Pressure Driven Alkane Dehydrogenation by Palladium Metal

Frost, Mungo; McBride, Emma E.; Smith, Dean; Smith, Jesse S.; Glenzer, Siegfried H.

doi:10.1002/admi.202202081

Title: Pressure Driven Alkane Dehydrogenation by Palladium Metal

Journal Article · 14 February 2023 · Advanced Materials Interfaces

DOI: https://doi.org/10.1002/admi.202202081 · OSTI ID:1926713

^[1]; McBride, Emma E. ^[1]; Smith, Dean ^[2]; Smith, Jesse S. ^[2]; Glenzer, Siegfried H. ^[1]

High Energy Density Sciences Division SLAC National Accelerator Laboratory 2575 Sand Hill Road Menlo Park CA 94025 USA
High Pressure Collaborative Access Team X‐Ray Sciences Division Argonne National Laboratory Argonne IL 60439 USA

Abstract Dehydrogenation of alkanes is of increasing importance in fulfilling global demand for olefins and offers a potential source of carbon‐neutral hydrogen as a co‐product. Currently commercial dehydrogenation processes occur at high‐temperatures (500–900 °C) which is energy intensive and results in side reactions and rapid coking of the catalysts. In addition, the hydrogen produced is often burned to maintain temperature and to inhibit the back reaction. Here, pressure is utilized as a parameter to enable novel chemical catalytic processes, and ambient‐temperature dehydrogenation of alkanes by palladium is observed at 50–100 MPa, with both hydrogen gas and olefins recovered on decompression. This reaction follows a fundamentally different path to current commercial high‐temperature low‐pressure dehydrogenation processes with the palladium catalyst reversibly forming a hydride intermediate.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE; USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE Office of Science (SC), Fusion Energy Sciences (FES)

Contributing Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Grant/Contract Number:: AC02-06CH11357; AC02-76SF00515

OSTI ID:: 1926713

Journal Information:: Advanced Materials Interfaces, Journal Name: Advanced Materials Interfaces Journal Issue: 9 Vol. 10; ISSN 2196-7350

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Title: Pressure Driven Alkane Dehydrogenation by Palladium Metal

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