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Title: Using Thermal Interface Resistance for Noninvasive Operando Mapping of Buried Interfacial Lithium Morphology in Solid-State Batteries

Journal Article · · ACS Applied Materials and Interfaces
ORCiD logo [1];  [2];  [3]; ORCiD logo [4]; ORCiD logo [2]; ORCiD logo [2];  [5]; ORCiD logo [4]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Mechanical Engineering, University of California, Berkeley, Berkeley, California 94720, United States, Energy Technologies Area, Lawrence Berkeley National Lab, 1 Cyclotron Road, Berkeley, California 94720, United States
  2. Energy Technologies Area, Lawrence Berkeley National Lab, 1 Cyclotron Road, Berkeley, California 94720, United States
  3. Department of Mechanical Engineering, University of California, Berkeley, Berkeley, California 94720, United States
  4. Argonne National Laboratory, Lemont, Illinois 60439, United States
  5. Energy Technologies Area, Lawrence Berkeley National Lab, 1 Cyclotron Road, Berkeley, California 94720, United States, Department of Mechanical Engineering, Boston University, Boston, Massachusetts 02215, United States

Not Available

Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1963120
Alternate ID(s):
OSTI ID: 2007762; OSTI ID: 2228873
Journal Information:
ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 13 Vol. 15; ISSN 1944-8244
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (51)

Toward Standardization of Electrochemical Impedance Spectroscopy Studies of Li-Ion Conductive Ceramics journal February 2020
Real-time 3D imaging of microstructure growth in battery cells using indirect MRI journal September 2016
Rethinking How External Pressure Can Suppress Dendrites in Lithium Metal Batteries journal January 2019
Identification and characterization of the dominant thermal resistance in lithium-ion batteries using operando 3-omega sensors journal March 2020
Recent advances in dendrite-free lithium metal anodes for high-performance batteries journal January 2022
A Review of Solid Electrolyte Interphases on Lithium Metal Anode journal November 2015
Temperature dependent flux balance of the Li/Li7La3Zr2O12 interface journal February 2019
Direct observation of lithium dendrites inside garnet-type lithium-ion solid electrolyte journal August 2015
High-rate lithium cycling in a scalable trilayer Li-garnet-electrolyte architecture journal January 2019
Reexamining the 3-omega technique for thin film thermal characterization journal October 2006
Nanoindentation of high-purity vapor deposited lithium films: The elastic modulus journal May 2018
Thermal conductivity measurement from 30 to 750 K: the 3ω method journal February 1990
Correlating the interface resistance and surface adhesion of the Li metal-solid electrolyte interface journal February 2018
The 3-Omega Method for the Measurement of Fouling Thickness, the Liquid Flow Rate, and Surface Contact journal March 2017
Reviving the lithium metal anode for high-energy batteries journal March 2017
Operando spatial mapping of lithium concentration using thermal-wave sensing journal August 2021
Toward a Fundamental Understanding of the Lithium Metal Anode in Solid-State Batteries—An Electrochemo-Mechanical Study on the Garnet-Type Solid Electrolyte Li 6.25 Al 0.25 La 3 Zr 2 O 12 journal March 2019
Linking void and interphase evolution to electrochemistry in solid-state batteries using operando X-ray tomography journal January 2021
Impedance Spectroscopy Analysis of the Lithium Ion Transport through the Li 7 La 3 Zr 2 O 12 /P(EO) 20 Li Interface journal January 2017
Recent advances in all-solid-state rechargeable lithium batteries journal March 2017
Stack Pressure Considerations for Room‐Temperature All‐Solid‐State Lithium Metal Batteries journal November 2019
Cryogenic Electron Microscopy for Characterizing and Diagnosing Batteries journal November 2018
A microbridge heater for low power gas sensing based on the 3-Omega technique journal September 2015
Lithium metal electrode kinetics and ionic conductivity of the solid lithium ion conductors “Li7La3Zr2O12” and Li7−xLa3Zr2−xTaxO12 with garnet-type structure journal May 2012
Local electrochemical impedance spectroscopy: A review and some recent developments journal April 2011
Elastoplastic Contact Conductance Model for Isotropic Conforming Rough Surfaces and Comparison With Experiments journal February 1996
Thermal conductivity of a -Si:H thin films journal September 1994
Hybrid Polymer/Garnet Electrolyte with a Small Interfacial Resistance for Lithium-Ion Batteries journal December 2016
Lithium-Metal Growth Kinetics on LLZO Garnet-Type Solid Electrolytes journal August 2019
1ω,2ω, and 3ω methods for measurements of thermal properties journal December 2005
Evolution of the Solid–Electrolyte Interphase on Carbonaceous Anodes Visualized by Atomic-Resolution Cryogenic Electron Microscopy journal July 2019
On our Limited Understanding of Electrodeposition journal January 2019
Algorithm for solutions of the thermal diffusion equation in a stratified medium with a modulated heating source journal January 1999
The origin of high electrolyte–electrode interfacial resistances in lithium cells containing garnet type solid electrolytes journal January 2014
Garnet-Type Solid-State Electrolytes: Materials, Interfaces, and Batteries journal April 2020
Creep-Enabled 3D Solid-State Lithium-Metal Battery journal November 2020
Review on Li-Sulfur Battery Systems: an Integral Perspective journal May 2015
General bidirectional thermal characterization via the 3ω technique journal June 2014
Effects of Pulse Charging by Triboelectric Nanogenerators on the Performance of Solid-State Lithium Metal Batteries journal June 2020
Interface in Solid-State Lithium Battery: Challenges, Progress, and Outlook journal May 2019
Lithium Metal Penetration Induced by Electrodeposition through Solid Electrolytes: Example in Single-Crystal Li 6 La 3 ZrTaO 12 Garnet journal January 2018
Enhancement of Thermal Contact Conductance by Metallic Coatings: Theory and Experiment journal August 1985
Microscopic and macroscopic thermal contact resistances of pressed mechanical contacts journal September 2006
In Situ STEM-EELS Observation of Nanoscale Interfacial Phenomena in All-Solid-State Batteries journal May 2016
Thermal conductivity measurement and sedimentation detection of aluminum oxide nanofluids by using the 3ω method journal October 2008
A New General Paradigm for Understanding and Preventing Li Metal Penetration through Solid Electrolytes journal December 2020
Exploiting self-heat in a lithium metal battery for dendrite healing journal July 2019
A durable and safe solid-state lithium battery with a hybrid electrolyte membrane journal March 2018
Pressure-Driven Interface Evolution in Solid-State Lithium Metal Batteries journal February 2020
Evolution of the lithium morphology from cycling of thin film solid state batteries journal March 2017
Characterizing the Li-Solid-Electrolyte Interface Dynamics as a Function of Stack Pressure and Current Density journal September 2019