X-ray Absorption Spectroscopy Studies of a Molecular CO2-Reduction Catalyst Deposited on Graphitic Carbon Nitride

Li, Junying; Huang, Peipei; Guo, Facheng; Huang, Jiahao; Xiang, Shuting; Yang, Ke; Deskins, N. Aaron; Batista, Victor S.; Li, Gonghu; Frenkel, Anatoly I.

doi:10.1021/acs.jpcc.2c08587

Title: X-ray Absorption Spectroscopy Studies of a Molecular CO₂-Reduction Catalyst Deposited on Graphitic Carbon Nitride

Journal Article · 09 February 2023 · Journal of Physical Chemistry. C

DOI: https://doi.org/10.1021/acs.jpcc.2c08587 · OSTI ID:1963583

Li, Junying ^[1]; Huang, Peipei ^[2]; Guo, Facheng ^[3]; Huang, Jiahao ^[1]; Xiang, Shuting ^[1];

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Stony Brook University, NY (United States)
University of New Hampshire, Durham, NH (United States)
Yale University, New Haven, CT (United States)
Worcester Polytechnic Institute, MA (United States)
Stony Brook University, NY (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Div.

Metal-ligand complexes have been extensively explored as well-defined molecular catalysts in small molecule activation reactions such as carbon dioxide (CO₂) reduction. Many hybrid photocatalysts have been prepared by coupling such complexes with photoactive surfaces for use in solar CO₂ reduction. In this work, we employ X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) spectroscopies, density functional theory (DFT) and computational XANES modeling to interrogate the structure of a hybrid photocatalyst consisting of a macrocyclic cobalt complex deposited on graphitic carbon nitride (C₃N₄). Results show that the cobalt complex binds on C₃N₄ through surface OH or NH₂ groups. By refining the local geometry and binding sites of this well-defined molecular cobalt complex on C₃N₄, here we established an important benchmark for modeling a large class of molecular catalysts that can be adapted to in situ/operando studies and further enhanced by applying chemometrics-based approaches and machine learning methods of XANES data analysis.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: SC0012704; SC0016417; FG02-07ER15909

OSTI ID:: 1963583

Report Number(s):: BNL-224186-2023-JAAM; {"","Journal ID: ISSN 1932-7447"}

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 7 Vol. 127; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (71)

X-ray absorption fine structure: characterization of thermal and structural disorder in non-crystalline solids Dalba, G.; Fornasini, P.; Grisenti, R. Journal of Non-Crystalline Solids, Vol. 345-346 https://doi.org/10.1016/j.jnoncrysol.2004.07.037	journal	October 2004
A novel Ru/TiO₂hybrid nanocomposite catalyzed photoreduction of CO₂to methanol under visible light Kumar, Pawan; Joshi, Chetan; Labhsetwar, Nitin Nanoscale, Vol. 7, Issue 37 https://doi.org/10.1039/C5NR03712C	journal	January 2015
Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure Ankudinov, A. L.; Ravel, B.; Rehr, J. J. Physical Review B, Vol. 58, Issue 12 https://doi.org/10.1103/PhysRevB.58.7565	journal	September 1998
Aliovalent Doping of CeO₂ Improves the Stability of Atomically Dispersed Pt Wang, Haodong; Kottwitz, Matthew; Rui, Ning ACS Applied Materials & Interfaces, Vol. 13, Issue 44 https://doi.org/10.1021/acsami.1c18330	journal	October 2021
Regulation of Coordination Number over Single Co Sites: Triggering the Efficient Electroreduction of CO ₂ Wang, Xiaoqian; Chen, Zhao; Zhao, Xuyan Angewandte Chemie International Edition, Vol. 57, Issue 7 https://doi.org/10.1002/anie.201712451	journal	January 2018
Energy and Climate Impacts of Producing Synthetic Hydrocarbon Fuels from CO ₂ van der Giesen, Coen; Kleijn, René; Kramer, Gert Jan Environmental Science & Technology, Vol. 48, Issue 12 https://doi.org/10.1021/es500191g	journal	May 2014
Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels Morris, Amanda J.; Meyer, Gerald J.; Fujita, Etsuko Accounts of Chemical Research, Vol. 42, Issue 12 https://doi.org/10.1021/ar9001679	journal	December 2009
Design of Single-Atom Co–N ₅ Catalytic Site: A Robust Electrocatalyst for CO ₂ Reduction with Nearly 100% CO Selectivity and Remarkable Stability Pan, Yuan; Lin, Rui; Chen, Yinjuan Journal of the American Chemical Society, Vol. 140, Issue 12 https://doi.org/10.1021/jacs.8b00814	journal	February 2018
Hybrid Artificial Photosynthetic Systems Comprising Semiconductors as Light Harvesters and Biomimetic Complexes as Molecular Cocatalysts Wen, Fuyu; Li, Can Accounts of Chemical Research, Vol. 46, Issue 11 https://doi.org/10.1021/ar300224u	journal	June 2013
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Impacts of Global Warming and Elevated CO2 on Sensory Behavior in Predator-Prey Interactions: A Review and Synthesis Draper, Alex M.; Weissburg, Marc J. Frontiers in Ecology and Evolution, Vol. 7 https://doi.org/10.3389/fevo.2019.00072	journal	March 2019
Probing Active Sites in Cu _x Pd _y Cluster Catalysts by Machine-Learning-Assisted X-ray Absorption Spectroscopy Liu, Yang; Halder, Avik; Seifert, Soenke ACS Applied Materials & Interfaces, Vol. 13, Issue 45 https://doi.org/10.1021/acsami.1c06714	journal	July 2021
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium Kresse, G.; Hafner, J. Physical Review B, Vol. 49, Issue 20, p. 14251-14269 https://doi.org/10.1103/PhysRevB.49.14251	journal	May 1994
Single Atom Catalysts: A Review of Characterization Methods Kottwitz, Matthew; Li, Yuanyuan; Wang, Haodong Chemistry–Methods, Vol. 1, Issue 6 https://doi.org/10.1002/cmtd.202100020	journal	June 2021
Probing structural relaxation in nanosized catalysts by combining EXAFS and reverse Monte Carlo methods Timoshenko, Janis; Frenkel, Anatoly I. Catalysis Today, Vol. 280 https://doi.org/10.1016/j.cattod.2016.05.049	journal	February 2017
Solving the Structure and Dynamics of Metal Nanoparticles by Combining X-Ray Absorption Fine Structure Spectroscopy and Atomistic Structure Simulations Timoshenko, J.; Duan, Z.; Henkelman, G. Annual Review of Analytical Chemistry, Vol. 12, Issue 1 https://doi.org/10.1146/annurev-anchem-061318-114929	journal	June 2019
EXAFS Studies on the Size Dependence of Structural and Dynamic Properties of CdS Nanoparticles Rockenberger, Jörg; Tröger, Larc; Kornowski, Andreas The Journal of Physical Chemistry B, Vol. 101, Issue 14 https://doi.org/10.1021/jp963266u	journal	April 1997
In-plane benzene incorporated g-C3N4 microtubes: Enhanced visible light harvesting and carrier transportation for photocatalytic CO2 reduction Wang, Wen-Feng; Zhang, Yong-Kang; Feng, Lie-Feng Fuel, Vol. 326 https://doi.org/10.1016/j.fuel.2022.125073	journal	October 2022
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Electrocatalytic and homogeneous approaches to conversion of CO ₂ to liquid fuels Benson, Eric E.; Kubiak, Clifford P.; Sathrum, Aaron J. Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B804323J	journal	January 2009
Spatially separating redox centers on 2D carbon nitride with cobalt single atom for photocatalytic H ₂ O ₂ production Chu, Chiheng; Zhu, Qianhong; Pan, Zhenhua Proceedings of the National Academy of Sciences, Vol. 117, Issue 12 https://doi.org/10.1073/pnas.1913403117	journal	March 2020
Heterogenised Molecular Catalysts for the Reduction of CO ₂ to Fuels Windle, Christopher D.; Reisner, Erwin CHIMIA International Journal for Chemistry, Vol. 69, Issue 7 https://doi.org/10.2533/chimia.2015.435	journal	August 2015
Efficient and selective electron mediation of cobalt complexes with cyclam and related macrocycles in the p-terphenyl-catalyzed photoreduction of carbon dioxide Matsuoka, Shinjiro; Yamamoto, Kiichi; Ogata, Tomoyuki Journal of the American Chemical Society, Vol. 115, Issue 2 https://doi.org/10.1021/ja00055a032	journal	January 1993
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Thermal properties and crystal structures of cobalt(III)–cyclam complexes with the bis(trifluoromethanesulfonyl)amide anion (cyclam = 1,4,8,11-tetraazacyclotetradecane) Oba, Yukiko; Mochida, Tomoyuki Polyhedron, Vol. 99 https://doi.org/10.1016/j.poly.2015.08.015	journal	October 2015
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO ₂ Fixation Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B. Chemical Reviews, Vol. 113, Issue 8 https://doi.org/10.1021/cr300463y	journal	June 2013
Catalysis by Supported Single Metal Atoms Liu, Jingyue ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b01534	journal	November 2016
Monolayer Molecular Functionalization Enabled by Acid–Base Interaction for High-Performance Photochemical CO₂ Reduction Shang, Bo; Zhao, Fengyi; Choi, Chungseok ACS Energy Letters, Vol. 7, Issue 7 https://doi.org/10.1021/acsenergylett.2c01147	journal	June 2022
The Synthesis and Crystal Structures of Two Cobalt(III) Complexes Containing the Ligand 1,4,8,11-Tetraazacyclotetradecane Funston, A. M.; McFadyen, W. D.; Tregloan, P. A. Australian Journal of Chemistry, Vol. 55, Issue 8 https://doi.org/10.1071/CH02015	journal	January 2002
Efficient Visible-Light-Driven CO ₂ Reduction by a Cobalt Molecular Catalyst Covalently Linked to Mesoporous Carbon Nitride Ma, Bing; Chen, Gui; Fave, Claire Journal of the American Chemical Society, Vol. 142, Issue 13 https://doi.org/10.1021/jacs.9b13930	journal	March 2020
Selective CO ₂ Reduction Catalyzed by Single Cobalt Sites on Carbon Nitride under Visible-Light Irradiation Huang, Peipei; Huang, Jiahao; Pantovich, Sebastian A. Journal of the American Chemical Society, Vol. 140, Issue 47 https://doi.org/10.1021/jacs.8b10380	journal	October 2018
Electrochemical Reduction of CO2: A Review of Cobalt Based Catalysts for Carbon Dioxide Conversion to Fuels Usman, Muhammad; Humayun, Muhammad; Garba, Mustapha D. Nanomaterials, Vol. 11, Issue 8 https://doi.org/10.3390/nano11082029	journal	August 2021
Revealing the Structure of Single Cobalt Sites in Carbon Nitride for Photocatalytic CO₂ Reduction Huang, Peipei; Huang, Jiahao; Li, Junying The Journal of Physical Chemistry C, Vol. 126, Issue 20 https://doi.org/10.1021/acs.jpcc.2c01216	journal	May 2022
A post-Hartree-Fock model of intermolecular interactions: Inclusion of higher-order corrections Johnson, Erin R.; Becke, Axel D. The Journal of Chemical Physics, Vol. 124, Issue 17 https://doi.org/10.1063/1.2190220	journal	May 2006
Comparative analysis of XANES and EXAFS for local structural characterization of disordered metal oxides Li, Junying; Li, Yuanyuan; Routh, Prahlad K. Journal of Synchrotron Radiation, Vol. 28, Issue 5 https://doi.org/10.1107/S1600577521007025	journal	August 2021
Visible-Light-Driven CO ₂ Reduction with Carbon Nitride: Enhancing the Activity of Ruthenium Catalysts Kuriki, Ryo; Sekizawa, Keita; Ishitani, Osamu Angewandte Chemie International Edition, Vol. 54, Issue 8 https://doi.org/10.1002/anie.201411170	journal	January 2015
Solar CO ₂ Reduction Using Surface-Immobilized Molecular Catalysts Louis, Michael E.; Fenton, Thomas G.; Rondeau, Jarec Comments on Inorganic Chemistry, Vol. 36, Issue 1 https://doi.org/10.1080/02603594.2015.1088008	journal	September 2015
Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes Dalle, Kristian E.; Warnan, Julien; Leung, Jane J. Chemical Reviews, Vol. 119, Issue 4 https://doi.org/10.1021/acs.chemrev.8b00392	journal	October 2018
Recent Advances in Solar-Driven Carbon Dioxide Conversion: Expectations versus Reality He, Jie; Janáky, Csaba ACS Energy Letters, Vol. 5, Issue 6 https://doi.org/10.1021/acsenergylett.0c00645	journal	May 2020
Machine Learning Spectral Indicators of Topology Andrejevic, Nina Machine Learning-Augmented Spectroscopies for Intelligent Materials Design https://doi.org/10.1007/978-3-031-14808-8_5	book	January 2022
Photochemical and Photoelectrochemical Reduction of CO ₂ Kumar, Bhupendra; Llorente, Mark; Froehlich, Jesse Annual Review of Physical Chemistry, Vol. 63, Issue 1 https://doi.org/10.1146/annurev-physchem-032511-143759	journal	May 2012
Architecture of supramolecular metal complexes for photocatalytic CO2 reduction Koike, Kazuhide; Naito, Sayoko; Sato, Shunsuke Journal of Photochemistry and Photobiology A: Chemistry, Vol. 207, Issue 1 https://doi.org/10.1016/j.jphotochem.2008.12.014	journal	September 2009
Supramolecular Photocatalysts for the Reduction of CO ₂ Tamaki, Yusuke; Ishitani, Osamu ACS Catalysis, Vol. 7, Issue 5 https://doi.org/10.1021/acscatal.7b00440	journal	April 2017
Solving the structure of “single-atom” catalysts using machine learning – assisted XANES analysis Xiang, Shuting; Huang, Peipei; Li, Junying Physical Chemistry Chemical Physics, Vol. 24, Issue 8 https://doi.org/10.1039/D1CP05513E	journal	January 2022
Visible-Light-Driven CO ₂ Reduction by Mesoporous Carbon Nitride Modified with Polymeric Cobalt Phthalocyanine Roy, Souvik; Reisner, Erwin Angewandte Chemie International Edition, Vol. 58, Issue 35 https://doi.org/10.1002/anie.201907082	journal	July 2019
Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes White, James L.; Baruch, Maor F.; Pander, James E. Chemical Reviews, Vol. 115, Issue 23 https://doi.org/10.1021/acs.chemrev.5b00370	journal	August 2015
Local Structure and Electronic State of Atomically Dispersed Pt Supported on Nanosized CeO ₂ Kottwitz, Matthew; Li, Yuanyuan; Palomino, Robert M. ACS Catalysis, Vol. 9, Issue 9 https://doi.org/10.1021/acscatal.9b02083	journal	August 2019
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/PhysRevB.47.558	journal	January 1993
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Surface strategies for catalytic CO ₂ reduction: from two-dimensional materials to nanoclusters to single atoms Wang, Liming; Chen, Wenlong; Zhang, Doudou Chemical Society Reviews, Vol. 48, Issue 21 https://doi.org/10.1039/C9CS00163H	journal	January 2019
Single-Atom Catalysts across the Periodic Table Kaiser, Selina K.; Chen, Zupeng; Faust Akl, Dario Chemical Reviews, Vol. 120, Issue 21 https://doi.org/10.1021/acs.chemrev.0c00576	journal	October 2020
Parameter-free calculations of X-ray spectra with FEFF9 Rehr, John J.; Kas, Joshua J.; Vila, Fernando D. Physical Chemistry Chemical Physics, Vol. 12, Issue 21 https://doi.org/10.1039/b926434e	journal	January 2010
Semiconductor–redox catalysis promoted by metal–organic frameworks for CO2 reduction Wang, Sibo; Lin, Jinliang; Wang, Xinchen Physical Chemistry Chemical Physics, Vol. 16, Issue 28 https://doi.org/10.1039/c4cp02173h	journal	January 2014
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu Grimme, Stefan; Antony, Jens; Ehrlich, Stephan The Journal of Chemical Physics, Vol. 132, Issue 15 https://doi.org/10.1063/1.3382344	journal	April 2010
High-order multiple-scattering calculations of x-ray-absorption fine structure Rehr, J. J.; Albers, R. C.; Zabinsky, S. I. Physical Review Letters, Vol. 69, Issue 23 https://doi.org/10.1103/PhysRevLett.69.3397	journal	December 1992
Isolated single atom cobalt in Bi3O4Br atomic layers to trigger efficient CO2 photoreduction Di, Jun; Chen, Chao; Yang, Shi-Ze Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10392-w	journal	June 2019
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Ocean Acidification: The Other CO ₂ Problem Doney, Scott C.; Fabry, Victoria J.; Feely, Richard A. Annual Review of Marine Science, Vol. 1, Issue 1 https://doi.org/10.1146/annurev.marine.010908.163834	journal	January 2009
Stabilization of Single Metal Atoms on Graphitic Carbon Nitride Chen, Zupeng; Mitchell, Sharon; Vorobyeva, Evgeniya Advanced Functional Materials, Vol. 27, Issue 8 https://doi.org/10.1002/adfm.201605785	journal	January 2017
Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials Zitolo, Andrea; Goellner, Vincent; Armel, Vanessa Nature Materials, Vol. 14, Issue 9 https://doi.org/10.1038/nmat4367	journal	August 2015
Hybrid materials based on conjugated polymers and inorganic semiconductors as photocatalysts: from environmental to energy applications Liras, Marta; Barawi, Mariam; de la Peña O’Shea, Víctor A. Chemical Society Reviews, Vol. 48, Issue 22 https://doi.org/10.1039/C9CS00377K	journal	January 2019
Effect of Carbon Doping on CO ₂ ‐Reduction Activity of Single Cobalt Sites in Graphitic Carbon Nitride Huang, Peipei; Huang, Jiahao; Li, Junying ChemNanoMat, Vol. 7, Issue 9 https://doi.org/10.1002/cnma.202100164	journal	June 2021
Photocatalytic CO ₂ reduction using a molecular cobalt complex deposited on TiO ₂ nanoparticles Jin, Tong; Liu, Chao; Li, Gonghu Chem. Commun., Vol. 50, Issue 47 https://doi.org/10.1039/C4CC00503A	journal	January 2014
Mapping XANES spectra on structural descriptors of copper oxide clusters using supervised machine learning Liu, Yang; Marcella, Nicholas; Timoshenko, Janis The Journal of Chemical Physics, Vol. 151, Issue 16 https://doi.org/10.1063/1.5126597	journal	October 2019
Hybrid Carbon Dioxide Reduction Photocatalysts Consisting of Macrocyclic Cobalt(III) Complexes Deposited on Semiconductor Surfaces Huang, Peipei; Pantovich, Sebastian A.; Okolie, Norbert O. ChemPhotoChem, Vol. 4, Issue 6 https://doi.org/10.1002/cptc.201900282	journal	March 2020
Toward Solar-Driven Photocatalytic CO ₂ Reduction Using Water as an Electron Donor Sato, Shunsuke; Arai, Takeo; Morikawa, Takeshi Inorganic Chemistry, Vol. 54, Issue 11 https://doi.org/10.1021/ic502766g	journal	February 2015
Deciphering the Local Environment of Single-Atom Catalysts with X-ray Absorption Spectroscopy Li, Yuanyuan; Frenkel, Anatoly I. Accounts of Chemical Research, Vol. 54, Issue 11 https://doi.org/10.1021/acs.accounts.1c00180	journal	May 2021
Molecular deposition of a macrocyclic cobalt catalyst on TiO2 nanoparticles Liu, Chao; Jin, Tong; Louis, Michael E. Journal of Molecular Catalysis A: Chemical, Vol. 423 https://doi.org/10.1016/j.molcata.2016.07.019	journal	November 2016
The teraton challenge. A review of fixation and transformation of carbon dioxide Mikkelsen, Mette; Jørgensen, Mikkel; Krebs, Frederik C. Energy Environ. Sci., Vol. 3, Issue 1 https://doi.org/10.1039/B912904A	journal	January 2010

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photocatalysis
CO2 reduction
x-ray absorption spectroscopy
theoretical XANES modeling
density functional theory

Title: X-ray Absorption Spectroscopy Studies of a Molecular CO2-Reduction Catalyst Deposited on Graphitic Carbon Nitride

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Title: X-ray Absorption Spectroscopy Studies of a Molecular CO₂-Reduction Catalyst Deposited on Graphitic Carbon Nitride