Copper Complexes with Diazoolefin Ligands and their Photochemical Conversion into Alkenylidene Complexes

Kooij, Bastiaan; Varava, Paul; Fadaei‐Tirani, Farzaneh; Scopelliti, Rosario; Pantazis, Dimitrios A.; Van Trieste, III, Gerard P.; Powers, David C.; Severin, Kay

doi:10.1002/ange.202214899

Title: Copper Complexes with Diazoolefin Ligands and their Photochemical Conversion into Alkenylidene Complexes

Journal Article · 18 December 2022 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.202214899 · OSTI ID:1905676

^[1];

^[2]; Van Trieste, III, Gerard P. ^[3];

^[3];

^[1]

Institut des Sciences et Ingénierie Chimiques Ecole Polytechnique Fédérale de Lausanne (EPFL) 1015 Lausanne Switzerland
Max-Planck-Institut für Kohlenforschung 45470 Mülheim an der Ruhr Germany
Department of Chemistry Texas A&,M University College Station TX 77843 USA

Abstract Homometallic copper complexes with alkenylidene ligands are discussed as intermediates in catalysis but the isolation of such complexes has remained elusive. Herein, we report the structural characterization of copper complexes with bridging and terminal alkenylidene ligands. The compounds were obtained by irradiation of Cu ^I complexes with N‐heterocyclic diazoolefin ligands. The complex with a terminal alkenylidene ligand required isolation in a crystalline matrix, and its structural characterization was enabled by in crystallo photolysis at low temperature.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357; SC0018977

OSTI ID:: 1905676

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 4 Vol. 135; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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