Nested Metal Catalysts: Metal Atoms and Clusters Stabilized by Confinement with Accessibility on Supports

Gates, Bruce C.; Katz, Alexander; Liu, Jingyue

doi:10.1021/prechem.2c00011

Title: Nested Metal Catalysts: Metal Atoms and Clusters Stabilized by Confinement with Accessibility on Supports

Journal Article · 14 February 2023 · Precision Chemistry

DOI: https://doi.org/10.1021/prechem.2c00011 · OSTI ID:1924831

^[1];

^[2]; Liu, Jingyue ^[3]

Department of Chemical Engineering, University of California, Davis, Davis, California 95616, United States
Department of Chemical and Biomolecular Engineering, University of California, Berkeley, Berkeley, California 94720, United States
Department of Physics, Arizona State University, Tempe, Arizona 85287, United States

Not Available

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-04ER15513; FG02-05ER15696

OSTI ID:: 1924831

Alternate ID(s):: OSTI ID: 1963597; OSTI ID: 2263481

Journal Information:: Precision Chemistry, Journal Name: Precision Chemistry Journal Issue: 1 Vol. 1; ISSN 2771-9316

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (43)

Sinter-resistant metal nanoparticle catalysts achieved by immobilization within zeolite crystals via seed-directed growth Zhang, Jian; Wang, Liang; Zhang, Bingsen Nature Catalysis, Vol. 1, Issue 7 https://doi.org/10.1038/s41929-018-0098-1	journal	July 2018
Applied Hydroformylation Franke, Robert; Selent, Detlef; Börner, Armin Chemical Reviews, Vol. 112, Issue 11 https://doi.org/10.1021/cr3001803	journal	August 2012
Single-Atom Alloy Catalysis Hannagan, Ryan T.; Giannakakis, Georgios; Flytzani-Stephanopoulos, Maria Chemical Reviews https://doi.org/10.1021/acs.chemrev.0c00078	journal	June 2020
Catalysis by Doped Oxides McFarland, Eric W.; Metiu, Horia Chemical Reviews, Vol. 113, Issue 6 https://doi.org/10.1021/cr300418s	journal	December 2012
γ-Al2O3-Supported Pt Catalysts with Extremely High Dispersions Resulting from Pt–W Interactions Alexeev, Oleg S.; Graham, George W.; Shelef, Mordecai Journal of Catalysis, Vol. 190, Issue 1 https://doi.org/10.1006/jcat.1999.2739	journal	February 2000
Electronic Structure of Atomically Dispersed Supported Iridium Catalyst Controls Iridium Aggregation Kurtoğlu, Samira F.; Hoffman, Adam S.; Akgül, Deniz ACS Catalysis, Vol. 10, Issue 21 https://doi.org/10.1021/acscatal.0c03909	journal	October 2020
Synthesis, characterization, and function of Au nanoparticles within TS-1 zeotypes as catalysts for alkene epoxidation using O2/H2O reactants Otto, Trenton; Zhou, Xiaoyu; Zones, Stacey I. Journal of Catalysis, Vol. 410 https://doi.org/10.1016/j.jcat.2022.04.002	journal	June 2022
A Comparative Study of the Catalytic Mechanisms of the Zinc and Cadmium Containing Carbonic Anhydrase Marino, Tiziana; Russo, Nino; Toscano, Marirosa Journal of the American Chemical Society, Vol. 127, Issue 12 https://doi.org/10.1021/ja045546q	journal	March 2005
A Tailored Microenvironment for Catalytic Biomass Conversion in Inorganic-Organic Nanoreactors Alamillo, Ricardo; Crisci, Anthony J.; Gallo, Jean Marcel R. Angewandte Chemie International Edition, Vol. 52, Issue 39 https://doi.org/10.1002/anie.201304693	journal	August 2013
Coordinately unsaturated clusters. A novel catalytic reaction Burch, R. R.; Shusterman, A. J.; Muetterties, E. L. Journal of the American Chemical Society, Vol. 105, Issue 11 https://doi.org/10.1021/ja00349a030	journal	June 1983
High productivity methanol carbonylation catalysis using iridium Sunley, Glenn J.; Watson, Derrick J. Catalysis Today, Vol. 58, Issue 4 https://doi.org/10.1016/S0920-5861(00)00263-7	journal	May 2000
Ship-in-Bottle Synthesis of [Pt ₁₅ (CO) ₃₀ ] ² ^- Encapsulated in Ordered Hexagonal Mesoporous Channels of FSM-16 and Their Effective Catalysis in Water-Gas Shift Reaction Yamamoto, Takashi; Shido, Toshifumi; Inagaki, Shinji Journal of the American Chemical Society, Vol. 118, Issue 24 https://doi.org/10.1021/ja953065o	journal	January 1996
Templated encapsulation of platinum-based catalysts promotes high-temperature stability to 1,100 °C Aitbekova, Aisulu; Zhou, Chengshuang; Stone, Michael L. Nature Materials, Vol. 21, Issue 11 https://doi.org/10.1038/s41563-022-01376-1	journal	October 2022
γ-Al₂O₃-Supported Re−Pt Cluster Catalyst Prepared from [Re₂Pt(CO)₁₂]: Characterization by Extended X-ray Absorption Fine Structure Spectroscopy and Catalysis of Methylcyclohexane Dehydrogenation Fung, A. S.; Kelley, M. J.; Koningsberger, D. C. Journal of the American Chemical Society, Vol. 119, Issue 25 https://doi.org/10.1021/ja962816z	journal	June 1997
Polymer-Encapsulated Metallic Nanoparticles as a Bridge Between Homogeneous and Heterogeneous Catalysis Gross, Elad; Dean Toste, F.; Somorjai, Gabor A. Catalysis Letters, Vol. 145, Issue 1 https://doi.org/10.1007/s10562-014-1436-9	journal	November 2014
Dynamic Reorganization and Confinement of Ti ^IV Active Sites Controls Olefin Epoxidation Catalysis on Two-Dimensional Zeotypes Grosso-Giordano, Nicolás A.; Hoffman, Adam S.; Boubnov, Alexey Journal of the American Chemical Society, Vol. 141, Issue 17 https://doi.org/10.1021/jacs.9b02160	journal	April 2019
Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit Lucci, Felicia R.; Liu, Jilei; Marcinkowski, Matthew D. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9550	journal	October 2015
Hydrogen Activation and Metal Hydride Formation Trigger Cluster Formation from Supported Iridium Complexes Lu, Jing; Aydin, Ceren; Browning, Nigel D. Journal of the American Chemical Society, Vol. 134, Issue 11 https://doi.org/10.1021/ja211380p	journal	March 2012
Single atom alloy surface analogs in Pd0.18Cu15 nanoparticles for selective hydrogenation reactions Boucher, Matthew B.; Zugic, Branko; Cladaras, George Physical Chemistry Chemical Physics, Vol. 15, Issue 29 https://doi.org/10.1039/c3cp51538a	journal	January 2013
Weakly interacting solvation spheres surrounding a calixarene-protected tetrairidium carbonyl cluster: contrasting effects on reactivity of alkane solvent and silica support Palermo, Andrew P.; Zhang, Shengjie; Hwang, Son-Jong Dalton Transactions, Vol. 47, Issue 38 https://doi.org/10.1039/C8DT01371C	journal	January 2018
A Review of the Phillips Supported Chromium Catalyst and Its Commercial Use for Ethylene Polymerization McDaniel, Max P. Advances in Catalysis https://doi.org/10.1016/S0360-0564(10)53003-7	book	January 2010
Functional CeOx nanoglues for robust atomically dispersed catalysts Li, Xu; Pereira-Hernández, Xavier Isidro; Chen, Yizhen Nature, Vol. 611, Issue 7935 https://doi.org/10.1038/s41586-022-05251-6	journal	October 2022
A Pd@Zeolite Catalyst for Nitroarene Hydrogenation with High Product Selectivity by Sterically Controlled Adsorption in the Zeolite Micropores Zhang, Jian; Wang, Liang; Shao, Yi Angewandte Chemie International Edition, Vol. 56, Issue 33 https://doi.org/10.1002/anie.201703938	journal	May 2017
Synthesis and Characterization of Model MgO-Supported Catalysts with Pt−Mo Interactions Alexeev, O.; Kawi, S.; Shelef, M. The Journal of Physical Chemistry, Vol. 100, Issue 1 https://doi.org/10.1021/jp951432c	journal	January 1996
Steering CO ₂ hydrogenation toward C–C coupling to hydrocarbons using porous organic polymer/metal interfaces Zhou, Chengshuang; Asundi, Arun S.; Goodman, Emmett D. Proceedings of the National Academy of Sciences, Vol. 119, Issue 7 https://doi.org/10.1073/pnas.2114768119	journal	February 2022
Mechanism of Oxidation Reactions Catalyzed by Cytochrome P450 Enzymes Meunier, Bernard; de Visser, Samuël P.; Shaik, Sason Chemical Reviews, Vol. 104, Issue 9 https://doi.org/10.1021/cr020443g	journal	September 2004
Epoxidation of 1-octene under harsh tail-end conditions in a flow reactor I: a comparative study of crystalline vs. amorphous catalysts Aigner, Martina; Grosso-Giordano, Nicolás Andrés; Okrut, Alexander Reaction Chemistry & Engineering, Vol. 2, Issue 6 https://doi.org/10.1039/C7RE00076F	journal	January 2017
Outer-Sphere Control of Catalysis on Surfaces: A Comparative Study of Ti(IV) Single-Sites Grafted on Amorphous versus Crystalline Silicates for Alkene Epoxidation Grosso-Giordano, Nicolás A.; Schroeder, Christian; Okrut, Alexander Journal of the American Chemical Society, Vol. 140, Issue 15 https://doi.org/10.1021/jacs.7b11467	journal	March 2018
Beating Heterogeneity of Single-Site Catalysts: MgO-Supported Iridium Complexes Hoffman, Adam S.; Debefve, Louise M.; Zhang, Shengjie ACS Catalysis, Vol. 8, Issue 4 https://doi.org/10.1021/acscatal.8b00143	journal	March 2018
First-principles design of a single-atom–alloy propane dehydrogenation catalyst Hannagan, Ryan T.; Giannakakis, Georgios; Réocreux, Romain Science, Vol. 372, Issue 6549 https://doi.org/10.1126/science.abg8389	journal	June 2021
MgO-Supported Platinum–Tungsten Catalysts Prepared from Organometallic Precursors: Platinum Clusters Isolated on Dispersed Tungsten Alexeev, O.; Shelef, M.; Gates, B. C. Journal of Catalysis, Vol. 164, Issue 1 https://doi.org/10.1006/jcat.1996.0357	journal	November 1996
Sintering-Resistant Nanoparticles in Wide-Mouthed Compartments for Sustained Catalytic Performance Liu, Jia; Ji, Qingmin; Imai, Tsubasa Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep41773	journal	February 2017
Ionic Liquid Sheath Stabilizes Atomically Dispersed Reduced Graphene Aerogel‐Supported Iridium Complexes during Ethylene Hydrogenation Catalysis Kurtoğlu‐Öztulum, Samira F.; Yalçın, Kaan; Hoffman, Adam S. ChemCatChem, Vol. 14, Issue 19 https://doi.org/10.1002/cctc.202200553	journal	August 2022
Epoxidation of Lower Olefins with Hydrogen Peroxide and Titanium Silicalite Clerici, M. G.; Ingallina, P. Journal of Catalysis, Vol. 140, Issue 1 https://doi.org/10.1006/jcat.1993.1069	journal	March 1993
Zeolite Fixed Metal Nanoparticles: New Perspective in Catalysis Wang, Yeqing; Wang, Chengtao; Wang, Lingxiang Accounts of Chemical Research, Vol. 54, Issue 11 https://doi.org/10.1021/acs.accounts.1c00074	journal	May 2021
Mechanical Control of Rate Processes: Effect of Ligand Steric Bulk on CO Exchange in Trisubstituted Tetrairidium Cluster Catalysts Solovyov, Andrew; Yabushita, Mizuho; Katz, Alexander The Journal of Physical Chemistry C, Vol. 124, Issue 48 https://doi.org/10.1021/acs.jpcc.0c07962	journal	November 2020
The role of vanadium bromoperoxidase in the biosynthesis of halogenated marine natural products Butler, Alison; Carter-Franklin, Jayme N. Natural Product Reports, Vol. 21, Issue 1 https://doi.org/10.1039/b302337k	journal	January 2004
Sieving Properties of Zeolites for C₆−C₈ Hydrocarbons: The Effects of a Trimethyltin Complex Grafted on the Pore Edge Bigot, Bernard; Peuch, Vincent-Henri The Journal of Physical Chemistry B, Vol. 102, Issue 44 https://doi.org/10.1021/jp9817776	journal	October 1998
Bulky Calixarene Ligands Stabilize Supported Iridium Pair-Site Catalysts Schöttle, Christian; Guan, Erjia; Okrut, Alexander Journal of the American Chemical Society, Vol. 141, Issue 9 https://doi.org/10.1021/jacs.8b13013	journal	February 2019
A Theory-Guided X-ray Absorption Spectroscopy Approach for Identifying Active Sites in Atomically Dispersed Transition-Metal Catalysts Chen, Yizhen; Rana, Rachita; Sours, Tyler Journal of the American Chemical Society, Vol. 143, Issue 48 https://doi.org/10.1021/jacs.1c07116	journal	November 2021
Supported Bimetallic Cluster Catalysts Alexeev, O. S.; Gates, B. C. Industrial & Engineering Chemistry Research, Vol. 42, Issue 8 https://doi.org/10.1021/ie020351h	journal	April 2003
Partially Decarbonylated Tetrairidium Clusters on γ-Al2O3: Structural Characterization and Catalysis of Toluene Hydrogenation Alexeev, O.; Panjabi, G.; Gates, B. C. Journal of Catalysis, Vol. 173, Issue 1 https://doi.org/10.1006/jcat.1997.1907	journal	January 1998
A Surface Organometallic Approach for Controlling the Pore Opening Size of Zeolites: the Case of Mordenite Modified via Grafting of Dineopentylmagnesium Théolier, Albert; Custodero, Emmanuel; Choplin, Agnès Angewandte Chemie International Edition in English, Vol. 29, Issue 7 https://doi.org/10.1002/anie.199008051	journal	July 1990

Similar Records

Atomically dispersed supported metal catalysts: perspectives and suggestions for future research

Journal Article · 2017 · Catalysis Science and Technology · OSTI ID:1539905

Gates, Bruce C.; Flytzani-Stephanopoulos, Maria; Dixon, David A.; +1 more

Bulky Calixarene Ligands Stabilize Supported Iridium Pair-Site Catalysts

Journal Article · 2019 · Journal of the American Chemical Society · OSTI ID:1609617

Schöttle, Christian; Guan, Erjia; Okrut, Alexander; +5 more

Dialing in single-site reactivity of a supported calixarene-protected tetrairidium cluster catalyst

Journal Article · 2017 · Chemical Science · OSTI ID:1429914

Palermo, Andrew; Solovyov, Andrew; Ertler, Daniel; +3 more

Title: Nested Metal Catalysts: Metal Atoms and Clusters Stabilized by Confinement with Accessibility on Supports

Citation Formats

References (43)

Similar Records

Related Subjects