Magnetic interactions in the one-dimensional spin-chain metal-organic compounds M ( N 2 H 5 ) 2 ( SO 4 ) 2 ( M = Cu ,   Co ,   Mn )

Calder, S.; Sanjeewa, L. D.; Garlea, V. O.; Xing, J.; Terry, R. J.; Kolis, J. W.

doi:10.1103/PhysRevMaterials.6.124407

Title: Magnetic interactions in the one-dimensional spin-chain metal-organic compounds $M {(N_{2} H_{5})}_{2} {({SO}_{4})}_{2}$ $(M = Cu, Co, Mn)$

Authors:

; Sanjeewa, L. D.; Garlea, V. O.; Xing, J.;

; Kolis, J. W.

Publication Date:: Mon Dec 19 00:00:00 EST 2022

Sponsoring Org.:: USDOE

OSTI Identifier:: 1905674

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Physical Review Materials

Additional Journal Information:: Journal Name: Physical Review Materials Journal Volume: 6 Journal Issue: 12; Journal ID: ISSN 2475-9953

Publisher:: American Physical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Calder, S., Sanjeewa, L. D., Garlea, V. O., Xing, J., Terry, R. J., and Kolis, J. W. Magnetic interactions in the one-dimensional spin-chain metal-organic compounds M ( N 2 H 5 ) 2 ( SO 4 ) 2 ( M = Cu ,   Co ,   Mn ).  United States: N. p., 2022. 
Web.  doi:10.1103/PhysRevMaterials.6.124407.

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                    Calder, S., Sanjeewa, L. D., Garlea, V. O., Xing, J., Terry, R. J., & Kolis, J. W. Magnetic interactions in the one-dimensional spin-chain metal-organic compounds M ( N 2 H 5 ) 2 ( SO 4 ) 2 ( M = Cu ,   Co ,   Mn ).  United States.  https://doi.org/10.1103/PhysRevMaterials.6.124407

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                    Calder, S., Sanjeewa, L. D., Garlea, V. O., Xing, J., Terry, R. J., and Kolis, J. W. Mon .  
"Magnetic interactions in the one-dimensional spin-chain metal-organic compounds M ( N 2 H 5 ) 2 ( SO 4 ) 2 ( M = Cu ,   Co ,   Mn )".  United States.  https://doi.org/10.1103/PhysRevMaterials.6.124407.

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@article{osti_1905674,

  title        = {Magnetic interactions in the one-dimensional spin-chain metal-organic compounds M ( N 2 H 5 ) 2 ( SO 4 ) 2 ( M = Cu ,   Co ,   Mn )},

  author       = {Calder, S. and Sanjeewa, L. D. and Garlea, V. O. and Xing, J. and Terry, R. J. and Kolis, J. W.},

  abstractNote = {},

  doi          = {10.1103/PhysRevMaterials.6.124407},

  journal      = {Physical Review Materials},

  number       = 12,

  volume       = 6,

  place        = {United States},

  year         = {Mon Dec 19 00:00:00 EST 2022},

  month        = {Mon Dec 19 00:00:00 EST 2022}

}

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Works referenced in this record:

Specific heat of hydrazinium-transition metal-sulfate linear chain compounds
journal, January 1975

Klaaijsen, F. W.; Den Adel, H.; Dokoupil, Z.
Physica B+C, Vol. 79, Issue 2
DOI: 10.1016/0378-4363(75)90025-X

Magnetic properties of six-coordinated high-spin cobalt(II) complexes: Theoretical background and its application
journal, September 2008

Lloret, Francesc; Julve, Miguel; Cano, Joan
Inorganica Chimica Acta, Vol. 361, Issue 12-13
DOI: 10.1016/j.ica.2008.03.114

Determination of atomic site susceptibility tensors from neutron diffraction data on polycrystalline samples
journal, November 2010

Gukasov, A.; Brown, P. J.
Journal of Physics: Condensed Matter, Vol. 22, Issue 50
DOI: 10.1088/0953-8984/22/50/502201

Probing magnetic interactions in metal–organic frameworks and coordination polymers microscopically
journal, January 2018

Saines, Paul J.; Bristowe, Nicholas C.
Dalton Transactions, Vol. 47, Issue 38
DOI: 10.1039/C8DT02411A

Paramagnetic and Optical Spectra of Divalent Cobalt in Cubic Crystalline Fields
journal, January 1958

Low, W.
Physical Review, Vol. 109, Issue 2
DOI: 10.1103/PhysRev.109.256

Linear-chain antiferromagnetism in the compounds MII(N2H5)2(SO4)2 with M = Mn, Fe, Co, Ni, and Cu
journal, June 1974

Witteveen, H. T.; Reedijk, J.
Journal of Solid State Chemistry, Vol. 10, Issue 2
DOI: 10.1016/0022-4596(74)90022-X

Linear-chain antiferromagnetism in Ni(N2H5)2(SO4)2
journal, June 1973

Witteveen, H. T.; Reedijk, J.
Solid State Communications, Vol. 12, Issue 11
DOI: 10.1016/0038-1098(73)90126-9

Magnetic metal–organic frameworks
journal, January 2009

Kurmoo, Mohamedally
Chemical Society Reviews, Vol. 38, Issue 5, 1353-1379
DOI: 10.1039/b804757j

Symmetry-Based Computational Tools for Magnetic Crystallography
journal, July 2015

Perez-Mato, J. M.; Gallego, S. V.; Tasci, E. S.
Annual Review of Materials Research, Vol. 45, Issue 1
DOI: 10.1146/annurev-matsci-070214-021008

A suite-level review of the neutron powder diffraction instruments at Oak Ridge National Laboratory
journal, September 2018

Calder, S.; An, K.; Boehler, R.
Review of Scientific Instruments, Vol. 89, Issue 9
DOI: 10.1063/1.5033906

Dimensionality Selection in a Molecule-Based Magnet
journal, February 2012

Goddard, Paul A.; Manson, Jamie L.; Singleton, John
Physical Review Letters, Vol. 108, Issue 7
DOI: 10.1103/PhysRevLett.108.077208

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

Rodríguez-Carvajal, Juan
Physica B: Condensed Matter, Vol. 192, Issue 1-2
DOI: 10.1016/0921-4526(93)90108-I

Iron(II) hydrazinium sulfate
journal, January 2007

Srinivasan, Krishnan; Govindarajan, Subbaiah; Harrison, William T. A.
Acta Crystallographica Section E Structure Reports Online, Vol. 63, Issue 2
DOI: 10.1107/S1600536806056509

Chromous hydrazine sulfate
journal, June 2001

Parkins, Adrian W.; Prince, Paul D.; Smith, Robert A. L.
Acta Crystallographica Section C Crystal Structure Communications, Vol. 57, Issue 6
DOI: 10.1107/S0108270101000919

Crossover from one- to three-dimensional behavior in theS = 1/2 Heisenberg antiferromagnet Cu(N₂H₅)₂(SO₄)₂
journal, October 2016

Paduan-Filho, A.; Vieira, A. P.; Ramon, J. G. A.
Journal of Physics: Condensed Matter, Vol. 28, Issue 50
DOI: 10.1088/0953-8984/28/50/506004

Spectroscopic study of the one- and three-dimensional magnetic interactions of a linear-chain antiferromagnet. Temperature dependence of the zero-field Moessbauer spectrum of hydrazinium ferrous sulfate, Fe(N2H5)2(SO4)2
journal, April 1977

Cheng, Chris.; Wong, Herbert.; Reiff, William Michael.
Inorganic Chemistry, Vol. 16, Issue 4
DOI: 10.1021/ic50170a019

The unit-cell dimensions of the metal hydrazinium sulphates (N2H5)2MII(SO4)2
journal, January 1966

Hand, D. W.; Prout, C. K.
Journal of the Chemical Society A: Inorganic, Physical, Theoretical
DOI: 10.1039/j19660000168

Conversion method of powder inelastic scattering data for one-dimensional systems
journal, March 2009

Tomiyasu, K.; Fujita, M.; Kolesnikov, A. I.
Applied Physics Letters, Vol. 94, Issue 9
DOI: 10.1063/1.3089566

A new protocol for the determination of magnetic structures using simulated annealing and representational analysis (SARAh)
journal, March 2000

Wills, A. S.
Physica B: Condensed Matter, Vol. 276-278
DOI: 10.1016/S0921-4526(99)01722-6

Über luftbeständige Chromoxydul‐Verbindungen
journal, April 1913

Traube, Wilhelm; Passarge, W.
Berichte der deutschen chemischen Gesellschaft, Vol. 46, Issue 2
DOI: 10.1002/cber.19130460238

Linear spin wave theory for single-Q incommensurate magnetic structures
journal, March 2015

Toth, S.; Lake, B.
Journal of Physics: Condensed Matter, Vol. 27, Issue 16
DOI: 10.1088/0953-8984/27/16/166002

The high-resolution powder diffractometer at the high flux isotope reactor
journal, March 2010

Garlea, V. O.; Chakoumakos, B. C.; Moore, S. A.
Applied Physics A, Vol. 99, Issue 3
DOI: 10.1007/s00339-010-5603-6

817. Hydrazinium (1+) as a ligand
journal, January 1961

Prout, C. K.; Powell, H. M.
Journal of the Chemical Society (Resumed)
DOI: 10.1039/jr9610004177

Dirac Magnons in a Honeycomb Lattice Quantum $XY$ Magnet ${CoTiO}_{3}$
journal, March 2020

Yuan, Bo; Khait, Ilia; Shu, Guo-Jiun
Physical Review X, Vol. 10, Issue 1
DOI: 10.1103/PhysRevX.10.011062

Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites
journal, September 2011

Stock, Norbert; Biswas, Shyam
Chemical Reviews, Vol. 112, Issue 2
DOI: 10.1021/cr200304e

Magnetic functionalities in MOFs: from the framework to the pore
journal, January 2018

Mínguez Espallargas, Guillermo; Coronado, Eugenio
Chemical Society Reviews, Vol. 47, Issue 2
DOI: 10.1039/C7CS00653E

Local magnetic anisotropy by polarized neutron powder diffraction: Application of magnetically induced preferred crystallite orientation
journal, November 2019

Kibalin, I. A.; Gukasov, A.
Physical Review Research, Vol. 1, Issue 3
DOI: 10.1103/PhysRevResearch.1.033100

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Title: Magnetic interactions in the one-dimensional spin-chain metal-organic compounds M ( N 2 H 5 ) 2 ( SO 4 ) 2 ( M = Cu , Co , Mn )

Citation Formats

Specific heat of hydrazinium-transition metal-sulfate linear chain compounds journal, January 1975

Magnetic properties of six-coordinated high-spin cobalt(II) complexes: Theoretical background and its application journal, September 2008

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Magnetic metal–organic frameworks journal, January 2009

Symmetry-Based Computational Tools for Magnetic Crystallography journal, July 2015

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Recent advances in magnetic structure determination by neutron powder diffraction journal, October 1993

Iron(II) hydrazinium sulfate journal, January 2007

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Crossover from one- to three-dimensional behavior in theS = 1/2 Heisenberg antiferromagnet Cu(N2H5)2(SO4)2 journal, October 2016

Spectroscopic study of the one- and three-dimensional magnetic interactions of a linear-chain antiferromagnet. Temperature dependence of the zero-field Moessbauer spectrum of hydrazinium ferrous sulfate, Fe(N2H5)2(SO4)2 journal, April 1977

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Title: Magnetic interactions in the one-dimensional spin-chain metal-organic compounds $M {(N_{2} H_{5})}_{2} {({SO}_{4})}_{2}$ $(M = Cu, Co, Mn)$

Specific heat of hydrazinium-transition metal-sulfate linear chain compounds
journal, January 1975

Magnetic properties of six-coordinated high-spin cobalt(II) complexes: Theoretical background and its application
journal, September 2008

Determination of atomic site susceptibility tensors from neutron diffraction data on polycrystalline samples
journal, November 2010

Probing magnetic interactions in metal–organic frameworks and coordination polymers microscopically
journal, January 2018

Paramagnetic and Optical Spectra of Divalent Cobalt in Cubic Crystalline Fields
journal, January 1958

Linear-chain antiferromagnetism in the compounds MII(N2H5)2(SO4)2 with M = Mn, Fe, Co, Ni, and Cu
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Linear-chain antiferromagnetism in Ni(N2H5)2(SO4)2
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Magnetic metal–organic frameworks
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A suite-level review of the neutron powder diffraction instruments at Oak Ridge National Laboratory
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