Nanoporous Pt(Au) Alloys for the Enhanced, Non–enzymatic Detection of Hydrogen Peroxide under Biofouling Conditions

Khan, Rezaul K.; Silva, Tiago A.; Fatibello‐Filho, Orlando; Collinson, Maryanne M.; Farghaly, Ahmed A.

doi:10.1002/elan.202100568

Title: Nanoporous Pt(Au) Alloys for the Enhanced, Non–enzymatic Detection of Hydrogen Peroxide under Biofouling Conditions

Journal Article · 11 January 2022 · Electroanalysis

DOI: https://doi.org/10.1002/elan.202100568 · OSTI ID:1958428

Khan, Rezaul K. ^[1];

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Virginia Commonwealth Univ., Richmond, VA (United States)
Federal Univ. of Sao Carlos, Sao Paulo (Brazil); Federal University of Vicosa, MG (Brazil)
Federal Univ. of Sao Carlos, Sao Paulo (Brazil)
Argonne National Lab. (ANL), Lemont, IL (United States); Assiut University (Egypt)

The non-enzymatic electrochemical sensing of hydrogen peroxide (H₂O₂) is described. This study utilized a 3D bicontinuous nanoporous platinum-gold alloy-based sensor (NP-Pt(Au) electrode), which has a morphology that resembles a molecular sieve. SEM and CV were used to evaluate the morphological and electrochemical characteristics of the NP-Pt(Au) electrodes. The cathodic voltammetric response of H₂O₂ was enhanced at the NP-Pt(Au) as compared to planar Pt electrodes. Further, the nanoporous electrode was able to maintain the H₂O₂ voltammetric profile even in the presence of the biofouling agent, serum albumin. Its application as a non-enzymatic sensor for the amperometric measurement of H₂O₂ was explored.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Brazilian Ministry of Higher Education, Coordination for the Improvement of Higher Education Personnel (CAPES); Virginia Commonwealth University

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1958428

Journal Information:: Electroanalysis, Journal Name: Electroanalysis Journal Issue: 12 Vol. 34; ISSN 1040-0397

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Nanoporous Pt(Au) Alloys for the Enhanced, Non–enzymatic Detection of Hydrogen Peroxide under Biofouling Conditions

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