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Title: Arrested coarsening and large density fluctuations in driven particle mixtures in two dimensions

Journal Article · · New Journal of Physics

Abstract Using molecular dynamics simulations, we study a driven, nonadditive binary mixture of spherical particles confined to move in two dimensions and immersed in an explicit solvent consisting of point particles with purely repulsive interactions. We show that, without a drive, the mixture of spherical particles phase separates and coarsens with kinetics consistent with an Ising-like conserved dynamics. Conversely, when the drive is applied, the coarsening is arrested and the system develops large density fluctuations. We show that the drive creates domains of a characteristic size which decreases with an increasing force. Furthermore, we find that these domains are anisotropic and can be oriented either parallel or perpendicular to the drive direction. Finally, we connect our findings to existing theories of strongly-driven systems, pointing out the importance of introducing the explicit solvent particles to break the Galilean invariance of the system.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1961012
Journal Information:
New Journal of Physics, Journal Name: New Journal of Physics Journal Issue: 3 Vol. 25; ISSN 1367-2630
Publisher:
IOP PublishingCopyright Statement
Country of Publication:
United Kingdom
Language:
English

References (34)

Theorie der Alterung von Niederschlägen durch Umlösen (Ostwald‐Reifung) journal September 1961
Interaction between particles suspended in solutions of macromolecules journal December 1958
Fast Parallel Algorithms for Short-Range Molecular Dynamics journal March 1995
Nonequilibrium steady states of stochastic lattice gas models of fast ionic conductors journal February 1984
Field theory of critical behaviour in driven diffusive systems journal December 1986
The kinetics of precipitation from supersaturated solid solutions journal April 1961
The London—van der Waals attraction between spherical particles journal October 1937
Implementing molecular dynamics on hybrid high performance computers – short range forces journal April 2011
Magnetic field guided colloidal assembly journal April 2013
Non-Equilibrium Phase Behavior of Immiscible Polymer-Grafted Nanoparticle Blends journal July 2019
Self-Assembly of Polymer Brush-Functionalized Inorganic Nanoparticles: From Hairy Balls to Smart Molecular Mimics journal October 2013
Friction between Brush Layers of Charged and Neutral Bottle-Brush Macromolecules. Molecular Dynamics Simulations journal December 2011
Critical-point and coexistence curve properties of a symmetric mixture of nonadditive hard spheres: A finite size scaling study journal August 2003
New Model for the Study of Liquid–Vapor Phase Transitions journal February 1970
Role of Repulsive Forces in Determining the Equilibrium Structure of Simple Liquids journal June 1971
On Interaction between Two Bodies Immersed in a Solution of Macromolecules journal July 1954
Fluid–fluid phase separations in nonadditive hard sphere mixtures journal January 1995
Energy dissipation and fluctuations in a driven liquid journal March 2018
Colloidal dispersions in external fields: recent developments journal September 2008
Phase coexistence far from equilibrium journal April 2016
Shear flow near solids: Epitaxial order and flow boundary conditions journal June 1990
Molecular-dynamics study of a three-dimensional one-component model for distortive phase transitions journal February 1978
Phase transitions in stationary nonequilibrium states of model lattice systems journal August 1983
Microemulsions in the driven Widom-Rowlinson lattice gas journal December 2021
Direct measurements of colloidal friction coefficients journal November 2001
Interaction potentials for soft and hard ellipsoids journal April 2003
Oscillatory driven colloidal binary mixtures: Axial segregation versus laning journal April 2009
Driven Widom-Rowlinson lattice gas journal June 2018
Spatial Structures and Giant Number Fluctuations in Models of Active Matter journal June 2012
Entropically Driven Surface Phase Separation in Binary Colloidal Mixtures journal January 1994
Motility-Induced Phase Separation journal March 2015
Instabilities and turbulence-like dynamics in an oppositely driven binary particle mixture journal September 2012
Active nematics on a substrate: Giant number fluctuations and long-time tails journal April 2003
Driven binary mixtures: Clustering and giant diffusion journal February 2006