Transformation of a ceramic precursor to a biomedical (metallic) alloy: Part I – sinterability of Ta2O5 and TiO2 mixed oxides

Chorney, Maureen P.; Hurley, Bridger P.; Mondal, Kunal; Khanolkar, Amey Rajendra; Downey, Jerome P.; Tripathy, Prabhat K

doi:10.1016/j.mset.2022.01.006

Title: Transformation of a ceramic precursor to a biomedical (metallic) alloy: Part I – sinterability of Ta₂O₅ and TiO₂ mixed oxides

Journal Article · 26 January 2022 · Materials Science for Energy Technologies

DOI: https://doi.org/10.1016/j.mset.2022.01.006 · OSTI ID:1924806

Chorney, Maureen P. ^[1]; Hurley, Bridger P. ^[1]; Mondal, Kunal ^[2]; Khanolkar, Amey Rajendra ^[2]; Downey, Jerome P. ^[1];

^[2]

Montana Technological Univ., Butte, MT (United States)
Idaho National Lab. (INL), Idaho Falls, ID (United States)

Mixed Ta₂O₅ – TiO₂ binary system was studied by a combination of differential thermal analysis (DTA), scanning electron microscopy-energy dispersive spectrometry (SEM-EDS), X-ray diffraction (XRD) and in situ high temperature X-ray diffraction (HT-XRD) techniques. Different compositions of the mixed oxide powders were fabricated by ball–milling the powdered compositions, pelletizing the homogenized composite powders, and heating the green pellets in air at different temperatures for fixed time intervals. The sintered pellets were evaluated and characterized with respect to porosity, morphology, and phase distribution. DTA runs of the un-sintered powders indicated the onset temperatures for both exothermic and endothermic changes in the binary system. Significant amount of sintering was observed to take place at temperatures higher than 900 °C. Both room and high temperature X-ray diffraction patterns exhibited consistency in phase formation. A ternary compound (TaTiO₄) and a ternary solid solution (Ti_0.33Ta_0.67O₂) were observed to form in both room and high temperatures in addition to the respective binary phases (Ta₂O₅ and TiO₂). A sintering temperature in the range 900–1000 °C was observed to be adequate to achieve the requisite mechanical strength and optimum internal porosity (40–48%) for subsequent electrochemical polarization experiments.

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Research Organization:: Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC07-05ID14517

OSTI ID:: 1924806

Report Number(s):: INL/JOU-18-52171-Rev000

Journal Information:: Materials Science for Energy Technologies, Journal Name: Materials Science for Energy Technologies Journal Issue: - Vol. 5; ISSN 2589-2991

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
mixed oxides
oxide morphology
phase evolution
sintering
tantalum pentoxide
titanium dioxide

Title: Transformation of a ceramic precursor to a biomedical (metallic) alloy: Part I – sinterability of Ta2O5 and TiO2 mixed oxides

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Title: Transformation of a ceramic precursor to a biomedical (metallic) alloy: Part I – sinterability of Ta₂O₅ and TiO₂ mixed oxides