwan)
Brown Univ., Providence, RI (United States)
Northeastern Univ., Boston, MA (United States)

The open-source statistical mechanics software described here, Arkane–Automated Reaction Kinetics and Network Exploration–facilitates computations of thermodynamic properties of chemical species, high-pressure limit reaction rate coefficients, and pressure-dependent rate coefficient over multi-well molecular potential energy surfaces (PES) including the effects of collisional energy transfer on phenomenological kinetics. Arkane can use estimates to fill in information for molecules or reactions where quantum chemistry information is missing. The software solves the internal energy master equation for complex unimolecular reaction systems. Inputs to the software include converged electronic structure computations performed by the user using a variety of supported software packages (Gaussian, Molpro, Orca, TeraChem, Q-Chem, Psi4). The software outputs high-pressure limit rate coefficients and pressure-dependent phenomenological rate coefficients, as well as computed thermodynamic properties (enthalpy, entropy, and constant pressure heat capacity) with added energy corrections. Some of the key features of Arkane include treatment of 1D, 2D or ND hindered internal rotation modes, treatment of free internal rotation modes, quantum tunneling effect consideration, transition state theory (TST) and Rice-Ramsperger-Kassel-Marcus (RRKM) rate coefficient computations, master equation solution with four implemented methods, inverse-Laplace transform of high-pressure limit rate coefficients into the energy domain, energy corrections based on bond-additivity or isodesmic reactions, automated and efficient PES exploration, and PES sensitivity analysis. The present work describes the design of Arkane, how it should be used, and refers to the theory that it employs. Arkane is distributed via the RMG-Py software suite (https://github.com/ReactionMechanismGenerator/RMG-Py).

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Research Organization:: Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: SC0014901

OSTI ID:: 1968115

Journal Information:: International Journal of Chemical Kinetics, Journal Name: International Journal of Chemical Kinetics Journal Issue: 6 Vol. 55; ISSN 0538-8066

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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