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Title: Versatile Graphitized Carbon Nanofibers in Energy Applications

Journal Article · · ACS Sustainable Chemistry & Engineering
 [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4];  [2]
  1. Thapar Institute of Engineering and Technology (TIET) - Virginia Tech Center of Excellence in Emerging Materials, Patiala (India). Thapar Institute of Engineering and Technology
  2. KLE Technological University, Karnataka (India)
  3. Idaho National Lab. (INL), Idaho Falls, ID (United States); Idaho State Univ., Pocatello, ID (United States)
  4. Indian Inst. of Technology (IIT), Kanpur (India)

Graphitized carbon nanofibers (CNFs) are the allotropic forms of carbon that offer exceptional electrical conductivity, high aspect ratio, large surface-to-volume ratio, flexibility, mechanical robustness, and structural stability. These properties render CNFs as useful materials in energy applications, including water electrocatalysis and electrochemical energy storage devices (EESDs). Graphitized CNFs manifest huge versatility in EESDs and have been employed as electrode materials, as supports for other electrode materials, and conductive additives. This perspective summarizes the production methods, structural aspects, and energy applications of graphitized CNFs. Different design strategies have been employed to produce CNFs with diverse and distinct morphologies and structures. Their fabrication methods, along with precursors and dopants or cocatalysts, impact the overall structural, functional, and topographical properties. Recent developments on the state-of-the-art interests of graphitic CNFs in lithium-ion batteries (LIBs), lithium–sulfur (Li–S) batteries, vanadium redox flow batteries (VRFBs), supercapacitors, and water splitting have explored the many possibilities in energy sectors. Finally, the assembly and functioning of CNFs in water splitting and EESDs as well as primary challenges are discussed in this perspective.

Research Organization:
Idaho National Laboratory (INL), Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE Office of Nuclear Energy (NE)
Grant/Contract Number:
AC07-05ID14517
OSTI ID:
1923465
Report Number(s):
INL/JOU-21-63043-Rev000
Journal Information:
ACS Sustainable Chemistry & Engineering, Journal Name: ACS Sustainable Chemistry & Engineering Journal Issue: 4 Vol. 10; ISSN 2168-0485
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English

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