Effect of bimetallic modification on blast furnace slag and its application in low‐temperature selective catalytic reduction

Zhang, Lei; Han, Yuzhen; Shu, Hao; Zhang, Lei; Han, Zhikun; Yang, Xueying; Chen, Ya

doi:10.1002/jctb.7298

Title: Effect of bimetallic modification on blast furnace slag and its application in low‐temperature selective catalytic reduction

Journal Article · 08 January 2023 · Journal of Chemical Technology and Biotechnology

DOI: https://doi.org/10.1002/jctb.7298 · OSTI ID:1908382

Zhang, Lei ^[1]; Han, Yuzhen ^[2]; Shu, Hao ^[3]; Zhang, Lei ^[4]; Han, Zhikun ^[2]; Yang, Xueying ^[2]; Chen, Ya ^[2]

Xi'an University of Science and Technology Xi'an China, Key Laboratory of Coal Resources Exploration and Comprehensive Utilization Ministry of Natural Resources Xi'an China, Shaanxi Bo Shi Yi San New Material Environmental Protection and Technology Co. Ltd Xi'an China
Xi'an University of Science and Technology Xi'an China
School of Water Resources and Hydroelectric Engineering Xi'an University of Technology Xi'an China
China National Heavy Machinery Research Institute Co. Ltd Xi'an China

Abstract Objective In order to control NO _x in low‐temperature flue gases emitted from non‐power industries and to reduce the preparation cost of denitration catalysts, this study uses inexpensive blast furnace slag as raw material to prepare denitration catalysts. Methods After cooling, drying and grinding, the blast furnace slag becomes a powder with considerable fineness and meets the requirements of activity index, which is called GGBS (ground granulated blast furnace slag). Using GGBS as denitration catalyst carrier, the active components M (M = Fe, Co, Ni, Cu and Ce) are loaded on Mn‐based GGBS catalyst using an impregnation method. Conclusions The effect of different active components on the denitration performance and sulfur resistance of Mn‐based GGBS catalysts is investigated. The results show that the Mn‐Ce/GGBS catalyst has better denitration performance and sulfur resistance. The Mn‐Ce/GGBS catalyst has a significant denitration performance when load ratio is 2:1. The active component Ce improves the denitration performance of the catalyst, reduces sulfur poisoning and extends the life of the catalyst. The SO ₂ in the flue gas increases the acid sites on the catalyst surface and improves catalyst activity. The larger the ratios of Mn ⁴⁺ /Mn ³⁺ , Ce ⁴⁺ /Ce ³⁺ and O _α /O _β , the stronger the catalyst activity and the better the denitration performance. © 2022 Society of Chemical Industry (SCI).

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 1908382

Journal Information:: Journal of Chemical Technology and Biotechnology, Journal Name: Journal of Chemical Technology and Biotechnology Journal Issue: 4 Vol. 98; ISSN 0268-2575

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (38)

Mechanism by which Tungsten Oxide Promotes the Activity of Supported V ₂ O ₅ /TiO ₂ Catalysts for NO _X Abatement: Structural Effects Revealed by ⁵¹ V MAS NMR Spectroscopy Jaegers, Nicholas R.; Lai, Jun‐Kun; He, Yang Angewandte Chemie International Edition, Vol. 58, Issue 36 https://doi.org/10.1002/anie.201904503	journal	September 2019
Shear Stress on the Structure Control of a Supported Fly Ash‐Based Catalyst and Its Application in SCR* Denitration Hao, Shu; Yuling, Liu; Yang, Jia ChemistrySelect, Vol. 6, Issue 31 https://doi.org/10.1002/slct.202101770	journal	August 2021
Application and removal mechanism of ZnO/bentonite desulfurizer in the dry desulfurization Lei, Zhang; Yang, Jia; Weiwei, Xie Applied Physics A, Vol. 128, Issue 2 https://doi.org/10.1007/s00339-021-05221-1	journal	January 2022
Preparation of MnO2@CeO2 core–shell catalyst and its application in SCO denitration performance Zhang, Lei; Han, Zhikun; Jia, Yang Applied Physics A, Vol. 128, Issue 7 https://doi.org/10.1007/s00339-022-05543-8	journal	June 2022
Decomposition of NO in automobile exhaust by plasma–photocatalysis synergy Chen, Meng; Jin, Lisheng; Liu, Yanhua Environmental Science and Pollution Research, Vol. 21, Issue 2 https://doi.org/10.1007/s11356-013-2021-2	journal	July 2013
Existing forms and changes of nitrogen inside of horizontal subsurface constructed wetlands Wang, Hao; Zhong, Huiyuan; Bo, Guozhu Environmental Science and Pollution Research, Vol. 25, Issue 1 https://doi.org/10.1007/s11356-017-0477-1	journal	October 2017
MnOx-CuOx cordierite catalyst for selective catalytic oxidation of the NO at low temperature Lei, Zhang; Hao, Shu; Zhang, Lei Environmental Science and Pollution Research, Vol. 27, Issue 19 https://doi.org/10.1007/s11356-020-08785-2	journal	April 2020
Improvement of NOX Reduction Rate of Urea SCR System Applied for an Non-Road Diesel Engine Han, Joonsoo; Kim, Taemin; Jung, Haksup International Journal of Automotive Technology, Vol. 20, Issue 6 https://doi.org/10.1007/s12239-019-0108-6	journal	September 2019
Spinel structured CoaMnbOx mixed oxide catalyst for the selective catalytic reduction of NOx with NH3 Meng, Dongmei; Xu, Qian; Jiao, Yunlei Applied Catalysis B: Environmental, Vol. 221 https://doi.org/10.1016/j.apcatb.2017.09.034	journal	February 2018
Smog analysis and its effect on reported ocular surface diseases: A case study of 2016 smog event of Lahore Ashraf, Arooj; Butt, Aleem; Khalid, Imran Atmospheric Environment, Vol. 198 https://doi.org/10.1016/j.atmosenv.2018.10.029	journal	February 2019
Nitrate isotopic composition of sequential Hurricane Harvey wet deposition: Low latitude NOx sources and oxidation chemistry David Felix, J.; Murgulet, Dorina Atmospheric Environment, Vol. 238 https://doi.org/10.1016/j.atmosenv.2020.117748	journal	October 2020
Volatile–char interactions during biomass pyrolysis: Cleavage of C–C bond in a β–5 lignin model dimer by amino-modified graphitized carbon nanotube Huang, Yong; Liu, Shasha; Zhang, Jie Bioresource Technology, Vol. 307 https://doi.org/10.1016/j.biortech.2020.123192	journal	July 2020
Comparison of Cu-Mg-Al-Ox and Cu/Al2O3 in selective catalytic oxidation of ammonia (NH3-SCO) Jabłońska, Magdalena; Wolkenar, Bernd; Beale, Andrew M. Catalysis Communications, Vol. 110 https://doi.org/10.1016/j.catcom.2018.03.003	journal	May 2018
Preparation of structured catalysts with Ni and Ni–Rh/CeO2 catalytic layers for syngas production by biogas reforming processes Italiano, C.; Balzarotti, R.; Vita, A. Catalysis Today, Vol. 273 https://doi.org/10.1016/j.cattod.2016.01.037	journal	September 2016
Co-pyrolytic mechanisms, kinetics, emissions and products of biomass and sewage sludge in N2, CO2 and mixed atmospheres Chen, Jiacong; Zhang, Junhui; Liu, Jingyong Chemical Engineering Journal, Vol. 397 https://doi.org/10.1016/j.cej.2020.125372	journal	October 2020
A high-safety and multifunctional MOFs modified aramid nanofiber separator for lithium-sulfur batteries Liu, Jianwei; Wang, Jianan; Zhu, Lei Chemical Engineering Journal, Vol. 411 https://doi.org/10.1016/j.cej.2021.128540	journal	May 2021
Study on catalytic co-pyrolysis of physical mixture/staged pyrolysis characteristics of lignite and straw over an catalytic beds of char and its mechanism Zhao, Hongyu; Song, Qiang; Liu, Shucheng Energy Conversion and Management, Vol. 161 https://doi.org/10.1016/j.enconman.2018.01.083	journal	April 2018
Study on dry desulfurization performance of MnOx hydrothermally loaded halloysite desulfurizer Lei, Zhang; Hao, Shu; Yusu, Wang Environmental Technology & Innovation, Vol. 26 https://doi.org/10.1016/j.eti.2022.102308	journal	May 2022
Characterization of the products obtained by pyrolysis of oil sludge with steel slag in a continuous pyrolysis-magnetic separation reactor Song, Qiang; Zhao, HongYu; Jia, JinWei Fuel, Vol. 255 https://doi.org/10.1016/j.fuel.2019.115711	journal	November 2019
Plasma-enhanced NOx remediation using nanosecond pulsed discharges in a water aerosol matrix Schroeder, Christi; Schroeder, William; Yang, Sisi Fuel Processing Technology, Vol. 208 https://doi.org/10.1016/j.fuproc.2020.106521	journal	November 2020
Syngas production by steam and oxy-steam reforming of biogas on monolith-supported CeO2-based catalysts Vita, Antonio; Italiano, Cristina; Ashraf, M. Arsalan International Journal of Hydrogen Energy, Vol. 43, Issue 26 https://doi.org/10.1016/j.ijhydene.2017.11.140	journal	June 2018
Investigation on the thermal behavior characteristics and products composition of four pulverized coals: Its potential applications in coal cleaning Zhao, Hongyu; Li, Yuhuan; Song, Qiang International Journal of Hydrogen Energy, Vol. 44, Issue 42 https://doi.org/10.1016/j.ijhydene.2019.07.087	journal	September 2019
Study on solid waste pyrolysis coke catalyst for catalytic cracking of coal tar Lei, Zhang; Hao, Shu; Yang, Jia International Journal of Hydrogen Energy, Vol. 45, Issue 38 https://doi.org/10.1016/j.ijhydene.2020.05.075	journal	July 2020
Catalytic reforming of volatiles from co-pyrolysis of lignite blended with corn straw over three different structures of iron ores Zhao, Hongyu; Li, Yuhuan; Song, Qiang Journal of Analytical and Applied Pyrolysis, Vol. 144 https://doi.org/10.1016/j.jaap.2019.104714	journal	November 2019
Effects of demineralization on the surface morphology, microcrystalline and thermal transformation characteristics of coal Song, Qiang; Zhao, Hongyu; Jia, Jinwei Journal of Analytical and Applied Pyrolysis, Vol. 145 https://doi.org/10.1016/j.jaap.2019.104716	journal	January 2020
Preparation of soybean oil factory sludge catalyst and its application in selective catalytic oxidation denitration process Lei, Zhang; Jihao, Chen; Zhang, Lei Journal of Cleaner Production, Vol. 225 https://doi.org/10.1016/j.jclepro.2019.03.254	journal	July 2019
An application of green surfactant synergistically metal supported cordierite catalyst in denitration of Selective Catalytic Oxidation Lei, Zhang; Gao, Hao; Chang, Xin Journal of Cleaner Production, Vol. 249 https://doi.org/10.1016/j.jclepro.2019.119307	journal	March 2020
Co-combustion of textile dyeing sludge with cattle manure: Assessment of thermal behavior, gaseous products, and ash characteristics Zhang, Junhui; Sun, Guang; Liu, Jingyong Journal of Cleaner Production, Vol. 253 https://doi.org/10.1016/j.jclepro.2019.119950	journal	April 2020
Pyrolysis of municipal solid waste with iron-based additives: A study on the kinetic, product distribution and catalytic mechanisms Song, Qiang; Zhao, Hongyu; Jia, Jinwei Journal of Cleaner Production, Vol. 258 https://doi.org/10.1016/j.jclepro.2020.120682	journal	June 2020
Plasma assisted Cu-Mn mixed oxide catalysts for trichloroethylene abatement in moist air Veerapandian, Savita Kaliya Perumal; Ye, Zhiping; Giraudon, Jean-Marc Journal of Hazardous Materials, Vol. 379 https://doi.org/10.1016/j.jhazmat.2019.120781	journal	November 2019
Effect of Ce doping into V 2 O 5 -WO 3 /TiO 2 catalysts on the selective catalytic reduction of NO x by NH 3 Chen, Mengyin; Zhao, Mengmeng; Tang, Fushun Journal of Rare Earths, Vol. 35, Issue 12 https://doi.org/10.1016/j.jre.2017.06.004	journal	December 2017
Effective removal of automobile exhausts over flower-like Ce1−Cu O2 nanocatalysts exposed active {100} plane Selvamani, A.; Shanthi, K.; Santhanaraj, D. Journal of Rare Earths, Vol. 36, Issue 6 https://doi.org/10.1016/j.jre.2017.12.006	journal	June 2018
CFD simulation of combustible solid waste pyrolysis in a fluidized bed reactor Ding, Kuan; Xiong, Qingang; Zhong, Zhaoping Powder Technology, Vol. 362 https://doi.org/10.1016/j.powtec.2019.12.011	journal	February 2020
Smart formaldehyde detection enabled by metal organic framework-derived doped electrospun hollow nanofibers Zhu, Lei; Wang, Jianan; Liu, Jianwei Sensors and Actuators B: Chemical, Vol. 326 https://doi.org/10.1016/j.snb.2020.128819	journal	January 2021
Mini-Review on Char Catalysts for Tar Reforming during Biomass Gasification: The Importance of Char Structure Xu, Deliang; Yang, Liu; Ding, Kuan Energy & Fuels, Vol. 34, Issue 2 https://doi.org/10.1021/acs.energyfuels.9b03725	journal	December 2019
Surfactant assisted synthesis of hierarchical porous metal-organic frameworks nanosheets Abdelhamid, Hani Nasser Nanotechnology, Vol. 30, Issue 43 https://doi.org/10.1088/1361-6528/ab30f6	journal	August 2019
Plasma and catalyst for the oxidation of NOx Jõgi, Indrek; Erme, Kalev; Levoll, Erik Plasma Sources Science and Technology, Vol. 27, Issue 3 https://doi.org/10.1088/1361-6595/aaae3c	journal	February 2018
Measurement of automobile N₂O from bag and continuous stream by quantum cascade laser spectroscopy Rahman, Montajir; Rooney, Richard; Hara, Kenji International Journal of Engine Research, Vol. 20, Issue 2 https://doi.org/10.1177/1468087417750937	journal	January 2018

Similar Records

Experimental evidence for the acceleration of slag hydration in blended cements by the addition of CaCl2

Journal Article · 2021 · Cement and Concrete Research · OSTI ID:23206203

Steger, Laurent; Blotevogel, Simon; Frouin, Laurent; +2 more

Impact of chemical variability of ground granulated blast-furnace slag on the phase formation in alkali-activated slag pastes

Journal Article · 2016 · Cement and Concrete Research · OSTI ID:22697085

Gong, Kai

Vitreous spheres of slag and slag-like materials and underground proppants

Patent · 1966 · OSTI ID:6625190

Schott, C W

Title: Effect of bimetallic modification on blast furnace slag and its application in low‐temperature selective catalytic reduction

Citation Formats

References (38)

Similar Records

Related Subjects