Crosslinked Polyethyleneimine Gel Polymer Interface to Improve Cycling Stability of RFBs

Journal Article · 04 January 2022 · Energy Material Advances

DOI: https://doi.org/10.34133/2022/9863679 · OSTI ID:1909284

Lim, Hyung-Seok  ^[1]; Chae, Sujong ^[1]; Yan, Litao ^[1]; Li, Guosheng  ^[1]; Feng, Ruozhu  ^[1]; Shin, Yongsoon ^[2]; Nie, Zimin ^[1]; Sivakumar, Bhuvaneswari Modachur ^[1]; Zhang, Xin  ^[2]; Liang, Yangang ^[1]; Bazak, David Jonathan  ^[2]; Shutthanandan, Vaithiyalingam  ^[2]; Murugesan, Vijayakumar  ^[2]; Kim, Soowhan ^[1]; Wang, Wei  ^[1]

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1. Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, WA 99354, USA
2. Physical &, Computational Science Directorate, Pacific Northwest National Laboratory, Richland, WA 99354, USA

Redox flow batteries are considered a promising technology for grid energy storage. However, capacity decay caused by crossover of active materials is a universal challenge for many flow battery systems, which are based on various chemistries. In this paper, using the vanadium redox flow battery as an example, we demonstrate a new gel polymer interface (GPI) consisting of crosslinked polyethyleneimine with a large amount of amino and carboxylic acid groups introduced between the positive electrode and the membrane. The GPI functions as a key component to prevent vanadium ions from crossing the membrane, thus supporting stable long-term cycling. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) measurements were conducted to investigate the effect of GPI on the electrochemical properties of graphitic carbon electrodes (GCFs) and redox reaction of catholyte. X-ray photoelectron spectroscopy (XPS) and ¹ H nuclear magnetic resonance (NMR) spectra demonstrated that the crosslinked GPI is chemically stable for 100 cycles without dissolution of polymers and swelling in the strong acidic electrolytes. Results from inductively coupled plasma mass spectrometry (ICP-MS), Fourier-transform infrared (FTIR) spectroscopy, and energy-dispersive X-ray (EDX) spectroscopy proved that the GPI is effective in maintaining the concentration of vanadium species in their respective half-cells, resulting in improved cycling stability because of it prevents active species from crossing the membrane and stabilizes the oxidation states of active species.

• Sponsoring Organization: USDOE
• Grant/Contract Number: AC05-76RL01830
• OSTI ID: 1909284
• Journal Information: Energy Material Advances, Journal Name: Energy Material Advances Vol. 2022; ISSN 2692-7640
• Publisher: American Association for the Advancement of Science (AAAS)Copyright Statement
• Country of Publication: United States
• Language: English